Correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase

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Article discussing research on the correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase.

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71 p.

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Sprunger, Laura M.; Achi, Sai S.; Acree, William E. (William Eugene); Abraham, M. H. (Michael H.); Hoekman, David & Leo, Albert J. July 25, 2009.

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Article discussing research on the correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase.

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71 p.

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This is the accepted manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved. The final definitive version is available here: http://dx.doi.org/10.1016/j.fluid.2009.04.012

Abstract: Data have been compiled from the published literature on the partition coefficients of solutes and vapors into chloroform, carbon tetrachloride, dichloromethane and 1-chlorobutane from both water and from the gas phase. The logarithms of the water-to-chloroalkane (log P) and gas-to-chloroalkane partition coefficients (log K) are correlated with the Abraham solvation parameter model. The derived correlations describe the observed log P and log K values within standard deviations of about 0.13-0.20 log units. For chloroform and carbon tetrachloride, the derived correlations were validated using training set and test set analyses.

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  • Fluid Phase Equilibria, 2009, New York: Elsevier Science Ltd., pp. 144-162

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  • Publication Title: Fluid Phase Equilibria
  • Volume: 281
  • Issue: 2
  • Page Start: 144
  • Page End: 162
  • Peer Reviewed: Yes

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  • July 25, 2009

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  • April 16, 2013, 8:47 a.m.

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  • April 1, 2015, 1:06 p.m.

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Sprunger, Laura M.; Achi, Sai S.; Acree, William E. (William Eugene); Abraham, M. H. (Michael H.); Hoekman, David & Leo, Albert J. Correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase, article, July 25, 2009; [New York, New York]. (digital.library.unt.edu/ark:/67531/metadc155630/: accessed October 19, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.