Dynamic structural effects and ultrafast biomolecular kinetics in photoinduced charge transfer reactions

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During the first budget significant progress was made in three areas: (1) assessment of dynamic structural effects accompanying charge transfer, (2) electrochemical assessment of site-to-site electronic coupling in simple inorganic systems, and (3) direct observation of intramolecular electron transfer kinetics in mixed-valence systems. In area 1 the most significant finding was that Franck-Condon parameters for electron transfer (i.e. normal coordinate displacements, vibrational frequencies, and single-mode vibrational reorganizational energy components) could be obtained for weakly interacting (ion-paired) redox systems (J.Phys.Chem., 1991, 95, 10535). Studies in area 3 have yielded results in both the ultrafast (femtosecond/picosecond) time regime (J.Phys.Chem. 1991, 95, 5712) ... continued below

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Pages: (6 p)

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Hupp, J.T. January 1, 1992.

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Description

During the first budget significant progress was made in three areas: (1) assessment of dynamic structural effects accompanying charge transfer, (2) electrochemical assessment of site-to-site electronic coupling in simple inorganic systems, and (3) direct observation of intramolecular electron transfer kinetics in mixed-valence systems. In area 1 the most significant finding was that Franck-Condon parameters for electron transfer (i.e. normal coordinate displacements, vibrational frequencies, and single-mode vibrational reorganizational energy components) could be obtained for weakly interacting (ion-paired) redox systems (J.Phys.Chem., 1991, 95, 10535). Studies in area 3 have yielded results in both the ultrafast (femtosecond/picosecond) time regime (J.Phys.Chem. 1991, 95, 5712) and the intermediate (microsecond/millisecond) time regime (J.Am.Chem. Soc., submitted).

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Pages: (6 p)

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OSTI; NTIS; GPO Dep.

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  • Other: DE92007562
  • Report No.: DOE/ER/13808-4
  • Grant Number: FG02-87ER13808
  • DOI: 10.2172/5714156 | External Link
  • Office of Scientific & Technical Information Report Number: 5714156
  • Archival Resource Key: ark:/67531/metadc1093408

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  • January 1, 1992

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  • Feb. 10, 2018, 10:06 p.m.

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  • Feb. 26, 2018, 12:16 p.m.

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Hupp, J.T. Dynamic structural effects and ultrafast biomolecular kinetics in photoinduced charge transfer reactions, report, January 1, 1992; United States. (digital.library.unt.edu/ark:/67531/metadc1093408/: accessed December 9, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.