Steering the Self-Assembly of Octadecylamine Monolayers on Mica by Controlled Mechanical Energy Transfer from the AFM Tip

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We have studied the effect of mechanical energy transfer from the tip of an Atomic Force Microscope on the dynamics of self-assembly of monolayer films of octadecylamine on mica. The formation of the self-assembled film proceeds in two successive stages, the first being a fast adsorption from solution that follows a Langmuir isotherm. The second is a slower process of island growth by aggregation of the molecules dispersed on the surface. We found that the dynamics of aggregation can be altered substantially by the addition of mechanical energy into the system through controlled tip-surface interactions. This leads to either the ... continued below

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Benitez, J.J.; Heredia-Guerrero, J.A. & Salmeron, M. June 24, 2010.

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We have studied the effect of mechanical energy transfer from the tip of an Atomic Force Microscope on the dynamics of self-assembly of monolayer films of octadecylamine on mica. The formation of the self-assembled film proceeds in two successive stages, the first being a fast adsorption from solution that follows a Langmuir isotherm. The second is a slower process of island growth by aggregation of the molecules dispersed on the surface. We found that the dynamics of aggregation can be altered substantially by the addition of mechanical energy into the system through controlled tip-surface interactions. This leads to either the creation of pinholes in existing islands as a consequence of vacancy concentration, and to the assembly of residual molecules into more compact islands.

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12630

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  • Journal Name: Journal of Physical Chemistry C; Journal Volume: 114; Journal Issue: 29

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  • Report No.: LBNL-3639E
  • Grant Number: DE-AC02-05CH11231
  • DOI: 10.1021/jp102813s | External Link
  • Office of Scientific & Technical Information Report Number: 985243
  • Archival Resource Key: ark:/67531/metadc1014477

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  • June 24, 2010

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  • Oct. 14, 2017, 8:36 a.m.

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  • Oct. 18, 2017, 10:13 a.m.

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Benitez, J.J.; Heredia-Guerrero, J.A. & Salmeron, M. Steering the Self-Assembly of Octadecylamine Monolayers on Mica by Controlled Mechanical Energy Transfer from the AFM Tip, article, June 24, 2010; Berkeley, California. (digital.library.unt.edu/ark:/67531/metadc1014477/: accessed December 10, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.