Correlation and prediction of partition coefficient between the gas phase and water, and the solvents dry methyl acetate, dry and wet ethyl acetate, and dry and wet butyl acetate

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Article discussing research on the correlation and prediction of partition coefficient between the gas phase and water, and the solvents dry methyl acetate, dry and wet ethyl acetate, and dry and wet butyl acetate.

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46 p.

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Sprunger, Laura M.; Proctor, Amy; Acree, William E. (William Eugene); Abraham, M. H. (Michael H.) & Benjellou-Dakhama, Nora August 25, 2008.

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Article discussing research on the correlation and prediction of partition coefficient between the gas phase and water, and the solvents dry methyl acetate, dry and wet ethyl acetate, and dry and wet butyl acetate.

Physical Description

46 p.

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This is the accepted manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved. The final definitive version is available here: http://dx.doi.org/10.1016/j.fluid.2008.06.001

Abstract: Experimental partition coefficient data have been compiled from the published literature for the water/methyl acetate, water/ethyl acetate and water/butyl acetate partition systems, log P data, and for the gas/methyl acetate, gas/ethyl acetate and gas/butyl acetate partition systems, log K data. Application of the Abraham solvation parameter model to the sets of partition coefficients leads to equations that correlate the log P data and log K data to 0.18 log units for the three dry alkyl acetate solvents. Slightly larger deviations were noted for solute partition into both wet ethyl acetate and wet butyl acetate. The derived correlations were validated using training set and test set analyses.

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  • Fluid Phase Equilibria, 2008, New York: Elsevier Science Ltd., pp. 30-44

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  • Publication Title: Fluid Phase Equilibria
  • Volume: 270
  • Issue: 1-2
  • Page Start: 30
  • Page End: 44
  • Peer Reviewed: Yes

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  • August 25, 2008

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  • April 16, 2013, 8:47 a.m.

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  • April 1, 2015, 1:44 p.m.

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Sprunger, Laura M.; Proctor, Amy; Acree, William E. (William Eugene); Abraham, M. H. (Michael H.) & Benjellou-Dakhama, Nora. Correlation and prediction of partition coefficient between the gas phase and water, and the solvents dry methyl acetate, dry and wet ethyl acetate, and dry and wet butyl acetate, article, August 25, 2008; [New York, New York]. (digital.library.unt.edu/ark:/67531/metadc155629/: accessed December 14, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.