Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Chloroform and 1,2-dichloroethane Based on the Abraham Model Metadata

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Title

  • Main Title Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Chloroform and 1,2-dichloroethane Based on the Abraham Model

Creator

  • Author: Mintz, Christina
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Burton, Katherine
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Acree, William E. (William Eugene)
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Abraham, M. H. (Michael H.)
    Creator Type: Personal
    Creator Info: University College London

Publisher

  • Name: Elsevier Science Ltd.
    Place of Publication: [Amsterdam, Netherlands]

Date

  • Creation: 2007-09-15

Language

  • English

Description

  • Content Description: This article discusses enthalpy of solvation correlations for gaseous solutes dissolved in chloroform and 1,2-dichloroethane based on the Abraham model.
  • Physical Description: 25 p.

Subject

  • Keyword: enthalpy of solvation
  • Keyword: enthalpy of transfers
  • Keyword: mathematical correlations
  • Keyword: partition coefficients
  • Keyword: solvation parameter model

Source

  • Journal: Fluid Phase Equilibria, 2007, Amsterdam: Elsevier Science Ltd., pp. 191-198

Citation

  • Publication Title: Fluid Phase Equilibria
  • Volume: 258
  • Issue: 2
  • Page Start: 191
  • Page End: 198
  • Peer Reviewed: True

Collection

  • Name: UNT Scholarly Works
    Code: UNTSW

Institution

  • Name: UNT College of Arts and Sciences
    Code: UNTCAS

Rights

  • Rights Access: public

Resource Type

  • Article

Format

  • Text

Identifier

  • DOI: 10.1016/j.fluid.2007.06.016
  • Archival Resource Key: ark:/67531/metadc155628

Degree

  • Academic Department: Chemistry

Note

  • Display Note: This is the accepted manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved. The final definitive version is available here: http://dx.doi.org/10.1016/j.fluid.2007.06.016
  • Display Note: Abstract: Enthalpy of solvation data have been compiled from the published literature for more than 80 solutes dissolved in chloroform and 1,2-dichloromethane. Mathematical correlations based on the Abraham general solvation parameter model are developed for describing the experimental solvation enthalpies to within standard deviations of 2.10 kJ/mol (chloroform) and 1.72 kJ/mol (1,2-dichloroethane). Division of the measured values into a training set and a test set shows that there is no bias in predictions, and that the estimative capability of the correlations is better than 2.5 kJ/mol.