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Thermodynamics of Mobile Order Theory: Solubility and Partition Aspects

Description: The purpose of this thesis is to analyze the thermochemical properties of solutes in nonelectrolyte pure solvents and to develop mathematical expressions with the ability to describe and predict solution behavior using mobile order theory. Solubilities of pesticides (monuron, diuron, and hexachlorobenzene), polycyclic aromatic hydrocarbons (biphenyl, acenaphthene, and phenanthrene), and the organometallic ferrocene were studied in a wide array of solvents. Mobile order theory predictive equatio… more
Date: August 2004
Creator: De Fina, Karina M.
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Solubility of water in hydrocarbons

Description: Report presenting a study of the literature data on the solubility of water in hydrocarbons, which includes information about the log of solubility, critical solution temperature, and ratios that may affect solubility are provided. An equation is presented and applied to a few petroleum fractions ranging from gasoline to lubricating oil, and a comparison of calculated and experimental solubilities is provided.
Date: July 10, 1952
Creator: Hibbard, R. R. & Schalla, R. L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Preferential Solvation Study of Rosuvastatin in the {PEG400 (1) + Water (2)} Cosolvent Mixture and GastroPlus Software-Based In Vivo Predictions

Description: Article claims that rosuvastatin (RST) is a poorly water-soluble drug responsible for limited in vivo dissolution and subsequently low oral systemic absorption (poor bioavailability). The results of inverse Kirkwood–Buff integrals showed the PS of RST by PEG400 as observed in all studied ratios of the binary mixture.
Date: March 28, 2023
Creator: Hussain, Afzal; Afzal, Obaid; Yasmin, Sabina; Haider, Nazima; Alfawaz Altamimi, Abdulmalik Saleh; Martínez, Fleming et al.
Item Type: Refine your search to only Article
Partner: UNT College of Science
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Chemical Equilibria in Binary Solvents

Description: Dissertation research involves development of Mobile Order Theory thermodynamic models to mathematically describe and predict the solubility, spectral properties, protonation equilibrium constants and two-phase partitioning behavior of solutes dissolved in binary solvent mixtures of analytical importance. Information gained provide a better understanding of solute-solvent and solvent-solvent interactions at the molecular level, which will facilitate the development of better chemical separation… more
Date: August 1997
Creator: McHale, Mary E. R.
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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The Preparation of Uranyl Carbonate and Measurement of Its Solubility

Description: From summary: "A method for the preparation of normal uranyl carbonate has been developed. Heretofore, this compound has been known only as a rare, naturally occurring material." The report further discusses the physical properties of the compound, its solubility in water, and its interaction with sodium carbonate.
Date: August 1, 1949
Creator: Miller, P. D.; Pray, H. A. & Munger, H. P.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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The Use of Aromatic Compounds of Arsenic in Chemical Analysis, Part 1

Description: Report discussing a study to "evaluate the analytical properties of aromatic arsonic acids and thus to establish a basis for their broader utilization in chemical analysis." More specifically, constants of dissociation, polarization of replacing radicals, and precipitation were investigated.
Date: September 1953
Creator: Portnov, A. I.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Thermochemical Study of Crystalline Solutes Dissolved in Ternary Hydrogen-Bonding Solvent Mixtures

Description: The purpose of this dissertation is to investigate the thermochemical properties of nonelectrolyte solutes dissolved in ternary solvent mixtures, and to develop mathematical expressions for predicting and describing behavior in the solvent mixtures. Forty-five ternary solvent systems were studied containing an ether (Methyl tert-butyl ether, Dibutyl ether, or 1,4-Dioxane), an alcohol (1-Propanol, 2-Propanol, 1-Butanol, 2-Butanol, or 2-Methyl-1-propanol), and an alkane (Cyclohexane, Heptane, or… more
Date: May 2001
Creator: Pribyla, Karen J.
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Thermodynamics of the Abraham General Solvation Model: Solubility and Partition Aspects

Description: Experimental mole fraction solubilities of several carboxylic acids (2-methoxybenzoic acid, 4-methoxybenzoic acid, 4-nitrobenzoic acid, 4-chloro-3-nitrobenzoic acid, 2-chloro-5-nitrobenzoic acid,2-methylbenzoic acid and ibuprofen) and 9-fluorenone, thianthrene and xanthene were measured in a wide range of solvents of varying polarity and hydrogen-bonding characteristics. Results of these measurements were used to calculate gas-to-organic solvent and water-to-organic solvent solubility ratios,… more
Date: August 2006
Creator: Stovall, Dawn Michele
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
open access

The Mg-MgCl2 System — A Chronopotentiometric Study

Description: The mode of dissolution of magnesium in molten magnesium chloride contacted with Mg-Pb alloys was studied at 750°C using anodic chronopotentiometry. An inert tantalum anode was used to determine relative amounts of magnesium dissolved in its chloride as a function of magnesium activity in the alloy. According to the law of mass action a linear dependence of magnesium solubility on a Mg indicates Mg2Cl2 as the reaction product and a parabolic dependence indicates MgCl. It was found that the amou… more
Date: February 1, 1968
Creator: Van Norman, John D. & Egan, James J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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