The following cells were operated at 820°C: [equations not transcribed] where the over-all reaction in each cell is simply the transfer of NaCl from pure NaCl to the mixtures of the right hand compartment. The porcelain acts as a pure sodium ion conductor in these cells. The relative partial molar free energy of mixing for sodium chloride, FMNaCl, is given by [equation not transcribed] where E is the EMF of the cell. Results are given over the entire composition range in each system and compared with previous measurements from other sources. Other thermodynamic quantities are calculated from the results. Experiments …
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Brookhaven National Laboratory Report BNL-6589
Description
The following cells were operated at 820°C: [equations not transcribed] where the over-all reaction in each cell is simply the transfer of NaCl from pure NaCl to the mixtures of the right hand compartment. The porcelain acts as a pure sodium ion conductor in these cells. The relative partial molar free energy of mixing for sodium chloride, FMNaCl, is given by [equation not transcribed] where E is the EMF of the cell. Results are given over the entire composition range in each system and compared with previous measurements from other sources. Other thermodynamic quantities are calculated from the results. Experiments using a H2, HCl mixture in place of Cl2 are discussed, as well as the extension of the measurements to other systems.
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Egan, James J. & Bracker, John.Thermodynamics of Fused Salt Mixtures From EMF Measurements. The Systems NaCl-KCl, NaCl-MgCl2, and NaCl-CeCl3.,
report,
February 1, 1963;
Washington D.C..
(https://digital.library.unt.edu/ark:/67531/metadc1250515/:
accessed February 19, 2025),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT Libraries Government Documents Department.