Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol

One of 74 reports in the series: AEC publication CONF available on this site.
Thumbnail image of item number 1 in: 'Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol'.
Thumbnail image of item number 2 in: 'Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol'.
Thumbnail image of item number 3 in: 'Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol'.
Thumbnail image of item number 4 in: 'Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol'.
Showing 1-4 of 9 pages in this report.

PDF Version Also Available for Download.

Description

Abstract. By means of the pulse radiolysis technique a short-lived transient species has been observed in irradiated de-aerated ethanol and methanol, exhibiting an optical absorption throughout the visible and near infra-red. This transient is suggested to be the solvated electron on the basis of the nature of the spectrum, the reactivity with hydrogen ion and with various organic electron acceptors, and the formation of mononegative ions of some of these acceptors. The absolute rate constants have been determined for the reactions of the solvated electron with hydrogen ion, oxygen and benzyl chloride in ethanol and methanol. The diphenylide ion was … continued below

Physical Description

9 pages : illustrations, charts, photographs.

Creation Information

Taub, Irwin A.; Sauer, Myran, C., Jr. & Dorfman, Leon M. June 10, 1963.

Context

This report is part of the collection entitled: Technical Report Archive and Image Library and was provided by the UNT Libraries Government Documents Department to the UNT Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 83 times. More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Authors

Sponsors

Publisher

Audiences

We've identified this report as a primary source within our collections. Researchers, educators, and students may find this report useful in their work.

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

About | Browse this Partner

Contact Us

Corrections Questions

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Titles

Description

Abstract. By means of the pulse radiolysis technique a short-lived transient species has been observed in irradiated de-aerated ethanol and methanol, exhibiting an optical absorption throughout the visible and near infra-red. This transient is suggested to be the solvated electron on the basis of the nature of the spectrum, the reactivity with hydrogen ion and with various organic electron acceptors, and the formation of mononegative ions of some of these acceptors. The absolute rate constants have been determined for the reactions of the solvated electron with hydrogen ion, oxygen and benzyl chloride in ethanol and methanol. The diphenylide ion was found to be short-lived in ethanol. The absolute rate constant for the first-order decay of the diphenylide ion has been determined.

Physical Description

9 pages : illustrations, charts, photographs.

Notes

Digitized from microopaque cards.

Subjects

Library of Congress Subject Headings

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Report No.: CONF-224-2
  • SuDoc Number: Y 3.At 7:22/CONF-224-2
  • Accession or Local Control No: metadc1201748
  • Archival Resource Key: ark:/67531/metadc1201748

Collections

This report is part of the following collections of related materials.

Technical Report Archive and Image Library

The Technical Report Archive & Image Library (TRAIL) identifies, acquires, catalogs, digitizes and provides unrestricted access to U.S. government agency technical reports. The mission of TRAIL is to ensure preservation, discoverability, and persistent open access to government technical publications regardless of form or format.

About | Browse this Collection

TRAIL Microcard Collection

Imaged from microcard, these technical reports describe research performed for U.S. government agencies from the 1930s to the 1960s. The reports were provided by the Technical Report Archive and Image Library (TRAIL).

About | Browse this Collection

What responsibilities do I have when using this report?

Digital Files

When

Dates and time periods associated with this report.

Creation Date

  • June 10, 1963

Added to The UNT Digital Library

  • Aug. 27, 2019, 3:53 p.m.

Description Last Updated

  • April 1, 2020, 4:06 p.m.

Usage Statistics

When was this report last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 83
More Statistics

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

Thumbnail image of item number 1 in: 'Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol'.
Thumbnail image of item number 2 in: 'Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol'.
Thumbnail image of item number 3 in: 'Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol'.
Thumbnail image of item number 4 in: 'Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol'.

PDF Version Also Available for Download.

Citations, Rights, Re-Use

International Image Interoperability Framework

IIF Logo

We support the IIIF Presentation API

Links for Robots

Helpful links in machine-readable formats.

Archival Resource Key (ARK)

International Image Interoperability Framework (IIIF)

Metadata Formats

Images

URLs

Stats

Taub, Irwin A.; Sauer, Myran, C., Jr. & Dorfman, Leon M. Pulse Radiolysis Studies of the Reactivity of the Solvated Electron in Ethanol and Methanol, report, June 10, 1963; Oak Ridge, Tennessee.. (https://digital.library.unt.edu/ark:/67531/metadc1201748/: accessed July 17, 2026), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.

Back to Top of Screen