Beta Radiation Processing at Rigorous Conditions

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Introduction: The literature reflects ever expansive studies of radiation chemistry over the past twenty years However, in the application of radiation processing to chemical reactions, in general and excepting a few isolated cases, the yield of useful products have been so low as to preclude practical utilization. Thus, for many reactions,radiation alone at ambient conditions is not a sufficient agent for economical production. Hence, we are led to the investigation of radiation effects on reactions at elevated temperatures and pressures where the thermodynamics favor more extensive reactions that may be induced by radiation. the probability of developing a successful practical … continued below

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12 pages ; illustrations.

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Yavorsky, P. M. & Gorin, E. November 15, 1963.

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Introduction: The literature reflects ever expansive studies of radiation chemistry over the past twenty years However, in the application of radiation processing to chemical reactions, in general and excepting a few isolated cases, the yield of useful products have been so low as to preclude practical utilization. Thus, for many reactions,radiation alone at ambient conditions is not a sufficient agent for economical production. Hence, we are led to the investigation of radiation effects on reactions at elevated temperatures and pressures where the thermodynamics favor more extensive reactions that may be induced by radiation. the probability of developing a successful practical radiation process is increased when applying radiation at rigorous conditions. To have a commercial advantage, a radiation process usually must replace an expensive catalyst system, generate a reaction at somewhat less rigorous conditions than is usually employed or yield a better or unique product of high value. In our investigations, we have examined only the potential of radiation as a replacement for contact catalyst. Results: We have worked with coal extract rather than coal because it can be melted or dissolved to facilitate pumping into the processing unit and, in general, permits easier handling than a solid. From numerous radiation runs with coat extract in the liquid phase, treated with 5000 psi of hydrogen pressure, temperatures up to 430 degree C, and total dose of up to 6 megarand, we have disappointingly but conclusively observed red that radiation does not induce hydrogenation beyond that obtain by thermal reaction alone.

Physical Description

12 pages ; illustrations.

Notes

Digitized from microopaque cards.

Work supported by the Division of Isotopes Development, U. S. Atomic Energy Commission, under Contract No. AT(30-1)-2978.

Includes bibliographical references (page 8).

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  • Report No.: CONF-187-77
  • Grant Number: AT(30-1)-2978
  • SuDoc Number: Y 3.At 7:22/CONF-187-77
  • Accession or Local Control No: metadc1201732
  • Archival Resource Key: ark:/67531/metadc1201732

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Technical Report Archive and Image Library

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Imaged from microcard, these technical reports describe research performed for U.S. government agencies from the 1930s to the 1960s. The reports were provided by the Technical Report Archive and Image Library (TRAIL).

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  • November 15, 1963

Added to The UNT Digital Library

  • Feb. 9, 2020, 2:12 p.m.

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  • June 24, 2024, 3:03 p.m.

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Yavorsky, P. M. & Gorin, E. Beta Radiation Processing at Rigorous Conditions, report, November 15, 1963; Oak Ridge, Tennessee. (https://digital.library.unt.edu/ark:/67531/metadc1201732/: accessed January 12, 2025), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.

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