Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin

Thumbnail image of item number 1 in: 'Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin'.
Thumbnail image of item number 2 in: 'Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin'.
Thumbnail image of item number 3 in: 'Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin'.
Thumbnail image of item number 4 in: 'Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin'.
Showing 1-4 of 36 pages in this document.

PDF Version Also Available for Download.

Description

A chelating ion-exchange resin with N-(2-hydroxyethyl)ethylene-diaminetriacetic acid (HEDTA) used as the ligand chemically bonded to XAD-4 by an ester linkage, HEDTA-4, was synthesized. It is stable under normal experimental conditions with the liquid chromatograph. The structure of the resin was confirmed by an infrared spectrum, and by potentiometric titrations. The capacity of the resin was also obtained by potentiometric titration and by a nitrogen analysis. The resin was used to pack a column of 5 mm internal diameter and 5 cm long. The effect of pH on the retention of different metal ions on the resin was studied. It was … continued below

Physical Description

34 pages

Creation Information

Lai, Y. F. October 1, 1977.

Context

This thesis or dissertation is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by the UNT Libraries Government Documents Department to the UNT Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 116 times. More information about this document can be viewed below.

Who

People and organizations associated with either the creation of this thesis or dissertation or its content.

Author

Sponsor

Publisher

  • Ames Laboratory
    Publisher Info: Ames Lab., Iowa (USA)
    Place of Publication: Iowa

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

About | Browse this Partner

Contact Us

Corrections Questions

What

Descriptive information to help identify this thesis or dissertation. Follow the links below to find similar items on the Digital Library.

Description

A chelating ion-exchange resin with N-(2-hydroxyethyl)ethylene-diaminetriacetic acid (HEDTA) used as the ligand chemically bonded to XAD-4 by an ester linkage, HEDTA-4, was synthesized. It is stable under normal experimental conditions with the liquid chromatograph. The structure of the resin was confirmed by an infrared spectrum, and by potentiometric titrations. The capacity of the resin was also obtained by potentiometric titration and by a nitrogen analysis. The resin was used to pack a column of 5 mm internal diameter and 5 cm long. The effect of pH on the retention of different metal ions on the resin was studied. It was found that the resin was most selective for chromium(III), copper(II), lead(II), mercury(II), uranium(VI), zirconium(IV) and zinc(II) at a pH of less than 3. Furthermore, the resin proves to be functioning with a chelating mechanism rather than ion-exchange, and it can concentrate trace metal ions in the presence of a large excess of calcium and magnesium. This makes the resin potentially useful for purifying and analyzing drinking water.

Physical Description

34 pages

Notes

Dep. NTIS, PC A03/MF A01.

Source

  • Other Information: Thesis

Language

Item Type

Identifier

Unique identifying numbers for this document in the Digital Library or other systems.

Collections

This document is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

About | Browse this Collection

What responsibilities do I have when using this thesis or dissertation?

Digital Files

When

Dates and time periods associated with this thesis or dissertation.

Creation Date

  • October 1, 1977

Added to The UNT Digital Library

  • Feb. 4, 2018, 10:51 a.m.

Description Last Updated

  • Feb. 12, 2021, 9:37 p.m.

Usage Statistics

When was this document last used?

Yesterday: 0
Past 30 days: 1
Total Uses: 116
More Statistics

Interact With This Thesis Or Dissertation

Here are some suggestions for what to do next.

Start Reading

Thumbnail image of item number 1 in: 'Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin'.
Thumbnail image of item number 2 in: 'Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin'.
Thumbnail image of item number 3 in: 'Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin'.
Thumbnail image of item number 4 in: 'Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin'.

PDF Version Also Available for Download.

Citations, Rights, Re-Use

International Image Interoperability Framework

IIF Logo

We support the IIIF Presentation API

Links for Robots

Helpful links in machine-readable formats.

Archival Resource Key (ARK)

International Image Interoperability Framework (IIIF)

Metadata Formats

Images

URLs

Stats

Lai, Y. F. Synthesis and characterization of an N-(2-hydroxyethyl)-ethylenediaminetriacetic acid resin, thesis or dissertation, October 1, 1977; Iowa. (https://digital.library.unt.edu/ark:/67531/metadc1069597/: accessed April 19, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.

Back to Top of Screen