Methane oxidation over dual redox catalysts

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Review and analysis of the literature data on electron transfer itself and electron transfer oxidation of alkyl radicals was done in order to understand the mechanism by which methyl radical can be oxidized to CH{sub 3}{sup +} and further substituted by OH{sup {minus}} to form methanol. This allowed to compare and classify the various possible reaction patterns, understand the mechanism and circumstances of operation of each of them and select those which can be involved in oxidation of methyl radical. As a result an approach that is complementary to catalytic test studies was proposed. It consists of investigation of a ... continued below

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Pages: (8 p)

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Klier, K.; Herman, R.G. & Sojka, Z. March 1, 1989.

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Description

Review and analysis of the literature data on electron transfer itself and electron transfer oxidation of alkyl radicals was done in order to understand the mechanism by which methyl radical can be oxidized to CH{sub 3}{sup +} and further substituted by OH{sup {minus}} to form methanol. This allowed to compare and classify the various possible reaction patterns, understand the mechanism and circumstances of operation of each of them and select those which can be involved in oxidation of methyl radical. As a result an approach that is complementary to catalytic test studies was proposed. It consists of investigation of a set of partial reactions which reproduce a whole catalytic cycle in order to prove the reaction mechanism. Synthesis of new oxide catalysts of the delafossite type, containing concentrated double redox sites, were designed. Synthesis of hydrozincite as a starting material for the preparation of doubly doped zinc oxide was performed.

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Pages: (8 p)

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OSTI; NTIS; GPO Dep.

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  • Other: DE92017580
  • Report No.: DOE/MC/26039-1
  • Grant Number: FG21-89MC26039
  • DOI: 10.2172/5100260 | External Link
  • Office of Scientific & Technical Information Report Number: 5100260
  • Archival Resource Key: ark:/67531/metadc1055360

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Office of Scientific & Technical Information Technical Reports

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  • March 1, 1989

Added to The UNT Digital Library

  • Jan. 22, 2018, 7:23 a.m.

Description Last Updated

  • Jan. 26, 2018, 5:58 p.m.

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Klier, K.; Herman, R.G. & Sojka, Z. Methane oxidation over dual redox catalysts, report, March 1, 1989; United States. (digital.library.unt.edu/ark:/67531/metadc1055360/: accessed July 18, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.