The Standard Molar Free Energy of Formation of MgCl2, CeCl3, ThCl4, and UCl3 Obtained by Solid State EMF Techniques

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Technical report about a study in the use of galvanic cells using solid electrolytes to obtain thermodynamic data at high temperatures to study the free energy of formation of chlorides using Daniell cells where all components are solid. "The experimental techniques used are presented, including cell construction, preparation of anhydrous materials, and the handling of reactive metals and hydroscopic materials for galvanic cells." from the abstract. Results are presented for magnesium chloride, cerium chloride, uranium chloride, and thorium chloride, and are compared with other available data.

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19 pages.

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Egan, J. J.; McCoy, W. & Bracker, J. June 19, 1962.

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Technical report about a study in the use of galvanic cells using solid electrolytes to obtain thermodynamic data at high temperatures to study the free energy of formation of chlorides using Daniell cells where all components are solid. "The experimental techniques used are presented, including cell construction, preparation of anhydrous materials, and the handling of reactive metals and hydroscopic materials for galvanic cells." from the abstract. Results are presented for magnesium chloride, cerium chloride, uranium chloride, and thorium chloride, and are compared with other available data.

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19 pages.

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Digitized from microopaque cards.

Includes bibliographic references (pages 12-13).

The work presented in this paper was done under the auspices of the U.S.Atomic Energy Commission, Washington, D.C.

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  • Report No.: BNL 6059
  • Accession or Local Control No: metadc1201094
  • SuDoc Number: Y 3.At 7:22/BNL-6059
  • Archival Resource Key: ark:/67531/metadc1201094

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  • June 19, 1962

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  • April 8, 2019, 4 p.m.

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  • June 26, 2020, 5:27 p.m.

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Egan, J. J.; McCoy, W. & Bracker, J. The Standard Molar Free Energy of Formation of MgCl2, CeCl3, ThCl4, and UCl3 Obtained by Solid State EMF Techniques, report, June 19, 1962; Upton, New York. (https://digital.library.unt.edu/ark:/67531/metadc1201094/: accessed October 6, 2026), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.

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