Study of Metal-1.10-Phenanthroline Complex Equilibria by Potentiometric Measurement

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Description

Technical report. From Abstract : "The silver-1,10-phenanthroline system has been studied and the stability constants determined for the 1:1 and 2:1 complexes using the silver electrode. This known system was then used to study the complexes of 1,10-phenanthroline with other metals. The log βn values found for the over-all stoichiometric stability constants are as follows: Ag, 5.02, 12.07; Mn, 3.88, 7.04, 10.11; Cd, 5.93, 10.52, 14.30; Zn, 6.83, 12.05, 16.92. The stoichiometric stability constants determined for copper are log k2 = 6.42 and log k2k3 = 11.05."

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15 pages : illustrations.

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Dale, John M. & Banks, Charles V. October 25, 1962.

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Description

Technical report. From Abstract : "The silver-1,10-phenanthroline system has been studied and the stability constants determined for the 1:1 and 2:1 complexes using the silver electrode. This known system was then used to study the complexes of 1,10-phenanthroline with other metals. The log βn values found for the over-all stoichiometric stability constants are as follows: Ag, 5.02, 12.07; Mn, 3.88, 7.04, 10.11; Cd, 5.93, 10.52, 14.30; Zn, 6.83, 12.05, 16.92. The stoichiometric stability constants determined for copper are log k2 = 6.42 and log k2k3 = 11.05."

Physical Description

15 pages : illustrations.

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Digitized from microopaque cards.

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"Contribution No. 1245 from the Institute for Atomic Research and Department of Chemistry, Iowa State University, Ames, Iowa. Work was performed in the Ames Laboratory of the U.S. Atomic Energy Commission."

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  • Report No.: IS-568
  • Accession or Local Control No: metadc1201556
  • SuDoc Number: Y 3.At 7:22/IS-568
  • Grant Number: Contract [W-7U05-ENG-82]
  • Archival Resource Key: ark:/67531/metadc1201556

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Creation Date

  • October 25, 1962

Added to The UNT Digital Library

  • Aug. 27, 2019, 3:53 p.m.

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  • Nov. 21, 2019, 2:41 p.m.

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Dale, John M. & Banks, Charles V. Study of Metal-1.10-Phenanthroline Complex Equilibria by Potentiometric Measurement, report, October 25, 1962; Ames, Iowa. (https://digital.library.unt.edu/ark:/67531/metadc1201556/: accessed October 10, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.

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