Highly nucleophilic acetylide, vinyl, and vinylidene complexes. Progress report Metadata

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Title

  • Main Title Highly nucleophilic acetylide, vinyl, and vinylidene complexes. Progress report

Contributor

  • Sponsor: United States. Department of Energy.
    Contributor Type: Organization
    Contributor Info: USDOE, Washington, DC (United States)

Publisher

  • Name: Pennsylvania State Univ., University Park, PA (United States). Dept. of Chemistry
    Place of Publication: United States

Date

  • Creation: 1992-06-15

Language

  • English

Description

  • Content Description: The research was divided into the following: studies of nucleophilic and chiral acetylide complex [Cp(CO)(PPh{sub 3})Mn-C{triple_bond}CR]{sup {minus}}; nucleophilic addition of carbene anions to organic ligands on electrophilic complexes; halide-promoted carbonylation of imido ligands; binuclear Fe{sub 2} complexes with bridging organonitrogen ligands; addition and cycloaddition reactions of carbyne complex [Cp(CO){sub 2}Re{triple_bond}CTol]{sup +}; addition and cycloaddition reactions of methylcarbyne complexes [Cp(CO){sub 2}M{triple_bond}CCH{sub 3}]{sup +} and vinylidene complexes Cp(CO){sub 2}M{double_bond}C{double_bond}CH{sub 2} (M=Mn, Re); studies of generation and reactivity of vinylcarbene complexes formed from reaction of manganese carbene anions and aldehydes; and addition of oxo ligands of nucleophilic oxo complexes to organic ligands on electrophilic metal centers.
  • Physical Description: 9 p.

Subject

  • Keyword: Carbynes
  • Keyword: Iron Complexes
  • Keyword: Alkynes
  • Keyword: Manganese Complexes
  • Keyword: Rhenium Complexes
  • STI Subject Categories: 37 Inorganic, Organic, Physical And Analytical Chemistry
  • Keyword: Carbenes
  • Keyword: Progress Report
  • Keyword: Cyclopentadiene
  • Keyword: Ligands
  • Keyword: Osmium Complexes
  • Keyword: Vinylidene Radicals
  • Keyword: Carbonylation
  • Keyword: Chemical Reactions
  • Keyword: Carbonyls
  • Keyword: Chemical And Physicochemical Properties
  • Keyword: Chemical Properties 400201

Source

  • Other Information: PBD: 15 Jun 1992

Collection

  • Name: Office of Scientific & Technical Information Technical Reports
    Code: OSTI

Institution

  • Name: UNT Libraries Government Documents Department
    Code: UNTGD

Resource Type

  • Report

Format

  • Text

Identifier

  • Other: DE93004560
  • Report No.: DOE/ER/13323--7
  • Grant Number: FG02-85ER13323
  • DOI: 10.2172/10191892
  • Office of Scientific & Technical Information Report Number: 10191892
  • Archival Resource Key: ark:/67531/metadc1402671

Note

  • Display Note: OSTI; NTIS; GPO Dep.