Characterization of Ionic Liquid Solvents Using a Temperature Independent, Ion-Specific Abraham Parameter Model
Description:
Experimental data for the logarithm of the gas-to-ionic liquid partition coefficient (log K) have been compiled from the published literature for over 40 ionic liquids over a wide temperature range. Temperature independent correlations based on the Gibbs free energy equation utilizing known Abraham solvation model parameters have been derived for the prediction of log K for 12 ionic liquids to within a standard deviation of 0.114 log units over a temperature range of over 60 K. Temperature inde…
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Date:
December 2014
Creator:
Stephens, Timothy W.
Partner:
UNT Libraries