Use of Phillips's five level training evaluation and ROI framework in the U.S. nonprofit sector.

Use of Phillips's five level training evaluation and ROI framework in the U.S. nonprofit sector.

Date: August 2007
Creator: Brewer, Travis K.
Description: This study examined training evaluation practices in U.S. nonprofit sector organizations. It offered a framework for evaluating employee training in the nonprofit sector and suggested solutions to overcome the barriers to evaluation. A mail survey was sent to 879 individuals who were members of, or had expressed an interest in, the American Society for Training and Development. The membership list consisted of individuals who indicated association/nonprofit or interfaith as an area of interest. Data from the survey show that training in the nonprofit sector is evaluated primarily at Level 1 (reaction) and Level 2 (learning). It also shows decreasing use from Level 3 (application) through Level 5 (ROI). Reaction questionnaires are the primary method for collecting Level 1 data. Facilitator assessment and self-assessment were listed as the primary method for evaluating Level 2. A significant mean rank difference was found between Level 2 (learning) and the existence of an evaluation policy. Spearman rho correlation revealed a statistically significant relationship between Level 4 (results) and the reasons training programs are offered. The Kruskal-Wallis H test revealed a statistically significant mean rank difference between "academic preparation" of managers with Level 3 evaluation. The Mann-Whitney U test was used post hoc and revealed ...
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Photophysical properties of pyrene, 2,7 diazapyrene and 1,3-bis(β-naphthyl)propane.

Photophysical properties of pyrene, 2,7 diazapyrene and 1,3-bis(β-naphthyl)propane.

Date: August 2007
Creator: Boateng, Stephen
Description: The luminescence properties of Van Der Waals' dimers and clusters of pyrene and diazapyrene have been investigated. Excimers, dimeric species which are associative in an excited electronic state and dissociative in their ground state, have long been established and play an important role in many areas of photochemistry. My work here focuses on the luminescence and absorption properties of ground state dimers/aggregates, which are less understood, and allows further characterization of the ground state and excited state association of these aromatic molecules.
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ANTI preference of the pyramidalized radical center to the two fluorines in difluoro cyclic compounds.

ANTI preference of the pyramidalized radical center to the two fluorines in difluoro cyclic compounds.

Date: May 2008
Creator: Tanna, Jigisha
Description: An extensive study of disubstituted cycloalkanes like CnH2n where n=3,4,5 and 6 using DFT((U)B3LYP/6-31G(d) and 6-311+G(2df,2p)) calculations is presented focusing on the effect of pyramidalization of the radical center. A potential energy surface (PES) analysis shows that the radical prefers to pyramidalize anti to the two cis fluorines in the disubstituted cycloalkanes. The degree of pyramidalization for 1,2-difluorocyclopropyl radical is 43.9o away from the cis fluorines whereas for 1,3-difluorocyclobutyl radical, 1,3-difluorocyclopentyl radical and 1,3-difluorocyclohexyl radical is 3.8o, 5.4o and 14.5o respectively away from the cis fluorines. The importance of this pyramidality effect in these compounds is discussed in context with the carbon-hydrogen bond dissociation energies (BDE's) because the preference of the radical centers to pyramidalize anti to the fluorines affects the bond dissociation energy. Importance of steric effect and unfavorable electronic interactions have been extensively explored in planar permethylated cyclobutadiene (Me4CBD) and cyclooctatetraene (Me8COT) using ((U)B3LYP/6-31G(d) and 6-311+G(2df,2p)) calculations. It is thought that steric interactions dominate electronic interactions in Me8COT, while this works opposite in case of Me4CBT. Instead, in Me4CBD the number of unfavorable electronic interactions between π bonds and out-of-plane hydrogens plays the dominant role in determining the relative energies. Interactions between the π bonds of CBD and ...
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Synthesis, characterization and properties of rigid macromolecules with extended conjugation, using palladium-catalyzed alkynylated polyhaloarenes.

Synthesis, characterization and properties of rigid macromolecules with extended conjugation, using palladium-catalyzed alkynylated polyhaloarenes.

