The transfer of neutral molecules, ions and ionic species from water to benzonitrile; comparison with nitrobenzene

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Article on the transfer of neutral molecules, ions and ionic species from water to benzonitrile and a comparison with nitrobenzene.

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18 p.

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Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.) October 15, 2011.

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Article on the transfer of neutral molecules, ions and ionic species from water to benzonitrile and a comparison with nitrobenzene.

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18 p.

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This is the author manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved. The final definitive version is available here: http://dx.doi.org/10.1016/j.tca.2011.08.014

Abstract: Equations have been constructed for the transfer of 64 neutral solutes from water and from the gas phase to the solvent benzonitrile. The equations contain five descriptors and can be used to predict further values of the water-benzonitrile and gas-benzonitrile partition coefficients for a wide range of solutes. The water-benzonitrile equation has been extended to include ions and ionic species derived from acids by loss of a proton and bases by acceptance of a proton. Only two further descriptors are needed, one for anions and one for cations. A previous equation for transfer of neutral solutes from water to nitrobenzene has also been extended to include ions and ionic species. Comparison of the equations for transfer to benzonitrile and to nitrobenzene shows that the two solvents behave quite similarly, although benzonitrile as a solvent is a stronger hydrogen bond base.

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  • Thermochimica Acta, 2011, New York: Elsevier Science Ltd., pp. 22-28

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  • Publication Title: Thermochimica Acta
  • Volume: 526
  • Issue: 1-2
  • Page Start: 22
  • Page End: 28
  • Peer Reviewed: Yes

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  • October 15, 2011

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  • April 26, 2013, 10:06 a.m.

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  • April 1, 2015, 1:13 p.m.

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Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.). The transfer of neutral molecules, ions and ionic species from water to benzonitrile; comparison with nitrobenzene, article, October 15, 2011; [New York, New York]. (digital.library.unt.edu/ark:/67531/metadc157294/: accessed November 17, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.