The basic objectives of this program were the determination of the thermal stability of various fission product oxides and nitrates, and an investigation of the gas phase decomposition of ruthenium tetroxide. To accomplish these objectives, a literature survey was flrst made of available physical and chemical data for the oxides and nitrates of Cs, Sr, Ru, Zr, Nb, and Ce. The data were supplemented by a calculation of thermodynamic functions for RuO/sub 4/ vapor from the experimentally determined infrared spectrum and the theoretically calculated raman-active fundamentals. Data are presented graphically. (C.H.)
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The basic objectives of this program were the determination of the thermal stability of various fission product oxides and nitrates, and an investigation of the gas phase decomposition of ruthenium tetroxide. To accomplish these objectives, a literature survey was flrst made of available physical and chemical data for the oxides and nitrates of Cs, Sr, Ru, Zr, Nb, and Ce. The data were supplemented by a calculation of thermodynamic functions for RuO/sub 4/ vapor from the experimentally determined infrared spectrum and the theoretically calculated raman-active fundamentals. Data are presented graphically. (C.H.)
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Ortner, M. H.; Anderson, C. J. & Campbell, P. F.Research and Development Studies on Waste Storage Process,
report,
May 19, 1961;
West Orange, New Jersey.
(https://digital.library.unt.edu/ark:/67531/metadc1059924/:
accessed December 11, 2024),
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crediting UNT Libraries Government Documents Department.