Predicting Solubility of Anthracene in Non-aqueous Solvent Mixtures Using a Combination of Jouyban-Acree and Abraham Models

Predicting Solubility of Anthracene in Non-aqueous Solvent Mixtures Using a Combination of Jouyban-Acree and Abraham Models

Date: August 1, 2006
Creator: Jouyban, Abolghasem; Khoubnasabjafari, Maryam & Acree, William E. (William Eugene)
Description: Article on predicting the solubility of anthracene in non-aqueous solvent mixtures using a combination of Jouyban-Acree and Abraham models.
Contributing Partner: UNT College of Arts and Sciences
Chemical Equilibria in Binary Solvents

Chemical Equilibria in Binary Solvents

Date: August 1997
Creator: McHale, Mary E. R.
Description: Dissertation research involves development of Mobile Order Theory thermodynamic models to mathematically describe and predict the solubility, spectral properties, protonation equilibrium constants and two-phase partitioning behavior of solutes dissolved in binary solvent mixtures of analytical importance. Information gained provide a better understanding of solute-solvent and solvent-solvent interactions at the molecular level, which will facilitate the development of better chemical separation methods based upon both gas-liquid and high-performance liquid chromatography, and better analysis methods based upon complexiometric and spectroscopic methods. Dissertation research emphasizes chemical equilibria in systems containing alcohol cosolvents with the understanding that knowledge gained will be transferable to more environmentally friendly aqueous-organic solvent mixtures.
Contributing Partner: UNT Libraries
IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 1. Binary Solvent Mixtures

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 1. Binary Solvent Mixtures

Date: February 28, 2013
Creator: Acree, William E. (William Eugene)
Description: Article on the solubility of polycyclic aromatic hydrocarbons in pure and organic solvent mixtures. This work updates volumes 54, 58, and 59 in the IUPAC Solubility Data Series and presents solubility data for polycyclic aromatic hydrocarbon solutes dissolved in binary organic solvent mixtures.
Contributing Partner: UNT College of Arts and Sciences
IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 2. Ternary Solvent Mixtures

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 2. Ternary Solvent Mixtures

Date: February 28, 2013
Creator: Acree, William E. (William Eugene)
Description: Article on the solubility of polycyclic aromatic hydrocarbons in pure and organic solvent mixtures. This work updates volumes 54, 58, and 59 in the IUPAC Solubility Data Series and presents solubility data for polycyclic aromatic hydrocarbon solutes dissolved in ternary organic solvent mixtures.
Contributing Partner: UNT College of Arts and Sciences
Thermochemical Investigations of Nearly Ideal Binary Solvents. 3. Solubility in Systems of Nonspecific Interactions

Thermochemical Investigations of Nearly Ideal Binary Solvents. 3. Solubility in Systems of Nonspecific Interactions

Date: June 1977
Creator: Acree, William E. (William Eugene) & Bertrand, Gary L.
Description: Article on thermochemical investigations of nearly ideal binary solvents and the solubility in systems of nonspecific interactions.
Contributing Partner: UNT College of Arts and Sciences
IUPAC-NIST Solubility Data Series. 99. Solubility of Benzoic Acid and Substituted Benzoic Acids in Both Neat Organic Solvents and Organic Solvent Mixtures.

IUPAC-NIST Solubility Data Series. 99. Solubility of Benzoic Acid and Substituted Benzoic Acids in Both Neat Organic Solvents and Organic Solvent Mixtures.

Date: May 15, 2013
Creator: Acree, William E. (William Eugene)
Description: Article on the solubility of benzoic acid and substituted benzoic acids in both neat organic solvents and organic solvent mixtures.
Contributing Partner: UNT College of Arts and Sciences
Descriptors for Artemisinin and its Derivatives; Estimation of Physicochemical and Biochemical Data

Descriptors for Artemisinin and its Derivatives; Estimation of Physicochemical and Biochemical Data

Date: 2013
Creator: Abraham, M. H. (Michael H.) & Acree, William E. (William Eugene)
Description: Article on descriptors for artemisinin and its derivatives and an estimation of physiochemical and biochemical data.
Contributing Partner: UNT College of Arts and Sciences
Thermochemical Study of Crystalline Solutes Dissolved in Ternary Hydrogen-Bonding Solvent Mixtures

Thermochemical Study of Crystalline Solutes Dissolved in Ternary Hydrogen-Bonding Solvent Mixtures

