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Reactions and Interfacial Behaviors of the Water–Amorphous Silica System from Classical and Ab Initio Molecular Dynamics Simulations

Description: Due to the wide application of silica based systems ranging from microelectronics to nuclear waste disposal, detailed knowledge of water-silica interactions plays an important role in understanding fundamental processes, such as glass corrosion and the long term reliability of devices. In this dissertation, atomistic computer simulation methods have been used to explore and identify the mechanisms of water-silica reactions and the detailed processes that control the properties of the water-sili… more
Date: May 2016
Creator: Rimsza, Jessica M.
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Hydrophobic, fluorinated silica xerogel for low-k applications.

Description: A new hydrophobic hybrid silica film was synthesized by introducing one silicon precursor (as modifiers) into another precursor (network former). Hybrid films have improved properties. Hydrolysis and condensation of dimethyldiethoxysilane (DMDES) (solvent (EtOH) to DMDES molar ratio R = 4, water to DMDES molar ratio r = 4, 0.01 N HCl catalyst) was analyzed using high-resolution liquid 29Si NMR. It was found that after several hours, DMDES hydrolyzed and condensed into linear and cyclic species.… more
Date: May 2004
Creator: Zhang, Zhengping
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Adsorption of Zirconium-Niobium on Silica Gel

Description: From abstract: "Adsorption of radioactive zirconium-niobium from uranyl nitrate solutions by silica gel was increased by increasing the temperature and time the solution contacts silica gel, and decreased by "aging" the solutions before contacting the silica gel."
Date: July 1957
Creator: Karraker, David G. & Parker, Sidney G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Isotopic Purification of Tritium by Electrolysis

Description: From abstract: "An electrolytic refining process was developed to produce tritium of high isotopic purity with negligible loss. The operation is semicontinuous, with multiple stages in cascade. All tritium oxide is handled within the confines of a hermetically sealed enclosure. The mechanical operability of the process was demonstrated in a five-stage prototype line designed to process 15 gram-mols of feed per day. An average separation factor per stage of 5.3 was obtained with a feed of tracer… more
Date: May 1958
Creator: Johnson, B. S., Jr.; Grace, J. T.; Meyer, L. H.; Karraker, D. G. & Nicholson, C. K.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Scavenging of Ruthenium From Purex Uranyl Nitrate Solution

Description: From introduction: "In previous work on the ion exchange adsorption of ruthenium, it was observed that when certain compounds of sulfur were added to dilute uranyl nitrate solutions, precipitates formed which carried ruthenium. The purpose of this investigation was to develop a similar method for scavenging ruthenium from concentrated uranyl nitrate solutions. Such a method, combined with the silica gel treatment for removing zirconium and niobium, might provide an integrated process to remove … more
Date: June 1958
Creator: Prohaska, Charles A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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