Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction

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Description

The purpose of this report is to update and reorganize our recent review on homogeneous catalysis of the water-gas shift reaction (WGSR) based on recent literature publications and patents. This updated version will serve as a means of selecting 10 candidate catalyst systems for use in developing effective, sulfur-tolerant, low temperature WGSR catalysts. This report discusses the variations possible in the basic chemistry associated with WGSR catalytic cycles, including basic, acidic, and neutral conditions. Then individual mechanism for specific WGSR catalyst systems are discussed. Finally, on the basis of the literature reports, a list is presented of candidate catalysts and ... continued below

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Pages: (52 p)

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Laine, R.M. January 20, 1986.

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This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 13 times , with 5 in the last month . More information about this report can be viewed below.

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Description

The purpose of this report is to update and reorganize our recent review on homogeneous catalysis of the water-gas shift reaction (WGSR) based on recent literature publications and patents. This updated version will serve as a means of selecting 10 candidate catalyst systems for use in developing effective, sulfur-tolerant, low temperature WGSR catalysts. This report discusses the variations possible in the basic chemistry associated with WGSR catalytic cycles, including basic, acidic, and neutral conditions. Then individual mechanism for specific WGSR catalyst systems are discussed. Finally, on the basis of the literature reports, a list is presented of candidate catalysts and basic systems we have chosen for study in Task 3.

Physical Description

Pages: (52 p)

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OSTI; NTIS; GPO Dep.

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  • Other: DE92017717
  • Report No.: DOE/MC/22065-T16
  • Grant Number: AC21-85MC22065
  • DOI: 10.2172/5128236 | External Link
  • Office of Scientific & Technical Information Report Number: 5128236
  • Archival Resource Key: ark:/67531/metadc1054471

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Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

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Creation Date

  • January 20, 1986

Added to The UNT Digital Library

  • Jan. 22, 2018, 7:23 a.m.

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  • Jan. 26, 2018, 5:50 p.m.

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Laine, R.M. Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction, report, January 20, 1986; United States. (digital.library.unt.edu/ark:/67531/metadc1054471/: accessed September 21, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.