Date: May 2001
Creator: Pribyla, Karen J.
Description: The purpose of this dissertation is to investigate the thermochemical properties of nonelectrolyte solutes dissolved in ternary solvent mixtures, and to develop mathematical expressions for predicting and describing behavior in the solvent mixtures. Forty-five ternary solvent systems were studied containing an ether (Methyl tert-butyl ether, Dibutyl ether, or 1,4-Dioxane), an alcohol (1-Propanol, 2-Propanol, 1-Butanol, 2-Butanol, or 2-Methyl-1-propanol), and an alkane (Cyclohexane, Heptane, or 2,2,4-Trimethylpentane) cosolvents. The Combined NIBS (Nearly Ideal Binary Solvent)/Redlich-Kister equation was used to assess the experimental data. The average percent deviation between predicted and observed values was less than ± 2 per cent error, documenting that this model provides a fairly accurate description of the observed solubility behavior. In addition, Mobile Order theory, the Kretschmer-Wiebe model, and the Mecke-Kempter model were extended to ternary solvent mixtures containing an alcohol (or an alkoxyalcohol) and alkane cosolvents. Expressions derived from Mobile Order theory predicted the experimental mole fraction solubility of anthracene in ternary alcohol + alkane + alkane mixtures to within ± 5.8%, in ternary alcohol + alcohol + alkane mixtures to within ± 4.0%, and in ternary alcohol + alcohol + alcohol mixtures to within ± 3.6%. In comparison, expressions derived from the Kretschmer-Wiebe model and the Mecke-Kempter ...
Contributing Partner: UNT Libraries
Solubility of Pioglitazone Hydrochloride in Aqueous Solutions of Ethanol, Propylene Glycol, and N-Methyl-2-Pyrrolidone at 298.2°K

Solubility of Pioglitazone Hydrochloride in Aqueous Solutions of Ethanol, Propylene Glycol, and N-Methyl-2-Pyrrolidone at 298.2°K

Date: December 2009
Creator: Soltanpour, Shahla; Acree, William E. (William Eugene) & Jouyban, Abolghasem
Description: Article on the solubility of pioglitazone hydrochloride in aqueous solutions of ethanol, propylene glycol, and n-methyl-2-pyrrolidone at 298°K.
Contributing Partner: UNT College of Arts and Sciences
Thermodynamics of Mobile Order Theory: Solubility and Partition Aspects

Thermodynamics of Mobile Order Theory: Solubility and Partition Aspects

Date: August 2004
Creator: De Fina, Karina M.
Description: The purpose of this thesis is to analyze the thermochemical properties of solutes in nonelectrolyte pure solvents and to develop mathematical expressions with the ability to describe and predict solution behavior using mobile order theory. Solubilities of pesticides (monuron, diuron, and hexachlorobenzene), polycyclic aromatic hydrocarbons (biphenyl, acenaphthene, and phenanthrene), and the organometallic ferrocene were studied in a wide array of solvents. Mobile order theory predictive equations were derived and percent average absolute deviations between experimental and calculated mole fraction solubilities for each solute were as follows: monuron in 21 non-alcoholic solvents (48.4%), diuron in 28 non-alcoholic solvents (60.1%), hexachlorobenzene (210%), biphenyl (13.0%), acenaphthene (37.8%), phenanthrene (41.3%), and ferrocene (107.8%). Solute descriptors using the Abraham solvation model were also calculated for monuron and diuron. Coefficients in the general solvation equation were known for all the solvents and solute descriptors calculated using multilinear regression techniques.
Contributing Partner: UNT Libraries
Thermodynamics of the Abraham General Solvation Model: Solubility and Partition Aspects

Thermodynamics of the Abraham General Solvation Model: Solubility and Partition Aspects

Date: August 2006
Creator: Stovall, Dawn Michele
Description: Experimental mole fraction solubilities of several carboxylic acids (2-methoxybenzoic acid, 4-methoxybenzoic acid, 4-nitrobenzoic acid, 4-chloro-3-nitrobenzoic acid, 2-chloro-5-nitrobenzoic acid,2-methylbenzoic acid and ibuprofen) and 9-fluorenone, thianthrene and xanthene were measured in a wide range of solvents of varying polarity and hydrogen-bonding characteristics. Results of these measurements were used to calculate gas-to-organic solvent and water-to-organic solvent solubility ratios, which were then substituted into known Abraham process partitioning correlations. The molecular solute descriptors that were obtained as the result of these computations described the measured solubility data to within an average absolute deviation of 0.2 log units. The calculated solute descriptors also enable one to estimate many chemically, biologically and pharmaceutically important properties for the ten solutes studied using published mathematical correlations.
Contributing Partner: UNT Libraries
IUPAC-NIST Solubility Data Series. 102. Solubility of Nonsteroidal Anti-inflammatory Drugs (NSAIDs) in Neat Organic Solvents and Organic Solvent Mixtures

