Cation-specific and anion-specific Abraham model correlations for solute transfer into ionic liquid solvents

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Article discussing research on cation-specific and anion-specific Abraham model correlations for solute transfer into ionic liquid solvents.

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19 p.

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Grubbs, Laura M.; Saifullah, Mariam; De la Rosa, Nohelli E.; Acree, William E. (William Eugene); Abraham, M. H. (Michael H.); Zhao, Qichao et al. August 2010.

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  • Cognizure
    Place of Publication: [Tamil Nadu, India]

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Article discussing research on cation-specific and anion-specific Abraham model correlations for solute transfer into ionic liquid solvents.

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19 p.

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Abstract: Data have been assembled from the published literature on the infinite dilution activity coefficients and gas solubilities of solutes dissolved in ionic liquid (IL) solvents. In total data for more than 1790 solute-IL pairs were compiled. The published experimental data were converted to gas-to-IL and water-to-IL partition coefficients, and correlated with the ion-specific equation coefficient version of the Abraham general solvation model. Ion-specific equation coefficients describe the experimental gas-to-IL and water-to-IL partition coefficient data to within 0.114 and 0.139 log units, respectively. Reported for the first time are equation coefficients for diethylphosphate, tris(pentafluoroethyl)trifluorophosphate and tetracyanoborate anions.

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  • Global Journal of Physical Chemistry, 2010, Tamil Nadu: Cognizure, pp. 1-19

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  • Publication Title: Global Journal of Physical Chemistry
  • Volume: 1
  • Issue: 1
  • Page Start: 1
  • Page End: 19
  • Peer Reviewed: Yes

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  • August 2010

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  • March 22, 2013, 6:09 p.m.

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  • May 12, 2014, 2:32 p.m.

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Grubbs, Laura M.; Saifullah, Mariam; De la Rosa, Nohelli E.; Acree, William E. (William Eugene); Abraham, M. H. (Michael H.); Zhao, Qichao et al. Cation-specific and anion-specific Abraham model correlations for solute transfer into ionic liquid solvents, article, August 2010; [Tamil Nadu, India]. (digital.library.unt.edu/ark:/67531/metadc152450/: accessed October 20, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.