Date: December 2007
Creator: Akintomide, Temiloluwa
Description: A synthetic approach to macromolecules of acetylenic arrays and luminescent properties is proposed and the execution of initial steps is described. Palladium-catalyzed coupling of 1,3,5-triiodobenzene with trimethylsilylbuta-1,3-diyne, trimethylsilylocta-1,3,5,7-tetrayne, and trimethylsilylhexadeca-1,3,5,7,9,11,13,15-octayne to yield the new 1,3,5-tris(trimethylsilylbuta-1,3-diynyl)benzene and the proposed 1,3,5-tris(8-(trimethylsilyl)octa-1,3,5,7-tetraynyl)benzene and 1,3,5-tris(trimethylsilyl)hexadeca-1,3,5,7,9,11,13,15-octaynyl)benzene respectively. The proposed three-coordinate Au (I) complexed macromolecules will be derived from the metallation of the aforementioned alkynylated arenes.
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Mental Toughness: An Analysis of Sex, Race, and Mood

Mental Toughness: An Analysis of Sex, Race, and Mood

Date: May 2012
Creator: Beck, Nicholas M.
Description: Mental toughness has become a focus for researchers as coaches, athletes, and others extol its influence in performance success. In this study I examined mental toughness among collegiate athletes, focusing on its potential relationship to different demographic variables and to the athletes’ mood. Two hundred seventy-two student-athletes representing 12 different sports from a southwestern NCAA Division I university, participated by completing the Sports Mental Toughness Questionnaire (SMTQ), the Brief Assessment of Mood (BAM), and providing demographic information. Analyses of variance (ANOVA) assessed differences in mental toughness scores by sex, race, scholarship status, and starting status. Significant differences in mental toughness emerged between Black – White, male – female, and full – partial – zero scholarship athletes. Pearson correlations showed mental toughness was significantly related to lower levels of anxiety, sadness, anger, confusion, fatigue, and total mood disturbance, and higher levels of vigor.
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Prevalence of Eating Disorders and Pathogenic Weight Control Behaviors Among Male Collegiate Athletes

Prevalence of Eating Disorders and Pathogenic Weight Control Behaviors Among Male Collegiate Athletes

Date: August 2012
Creator: Chatterton, Justine M.
Description: Training in sport environments that emphasize leanness and muscularity may damage athletes' body image and negatively influence male athletes' eating behaviors and attitudes. The Questionnaire for Eating Disorder Diagnosis and the Bulimia Test – Revised were completed anonymously online by 732 male intercollegiate athletes. Most male collegiate athletes were classified as asymptomatic (82.9%), followed by symptomatic (16%) and eating disordered (1.1%). The most common forms pathogenic behaviors were excessive exercise (51.6%), binge eating (21.4%), and dieting or fasting (20.5%). Results suggested that athletes who participate in weight class sports are at higher risk for developing these behaviors than endurance sport or ball game athletes. Counseling and other implications for professionals working with athletes are discussed.
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Photophysical studies of silver(I), platinum(II), palladium(II), and nickel(II) complexes and their use in electronic devices.

Photophysical studies of silver(I), platinum(II), palladium(II), and nickel(II) complexes and their use in electronic devices.

Date: December 2007
Creator: Hudson, Joshua M.
Description: This dissertation deals with two major topics that involve spectroscopic studies of (a) divalent group 10 metals and (b) silver(I)-phosphine complexes. The scope of the work involved the delineation of the electronic structure of these complexes in different environments and their use in electronic devices. The first topic is a look at the luminescence of tetrahedral silver(I)-phosphine complexes. Broad unstructured emissions with large Stokes shifts were found for these complexes. Computational analysis of the singlet and triplet state geometries suggests that this emission is due to a Jahn-Teller type distortion. The second topic represents the major thrust of this research, which is an investigation into the electronic structure of M(diimine)X2 (M= Pt(II), Pd(II), or Ni(II); X = dichloro, or dithiolate ligands) complexes and their interactions with an electron acceptor or Lewis acid. Chapter 3 assesses the use of some of these complexes in dye sensitized solar cells (DSSCs); it is shown that these complexes may lead to a viable alternative to the more expensive ruthenium-based dyes that are being implemented now. Chapter 4 is an investigation into donor/acceptor pairs involving this class of complexes, which serves as a feasibility test for the use of these complexes in organic photo-voltaics (OPVs) ...
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Multiple Predictors of College Adjustment and Academic Performance for Undergraduates in Their First Semester

