Investigations on SYNROC mineralogy. Progress report

PDF Version Also Available for Download.

Description

Progress reports are presented for the following projects: (1) factors influencing the leaching performance of hollandiate; (2) incorporation of uranium and rare earths into zirconolite; (3) reconnaissance studies of the stability relations of Ca-Ti-Al phases in SYNROC C formulations; (4) immobilization of highly aluminous sludges; (5) SYNROC D formulations produced by sintering in air; (6) crystallization behavior of interstitial glass in SYNROC D formulations. Some of the highlights are: (1) leaching performance of all hollandites irrespective of preparation technique, can be improved by hot-pressing under specific controlled redox conditions, below Ni-NiO; (2) there is no satisfactory crystal-chemical reason why the ... continued below

Physical Description

Pages: 97

Creation Information

Ringwood, A.E. January 21, 1982.

Context

This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Publisher

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Description

Progress reports are presented for the following projects: (1) factors influencing the leaching performance of hollandiate; (2) incorporation of uranium and rare earths into zirconolite; (3) reconnaissance studies of the stability relations of Ca-Ti-Al phases in SYNROC C formulations; (4) immobilization of highly aluminous sludges; (5) SYNROC D formulations produced by sintering in air; (6) crystallization behavior of interstitial glass in SYNROC D formulations. Some of the highlights are: (1) leaching performance of all hollandites irrespective of preparation technique, can be improved by hot-pressing under specific controlled redox conditions, below Ni-NiO; (2) there is no satisfactory crystal-chemical reason why the leaching performance of Ti/sup 3 +/-bearing hollandite should be superior to that of Al/sup 3 +/ hollandite; (3) experiments have shown that the zirconolite lattice can accept up to 30% rare earths (Sm/sub 2/O/sub 3/) before becoming destabilized in favor of pyrochlore or a related f.c.c. structure; (4) SYNROC zirconolites will therefore be well below their saturation limits in rare earths and trivalent actinides; (5) experiments have established that the Ca-Ti-Al phase (CTA) is compatible with perovskite, hollandite and zirconolite; (6) magnetoplumbite-type phases coexists with hollandite, perovskite, zirconolite and Fe-bearing pseudobrookite, but do not coexist with the CTA phase CaTi/sub 3/Al/sub 8/O/sub 19/; (7) experiments demonstrated that it is not possible to convert highly aluminous sludges to a waste form comprising zirconolite, perovskite, spinel and nepheline plus corundum, by adding appropriate minimum amounts of the inert SYNROC additives (CaO, TiO/sub 2/, ZrO/sub 2/, SiO/sub 2/); (8) sintering of SYNROC D in air at temperatures just above the solidus (1200 to 1250/sup 0/C) produced a dense compact ceramic, but the optimum SYNROC-D mineralogy was not produced. (ATT)

Physical Description

Pages: 97

Notes

NTIS, PC A05/MF A01.

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Other: DE82011072
  • Report No.: UCRL-15436
  • Grant Number: W-7405-ENG-48
  • DOI: 10.2172/5516706 | External Link
  • Office of Scientific & Technical Information Report Number: 5516706
  • Archival Resource Key: ark:/67531/metadc1091870

Collections

This report is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this report?

When

Dates and time periods associated with this report.

Creation Date

  • January 21, 1982

Added to The UNT Digital Library

  • Feb. 10, 2018, 10:06 p.m.

Description Last Updated

  • April 26, 2018, 6:45 p.m.

Usage Statistics

When was this report last used?

Yesterday: 0
Past 30 days: 1
Total Uses: 3

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

International Image Interoperability Framework

IIF Logo

We support the IIIF Presentation API

Ringwood, A.E. Investigations on SYNROC mineralogy. Progress report, report, January 21, 1982; [Livermore,] California. (https://digital.library.unt.edu/ark:/67531/metadc1091870/: accessed March 22, 2019), University of North Texas Libraries, Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.