Molecular and supramolecular orientation in conducting polymers

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Intrinsic anisotropy in electrical and optical properties of conducting polymers constitutes a unique aspect that derives ..pi..-electron delocalization along the polymer backbone and from the weak inter-chain interaction. To acquire such an intrinsic property, conducting polymers have to be oriented macroscopically and microscopically (at the chain level). A review of the various techniques, including stretch-alignment of the polymer and of precursor polymers, polymerization in ordered media, i.e., in a liquid crystal solvent, and synthesis of liquid crystalline conducting polymers will be given. 29 refs.

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13 pages

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Aldissi, M. January 1, 1987.

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Description

Intrinsic anisotropy in electrical and optical properties of conducting polymers constitutes a unique aspect that derives ..pi..-electron delocalization along the polymer backbone and from the weak inter-chain interaction. To acquire such an intrinsic property, conducting polymers have to be oriented macroscopically and microscopically (at the chain level). A review of the various techniques, including stretch-alignment of the polymer and of precursor polymers, polymerization in ordered media, i.e., in a liquid crystal solvent, and synthesis of liquid crystalline conducting polymers will be given. 29 refs.

Physical Description

13 pages

Notes

NTIS, PC A02/MF A01; 1.

Source

  • International symposium on polymers for advanced technologies, Jerusalem, Israel, 16 Aug 1987

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  • Other: DE88000533
  • Report No.: LA-UR-87-3027
  • Report No.: CONF-8708139-1
  • Grant Number: W-7405-ENG-36
  • Office of Scientific & Technical Information Report Number: 5921955
  • Archival Resource Key: ark:/67531/metadc1101169

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Office of Scientific & Technical Information Technical Reports

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Creation Date

  • January 1, 1987

Added to The UNT Digital Library

  • Feb. 18, 2018, 3:59 p.m.

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  • June 27, 2019, 12:44 p.m.

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Aldissi, M. Molecular and supramolecular orientation in conducting polymers, article, January 1, 1987; New Mexico. (https://digital.library.unt.edu/ark:/67531/metadc1101169/: accessed September 22, 2019), University of North Texas Libraries, Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.