Multiple Predictors of College Adjustment and Academic Performance for Undergraduates in Their First Semester

Date: May 2001
Creator: Stoever, Shawn
Description: College success, as defined by adjustment to college and academic performance, is a multidetermined with a number of contributing influences, including academic factors, personality variables, family characteristics, and environmental factors. This study attempted to provide an organizing model of the college success literature that was based on previous research (e.g., Aspinwall & Taylor, 1994) and current stress-coping theory (Moos & Swindle, 1990). Structural equation modeling analyses indicated that the hypothesized model did not fit the data well. However, subsequent regression analyses did validate the view that college success is multidetermined. Specifically, academic performance was predicted by a combination of academic factors (SAT score and class rank) and academic adjustment. In turn, academic adjustment was predicted by locus of control, perceived social support, and high school class rank. Personal adjustment was predicted by coping strategies employed, parents who fostered autonomy, locus of control, self-esteem, and high school class rank. Finally, social adjustment was predicted by optimism, coping strategies employed, and locus of control. Treatment implications as well as directions for future research were discussed.
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The effects of media exposure on body satisfaction, beliefs about attractiveness, mood and bulimic symptomatology among college women

The effects of media exposure on body satisfaction, beliefs about attractiveness, mood and bulimic symptomatology among college women

Date: December 2000
Creator: Varnado, Jessica Lea
Description: The research of Stice et al. (1994) and Stice and Shaw (1994) proposed several mechanisms that may mediate the adverse effects of media exposure to the thin ideal including internalization of the thin-ideal, negative affect, and body dissatisfaction. The purpose of this study was to extend initial research of Stice and Shaw (1994) by incorporating two forms of media (e.g., TV and Magazines) to assess the effects of exposure to the media portrayal of ideal body shape on women's mood, body satisfaction, and internalization of societal values concerning attractiveness. The relation of these variables to bulimic symptomatology was examined. The current study improved upon Stice and Shaw's study (1994) by matching participants' scores on BMI, level of negative affect, and level of body satisfaction before random assignment to the experimental conditions. Female undergraduates aged 18 to 25 years participated in premeasure (N = 198) and post measure (N = 164) conditions. Results from repeated mulitvariate analysis indicated media exposure to ideal-body images demonstrated no significant changes in women's affect, body satisfaction or endorsement of the thin ideal. Indirect support for the sociocultural theory of eating disorders was provided by multiple regression analyses that demonstrated lower levels of satisfaction with size ...
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Psychological correlates of eating disorders:  Exploring the continuum perspective.

Psychological correlates of eating disorders: Exploring the continuum perspective.

Date: August 2002
Creator: Cohen, Diane L.
Description: Psychological and behavioral characteristics of female undergraduates with varying levels of disordered eating, as measured by the Questionnaire for Eating Disorder Diagnoses (Q-EDD; Mintz, O'Halloran, Mulholland, & Schneider, 1997), were investigated. Results suggest that the Q-EDD is an appropriate instrument for measuring eating disorder symptomatology. Greater disordered eating was associated with more bulimic, dieting, and weight fluctuation symptoms, higher impression management and approval-seeking needs, more dichotomous thinking, self control, and rigid weight regulation, and increased concern with body shape and dissatisfaction with facial features. Eating-disordered and symptomatic women evidenced more severe eating disorder behaviors and psychological distress than asymptomatic women. Findings are congruent with a redefined discontinuity perspective of eating disorder symptomatology. Treatment implications and campus-wide preventions are suggested.
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