Catalytic hydrocarbon reactions over supported metals Metadata

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Title

  • Main Title Catalytic hydrocarbon reactions over supported metals

Creator

  • Author: Ekerdt, J.G.
    Creator Type: Personal

Contributor

  • Sponsor: United States. Department of Energy.
    Contributor Type: Organization
    Contributor Info: DOE; USDOE, Washington, DC (United States)

Publisher

  • Name: Texas Univ., Austin, TX (United States)
    Place of Publication: United States

Date

  • Creation: 1993-03-29

Language

  • English

Description

  • Content Description: During the past year we have completed our characterization of the factors that control the structure of fully oxidized W and Mo on silica and have established that support hydroxyl groups play a central role in dispersing and attaching cations to the support oxide. Work with M[sub 2](CO)[sub 4]Cp[sub 2](M[sub 2]=MoMo, WW, MoW) system has been very encouraging and continues to support the notion that it may be possible to control the structure of adsorbed catalysts (in this case generate metal dimers) by use of organometallic precursors. Techniques are being developed necessary to employ XPS as a means to characterize the attachment process and the oxidation state of the cations after various thermal and photolytic reduction steps.
  • Physical Description: Pages: (3 p)

Subject

  • Keyword: Cycloalkenes
  • Keyword: Magnesium Oxides
  • Keyword: Catalytic Effects
  • Keyword: Organic Compounds
  • Keyword: Oxidation
  • Keyword: Progress Report
  • Keyword: Document Types
  • Keyword: Oxides
  • Keyword: Polyenes
  • Keyword: Chemical Reactions
  • Keyword: Tungsten Oxides
  • Keyword: Chalcogenides
  • Keyword: Transition Element Compounds
  • Keyword: Refractory Metal Compounds
  • Keyword: Molybdenum Oxides
  • Keyword: Electron Spectroscopy
  • Keyword: Spectroscopy
  • Keyword: Catalyst Supports
  • Keyword: Magnesium Compounds
  • Keyword: Hydrocarbons
  • Keyword: Photoelectron Spectroscopy
  • Keyword: Alkaline Earth Metal Compounds
  • Keyword: Dienes
  • Keyword: Silicon Oxides
  • Keyword: Silicon Compounds
  • Keyword: Carbonyls
  • Keyword: Alcohols
  • Keyword: Oxygen Compounds
  • Keyword: Hydroxy Compounds
  • STI Subject Categories: 37 Inorganic, Organic, Physical And Analytical Chemistry
  • Keyword: Molybdenum Compounds
  • Keyword: Cyclopentadiene
  • Keyword: Methanol
  • Keyword: Alkenes
  • Keyword: Tungsten Compounds 400201* -- Chemical & Physicochemical Properties

Collection

  • Name: Office of Scientific & Technical Information Technical Reports
    Code: OSTI

Institution

  • Name: UNT Libraries Government Documents Department
    Code: UNTGD

Resource Type

  • Report

Format

  • Text

Identifier

  • Other: DE93018168
  • Report No.: DOE/ER/13604-22
  • Grant Number: FG05-86ER13604
  • DOI: 10.2172/6347877
  • Office of Scientific & Technical Information Report Number: 6347877
  • Archival Resource Key: ark:/67531/metadc1207843

Note

  • Display Note: OSTI; NTIS; GPO Dep.