Development of Abraham model correlations for solvation characteristics of linear alcohols

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This article discusses the development of Abraham model correlations for solvation characteristics of linear alcohols.

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23 p.

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Sprunger, Laura M.; Achi, Sai S.; Pointer, Racheal; Blake-Taylor, Brooke H.; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.) December 15, 2009.

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This article is part of the collection entitled: UNT Scholarly Works and was provided by UNT College of Arts and Sciences to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 148 times . More information about this article can be viewed below.

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This article discusses the development of Abraham model correlations for solvation characteristics of linear alcohols.

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23 p.

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This is the accepted manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved. The final definitive version is available here: http://dx.doi.org/10.1016/j.fluid.2009.09.004

Abstract: Data have been compiled from the published literature on the partition coefficients of solutes and vapors into the anhydrous linear alcohols (methanol through 1-heptanol, and 1-decanol) from both water and from the gas phase. The logarithms of the water-to-alcohol partition coefficients (log P) and gas-to-alcohol partition coefficients (log K) were correlated with the Abraham solvation parameter model. The derived correlations described the observed log P and log K values to within average standard deviations of 0.14 and 0.12 log units, respectively. The predictive abilities of the each correlation were assessed by dividing databases into a separate training set and test set.

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  • Fluid Phase Equilibria, 2009, Amsterdam: Elsevier Science Ltd., pp. 170-174

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  • Publication Title: Fluid Phase Equilibria
  • Volume: 286
  • Issue: 2
  • Page Start: 170
  • Page End: 174
  • Peer Reviewed: Yes

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  • December 15, 2009

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  • April 16, 2013, 8:47 a.m.

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  • May 28, 2014, 2:15 p.m.

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Sprunger, Laura M.; Achi, Sai S.; Pointer, Racheal; Blake-Taylor, Brooke H.; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.). Development of Abraham model correlations for solvation characteristics of linear alcohols, article, December 15, 2009; [Amsterdam, Netherlands]. (digital.library.unt.edu/ark:/67531/metadc155631/: accessed December 14, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.