Solvent Extraction Recovery of Vanadium (and Uranium) From Acid Liquors With Di(2-Ethylhexyl) Phosphoric Acid

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Bench-scale studies were made on use of di(2ethylhexyl)-phosphoric acid in an organic diluent (Dapex process) for solvent extraction recovery of vanadium from acid leach liquors. Vanadium may be stripped from the solvent by either acidic or alkaline reagents, the former having been studied in considerably greater detail. A process for single-cycle recovery and separation of uranium and vanadium from sulfate leach liquors was shown to be attractive both from the standpoint of operation and chemical costs. Process schemes for recovery of vanadium from uranium-barren liquors are also described. On the basis of the encouraging laboratory results, pilot scale tests for … continued below

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81 pages

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Crouse, D.J. & Brown, K.B. November 25, 1959.

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Bench-scale studies were made on use of di(2ethylhexyl)-phosphoric acid in an organic diluent (Dapex process) for solvent extraction recovery of vanadium from acid leach liquors. Vanadium may be stripped from the solvent by either acidic or alkaline reagents, the former having been studied in considerably greater detail. A process for single-cycle recovery and separation of uranium and vanadium from sulfate leach liquors was shown to be attractive both from the standpoint of operation and chemical costs. Process schemes for recovery of vanadium from uranium-barren liquors are also described. On the basis of the encouraging laboratory results, pilot scale tests for specific applications are recommended. (auth)

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81 pages

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Other Information: Orig. Receipt Date: 31-DEC-60

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  • November 25, 1959

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Crouse, D.J. & Brown, K.B. Solvent Extraction Recovery of Vanadium (and Uranium) From Acid Liquors With Di(2-Ethylhexyl) Phosphoric Acid, report, November 25, 1959; Oak Ridge, Tennessee. (https://digital.library.unt.edu/ark:/67531/metadc1021301/: accessed June 22, 2025), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.

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