Behavior of Polyvalent Metallic Ions in 100% Acetic Acid Reactions of Rare Earth Compounds in Acetic Acid

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Description

"The solution of a polymeric oxide such as a rare earth oxide in protonic solvents such as acetic acid may be regarded as a steo-wise process involving rupture of Ln-O-Ln linkages, to form "hydroxyacetates" of varying molecular size and complexity. Intermediate oxo-hydroxo-brdiges aggregates could therefore be formed by solvolysis processes. Further reaction with acetic acid could effect dehydration of such "hydroxyacetates", to yield oxo-bridged acetates, Ln2O(OAc).

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64 pages : illustration, tables

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Audrieth, L. F.; Seaton, J. A. & Sherif, F. G. October 31, 1957.

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  • Main Title: Behavior of Polyvalent Metallic Ions in 100% Acetic Acid Reactions of Rare Earth Compounds in Acetic Acid
  • Added Title: Final Report
  • Series Title: AECU (Series)
  • Series Title: Atomic Energy Commission Reports
  • Added Title: Atomic Energy Commission Report AECU-3662

Description

"The solution of a polymeric oxide such as a rare earth oxide in protonic solvents such as acetic acid may be regarded as a steo-wise process involving rupture of Ln-O-Ln linkages, to form "hydroxyacetates" of varying molecular size and complexity. Intermediate oxo-hydroxo-brdiges aggregates could therefore be formed by solvolysis processes. Further reaction with acetic acid could effect dehydration of such "hydroxyacetates", to yield oxo-bridged acetates, Ln2O(OAc).

Physical Description

64 pages : illustration, tables

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Digitized from microopaque cards (3).

Contract no. AT(11-1)-67.

Includes bibliographical references (page 63-64).

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  • Report No.: AECU-3662
  • SuDoc Number: Y 3.At 7:22/AECU-3662
  • Accession or Local Control No: metadc1240379
  • Archival Resource Key: ark:/67531/metadc1240379

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  • October 31, 1957

Added to The UNT Digital Library

  • Nov. 5, 2023, 7:47 a.m.

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  • July 1, 2025, 3:20 p.m.

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Thumbnail image of item number 1 in: 'Behavior of Polyvalent Metallic Ions in 100% Acetic Acid Reactions of Rare Earth Compounds in Acetic Acid'.
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Audrieth, L. F.; Seaton, J. A. & Sherif, F. G. Behavior of Polyvalent Metallic Ions in 100% Acetic Acid Reactions of Rare Earth Compounds in Acetic Acid, report, October 31, 1957; Washington D.C.. (https://digital.library.unt.edu/ark:/67531/metadc1240379/: accessed June 16, 2026), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.

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