Abraham Model Correlations for Transfer of Neutral Molecules and Ions to Sulfolane

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Article on Abraham model correlations for the transfer of neutral molecules and ions to sulfolane.

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20 p.

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Stephens, Timothy W.; De la Rosa, Nohelli E.; Saifullah, Mariam; Ye, Shulin; Chou, Vicky; Quay, Amanda N. et al. October 15, 2011.

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Article on Abraham model correlations for the transfer of neutral molecules and ions to sulfolane.

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20 p.

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This is the authors' manuscript version of the article. Reprinted from the Fluid Phase Equilibria, 2011, 523:1-2, pp. 214-220. Reprinted with permission from Elsevier Science Ltd. The final definitive version is available here: http://dx.doi.org/10.1016/j.fluid.2011.06.037

Abstract: Data have been compiled from the published literature on the partition coefficients of solutes and vapors into anhydrous sulfolane. The logarithms of the water-to-sulfolane partition coefficients, log P, and gas-to-sulfolane partition coefficients, log K, were correlated with the Abraham solvation parameter model. The derived correlations described the observed log P and log K values for solutes dissolved in sulfolane to within average standard deviations of 0.14 log units or less. The log P correlation was extended to include the partition of ions by inclusion of a cation-solvent and an anion-solvent term.

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  • Fluid Phase Equilibria, 2011, New York: Elsevier Science Ltd., pp. 30-35

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  • Publication Title: Fluid Phase Equilibria
  • Volume: 309
  • Issue: 1
  • Page Start: 30
  • Page End: 35
  • Peer Reviewed: Yes

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  • October 15, 2011

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  • April 26, 2013, 10:06 a.m.

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  • April 1, 2015, 1:09 p.m.

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Stephens, Timothy W.; De la Rosa, Nohelli E.; Saifullah, Mariam; Ye, Shulin; Chou, Vicky; Quay, Amanda N. et al. Abraham Model Correlations for Transfer of Neutral Molecules and Ions to Sulfolane, article, October 15, 2011; [New York, New York]. (digital.library.unt.edu/ark:/67531/metadc157293/: accessed September 19, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.