IUPAC-NIST Solubility Data Series. 102. Solubility of Nonsteroidal Anti-inflammatory Drugs (NSAIDs) in Neat Organic Solvents and Organic Solvent Mixtures

Date: April 25, 2014
Creator: Acree, William E. (William Eugene)
Description: Article on the solubility of nonsteroidal anti-inflammatory drugs (NSAIDs) in neat organic solvents and organic solvent mixtures.
Contributing Partner: UNT College of Arts and Sciences
A Unified Cosolvency Model for Calculating Solute Solubility in Mixed Solvents

A Unified Cosolvency Model for Calculating Solute Solubility in Mixed Solvents

Date: June 2005
Creator: Jouyban, Abolghasem; Chew, Nora Yat Knork; Chan, Hak-Kim; Sabour, Mohammad & Acree, William E. (William Eugene)
Description: Article discussing a unified cosolvency model for calculating solute solubility in mixed solvents.
Contributing Partner: UNT College of Arts and Sciences
Solubility of Anthracene in C1-C3 Alcohols from (298.2 to 333.2) K and Their Mixtures with 2-Propanone at 298.2 K

Solubility of Anthracene in C1-C3 Alcohols from (298.2 to 333.2) K and Their Mixtures with 2-Propanone at 298.2 K

Date: August 25, 2010
Creator: Jouyban, Abolghasem; Manzoori, Jamshid L.; Soleymani, Jafar; Panahi-Azar, Vahid; Fakhree, Mohammad Amin Abolghassemi; Ahmadian, Somaieh et al.
Description: Article discussing the solubility of anthracene in C1-C3 alcohols from (298.2 to 333.2) K and their mixtures with 2-propanone at 298.2 K.
Contributing Partner: UNT College of Arts and Sciences
Solubility Prediction of Solutes in Non-Aqueous Binary Solvent Mixtures

Solubility Prediction of Solutes in Non-Aqueous Binary Solvent Mixtures

Date: 2008
Creator: Jouyban, Abolghasem; Khoubnasabjafari, Maryam; Soltani, Somaieh; Soltanpour, Shahla; Tamizi, Elnaz & Acree, William E. (William Eugene)
Description: Article on the solubility prediction of solutes in non-aqueous binary solvent mixtures.
Contributing Partner: UNT College of Arts and Sciences
Solubility of Acetaminophen and Ibuprofen in the Mixtures of Polyethylene Glycol 200 or 400 with Ethanol and water and the Density of Solute-Free Mixed Solvents at 298.2 K

Solubility of Acetaminophen and Ibuprofen in the Mixtures of Polyethylene Glycol 200 or 400 with Ethanol and water and the Density of Solute-Free Mixed Solvents at 298.2 K

Date: October 26, 2010
Creator: Jouyban, Abolghasem; Soltanpour, Shahla & Acree, William E. (William Eugene)
Description: Article on the solubility of acetaminophen and ibuprofen in the mixtures of polyethylene glycol 200 or 400 with ethanol and water and the density of solute-free mixed solvents at 298.2 K.
Contributing Partner: UNT College of Arts and Sciences
Solubility Prediction of Anthracene in Mixed Solvents Using a Minimum Number of Experimental Data

Solubility Prediction of Anthracene in Mixed Solvents Using a Minimum Number of Experimental Data

Date: January 2002
Creator: Jouyban, Abolghasem; Khoubnasabjafari, Maryam; Chan, Hak-Kim; Clark, Brian J. & Acree, William E. (William Eugene)
Description: Article on the solubility prediction of anthracene in mixed solvents using a minimum number of experimental data.
Contributing Partner: UNT College of Arts and Sciences
A General Treatment of Solubility. 3. Principal Component Analysis (PCA) of the Solubilities of Diverse Solutes in Diverse Solvents

A General Treatment of Solubility. 3. Principal Component Analysis (PCA) of the Solubilities of Diverse Solutes in Diverse Solvents

