The discussion attempts to summarize present trends and future possibilities. After consideration of the areas of analytical applicability of polarography of organic compounds with stress on the use of chemical treatment to convert polarographically inert species to active ones, the importance of the composition of the test solution is discussed from the viewpoint of the effects of pH, buffer composition and concentration, ionic strength, solvent nature and additives. The critical factors in the preparation of the test solution and in the analysis of the polarographic curve are then considered. The importance of fundamental studies of the electrochemical behavior of organic …
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Atomic Energy Commission Report AECU-3999
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The discussion attempts to summarize present trends and future possibilities. After consideration of the areas of analytical applicability of polarography of organic compounds with stress on the use of chemical treatment to convert polarographically inert species to active ones, the importance of the composition of the test solution is discussed from the viewpoint of the effects of pH, buffer composition and concentration, ionic strength, solvent nature and additives. The critical factors in the preparation of the test solution and in the analysis of the polarographic curve are then considered. The importance of fundamental studies of the electrochemical behavior of organic compounds is stressed. (auth)
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