Comments on the Competitive Preferential Solvation Theory

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Article commenting on the competitive preferential solvation theory.

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3 p.

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Acree, William E. (William Eugene); Zvaigzne, Anita I. & Tucker, Sheryl A. (Sheryl Ann) 1990.

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Article commenting on the competitive preferential solvation theory.

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3 p.

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Journal of the Chemical Society, Faraday Transactions, 1990, 86:2, pp. 307-309, http://pubs.rsc.org/en/content/articlehtml/1990/ft/ft9908600307

Abstract: Simple additive relationships for the physico-chemical properties of a solute dissolved in binary solvent mixtures are developed from the competitive preferential solvation model. Additive expressions for solute mole fraction solubility and logarithm of solute solubility are mathematically identical to equations derived previously from the microscopic partition and basic nearly ideal binary solvent models. Calculated values based on the various additive relationships are compared to carbazole solubilities in ten binary solvent mixtures containing dibutyl ether with n-hexane, n-heptane, n-octane, cyclohexane, cyclo-octane, methylcyclohexane, iso-octane, n-hexadecane, squalane and t-butylcyclohexane.

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  • Journal of the Chemical Society, Faraday Transactions, 1990, Cambridge: Royal Society of Chemistry (Great Britain), pp. 307-309

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  • Publication Title: Journal of the Chemical Society, Faraday Transactions
  • Volume: 86
  • Issue: 2
  • Page Start: 307
  • Page End: 309
  • Peer Reviewed: Yes

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  • 1990

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  • April 26, 2013, 10:06 a.m.

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Acree, William E. (William Eugene); Zvaigzne, Anita I. & Tucker, Sheryl A. (Sheryl Ann). Comments on the Competitive Preferential Solvation Theory, article, 1990; [Cambridge, England]. (digital.library.unt.edu/ark:/67531/metadc157300/: accessed June 23, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.