Date: June 7, 2005
Creator: Katritzky, Alan R.; Tulp, Indrek; Fara, Dan C.; Lauria, Antonino; Maran, Uko, 1966- & Acree, William E. (William Eugene)
Description: Article discussing a general treatment of solubility and principle component analysis (PCA) of the solubilities of diverse solutes in diverse solvents.
Contributing Partner: UNT College of Arts and Sciences
Solubility of Phenanthrene in Ternary Mixtures of C1-C4 Alcohols at 298.2 K

Solubility of Phenanthrene in Ternary Mixtures of C1-C4 Alcohols at 298.2 K

Date: May 21, 2010
Creator: Fakhree, Mohammad Amin Abolghassemi; Acree, William E. (William Eugene) & Jouyban, Abolghasem
Description: This article discusses the solubility of phenanthrene in ternary mixtures of C1-C4 alcohols at 298.2 K.
Contributing Partner: UNT College of Arts and Sciences
Solubility of Anthracene in Ternary Dibutyl Ether + Alcohol + 2,2,4-Trimethylpentane Solvent Mixtures

Solubility of Anthracene in Ternary Dibutyl Ether + Alcohol + 2,2,4-Trimethylpentane Solvent Mixtures

Date: October 14, 1999
Creator: Pribyla, Karen J.; Spurgin, Michael A.; Chuca, Ivette & Acree, William E. (William Eugene)
Description: Article on the solubility of anthracene in ternary dibutyl ether + alcohol + 2,2,4-trimethylpentane solvent mixtures.
Contributing Partner: UNT College of Arts and Sciences
Solubility of Phenanthrene in Binary Mixtures of C1 - C4 Alcohols + 2-Propanol and Ethanol + Methanol at 298.2 K

Solubility of Phenanthrene in Binary Mixtures of C1 - C4 Alcohols + 2-Propanol and Ethanol + Methanol at 298.2 K

Date: March 24, 2009
Creator: Fakhree, Mohammad Amin Abolghassemi; Shayanfar, Ali; Acree, William E. (William Eugene) & Jouyban, Abolghasem
Description: Article discussing the solubility of phenanthrene in binary mixtures of C1 - C4 alcohols + 2-propanol and ethanol + methanol at 298.2 K.
Contributing Partner: UNT College of Arts and Sciences
Solubility of Lamotrigine, Diazepam, Clonazepam, and Phenobarbital in Propylene Glycol + Water Mixtures at 298.15 K

Solubility of Lamotrigine, Diazepam, Clonazepam, and Phenobarbital in Propylene Glycol + Water Mixtures at 298.15 K

Date: February 9, 2009
Creator: Shayanfar, Ali; Acree, William E. (William Eugene) & Jouyban, Abolghasem
Description: Article discussing the solubility of lamotrigine, diazepam, clonazepam, and phenobarbital in propylene glycol + water mixtures at 298.15 K.
Contributing Partner: UNT College of Arts and Sciences
Solubility of Clonazepam, Diazepam, Lamotrigine, and Phenobarbital in N-Methyl-2-pyrrolidone + Water Mixtures at 298.2 K

Solubility of Clonazepam, Diazepam, Lamotrigine, and Phenobarbital in N-Methyl-2-pyrrolidone + Water Mixtures at 298.2 K

Date: June 4, 2009
Creator: Shayanfar, Ali; Acree, William E. (William Eugene) & Jouyban, Abolghasem
Description: Article on the solubility of clonazepam, diazepam, lamotrigine, and phenobarbital in N-methyl-2-pyrrolidone + water mixtures at 298.2 K.
Contributing Partner: UNT College of Arts and Sciences
Solubility in Binary Solvent Mixtures: Anthracene Dissolved in Alcohol + Carbon Tetrachloride Mixtures at 298.2 K

Solubility in Binary Solvent Mixtures: Anthracene Dissolved in Alcohol + Carbon Tetrachloride Mixtures at 298.2 K

Date: October 9, 2003
Creator: Taylor, Priscilla G.; Tran, Anh M.; Charlton, Amanda K.; Daniels, Charlisa R. & Acree, William E. (William Eugene)
Description: Article discussing solubility in binary solvent mixtures and anthracene dissolved in alcohol + carbon tetrachloride mixtures at 298.2 K.
Contributing Partner: UNT College of Arts and Sciences
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