Correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase Metadata

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Title

  • Main Title Correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase

Creator

  • Author: Sprunger, Laura M.
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Achi, Sai S.
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Acree, William E. (William Eugene)
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Abraham, M. H. (Michael H.)
    Creator Type: Personal
    Creator Info: University College London
  • Author: Hoekman, David
    Creator Type: Personal
    Creator Info: David Hoekman Consulting, Inc.
  • Author: Leo, Albert J.
    Creator Type: Personal
    Creator Info: BioByte Corp.

Publisher

  • Name: Elsevier Science Ltd.
    Place of Publication: [New York, New York]

Date

  • Creation: 2009-07-25

Language

  • English

Description

  • Content Description: Article discussing research on the correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase.
  • Physical Description: 71 p.

Subject

  • Keyword: carbon tetrachloride
  • Keyword: chloroform
  • Keyword: dichloromethane
  • Keyword: 1-chlorobutane
  • Keyword: partition coefficients
  • Keyword: molecular solute descriptors

Source

  • Journal: Fluid Phase Equilibria, 2009, New York: Elsevier Science Ltd., pp. 144-162

Citation

  • Publication Title: Fluid Phase Equilibria
  • Volume: 281
  • Issue: 2
  • Page Start: 144
  • Page End: 162
  • Peer Reviewed: True

Collection

  • Name: UNT Scholarly Works
    Code: UNTSW

Institution

  • Name: UNT College of Arts and Sciences
    Code: UNTCAS

Rights

  • Rights Access: public

Resource Type

  • Article

Format

  • Text

Identifier

  • DOI: 10.1016/j.fluid.2009.04.012
  • Archival Resource Key: ark:/67531/metadc155630

Degree

  • Academic Department: Chemistry

Note

  • Display Note: This is the accepted manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved. The final definitive version is available here: http://dx.doi.org/10.1016/j.fluid.2009.04.012
  • Display Note: Abstract: Data have been compiled from the published literature on the partition coefficients of solutes and vapors into chloroform, carbon tetrachloride, dichloromethane and 1-chlorobutane from both water and from the gas phase. The logarithms of the water-to-chloroalkane (log P) and gas-to-chloroalkane partition coefficients (log K) are correlated with the Abraham solvation parameter model. The derived correlations describe the observed log P and log K values within standard deviations of about 0.13-0.20 log units. For chloroform and carbon tetrachloride, the derived correlations were validated using training set and test set analyses.