Energy transfer in anisotropic systems: A. Excitation migration in substitutionally disordered one-dimensional solids. B. The spectroscopy of molecules adsorbed on metal surfaces

PDF Version Also Available for Download.

Description

The energy and dynamics of excited states in a variety of anisotropic environments, including isotopically and chemically mixed crystals and molecular overlayers adsorbed on a nickel (111) surface, are investigated. The relationship between local and long-range structure and spectroscopic properties is explored. A theory for energy transfer in substitutionally disordered solids is presented. Explicit expressions for the ''diffusion'' coefficients and the energy partitioning ratios in binary systems are derived. Energy transfer between localized states is found to be facilitated by concurrent tunnelling and thermal promotion. Experimental results for triplet energy partitioning between mobile and stationary trap states as a function ... continued below

Creation Information

Zwemer, D.A. November 1, 1978.

Context

This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Author

Publisher

  • Lawrence Berkeley Laboratory
    Publisher Info: California Univ., Berkeley (USA). Lawrence Berkeley Lab.
    Place of Publication: Berkeley, California

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Description

The energy and dynamics of excited states in a variety of anisotropic environments, including isotopically and chemically mixed crystals and molecular overlayers adsorbed on a nickel (111) surface, are investigated. The relationship between local and long-range structure and spectroscopic properties is explored. A theory for energy transfer in substitutionally disordered solids is presented. Explicit expressions for the ''diffusion'' coefficients and the energy partitioning ratios in binary systems are derived. Energy transfer between localized states is found to be facilitated by concurrent tunnelling and thermal promotion. Experimental results for triplet energy partitioning between mobile and stationary trap states as a function of mobile trap concentration in the ternary d/sub 2/-1,2,4,5-tetrachlorobenzene--h/sub 2/-1,2,4,5-tetrachlorobenzene--pyrazine system are analyzed. It is shown that both tunnelling and thermal detrapping contribute to triplet exciton mobility below 4.2 K. Singlet exciton migration makes an important contribution to trap equilibration before intersystem crossing to the triplet manifold. Spin coherence experiments are used to determine the energy level structure, physical geometry, and exciton dynamics of a series of impurity-induced traps in 1,2,4,5-tetrachlorobenzene. The uv spectra of pyrazine, pyridine, and naphthalene adsorbed on a nickel single crystal (111) surface are measured by spectroscopic ellipsometry at low temperatures. The excited electronic and vibronic energy levels measured are similar to bulk molecular crystal values, but pyrazine and pyridine show small, but significant deviations. The ordering of molecular overlays is observed spectroscopically and information about overlayer crystal structure is deduced. 148 references, 48 figures, 5 tables.

Notes

Dep. NTIS, PC A11/MF A01.

Source

  • Other Information: Thesis. Portions of document are illegible

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Report No.: LBL-8332
  • Grant Number: W-7405-ENG-48
  • DOI: 10.2172/6500839 | External Link
  • Office of Scientific & Technical Information Report Number: 6500839
  • Archival Resource Key: ark:/67531/metadc1212547

Collections

This report is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this report?

When

Dates and time periods associated with this report.

Creation Date

  • November 1, 1978

Added to The UNT Digital Library

  • July 5, 2018, 11:11 p.m.

Description Last Updated

  • Oct. 29, 2018, 10:35 p.m.

Usage Statistics

When was this report last used?

Congratulations! It looks like you are the first person to view this item online.

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

International Image Interoperability Framework

IIF Logo

We support the IIIF Presentation API

Zwemer, D.A. Energy transfer in anisotropic systems: A. Excitation migration in substitutionally disordered one-dimensional solids. B. The spectroscopy of molecules adsorbed on metal surfaces, report, November 1, 1978; Berkeley, California. (digital.library.unt.edu/ark:/67531/metadc1212547/: accessed November 14, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.