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Chemical Technology Division Unit Operations Section Monthly Progress Report, September 1961

Description: Nine samples of ThO/sub 2/ -UO/sub 2/ prepared as part of the solgel process development studies showed no consistent effects from small variations in several process parameters. The reaction of methane and copper oxide was studied. Engineering studies of the continuous dissolution of simulated U-Zr-Sn fuels in 6.5 M NH4F, 0.6-1.0 M NH/sub 4/NO/sub 3/, 0.1 M H/sub 2/O/sub 2/ were continued in modified 6-in.-dia. equipment. A total of 1642 kg of U from NaK bonded SRE Core I fuel rods wad dejacke… more
Date: April 1, 1962
Creator: Whatley, M. E.; Haas, P. A.; Horton, R. W.; Ryon, A. D.; Suddath, J. C. & Watson, C. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Diffusion of Slow Electrons in Gases

Description: The properties of electrons in a gas and an external electric field, e.g., agitation velocity, free path, energy lost per collision, and collision cross sections, were determined for electrons of energy less than 2 ev in a large number of gases. The computations were made from previously measured values for Townsend's energy factor or the ratio of electron agitation energy to molecule thermal energy. Results are presented for hydrogen, nitrogen, carbon dioxide, methane, ethylene, cyclopropane, … more
Date: October 24, 1961
Creator: Forester, D. W. & Cochran, L. W.
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries Government Documents Department
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Unit Operations Section Monthly Progress Report, November 1961

Description: Openation of a 6-in.-dia foam separation column with Sr/sup 89/ tracer and dodecylbenzenesulfonate as a surfactant and foaming agent was continued. The catalytic oxidation of H/sub 2/, CO, and CH/sub 4/ was studied using a nickel- chromepalladium ribbon catalyst. A Mark I prototype fuel assembly was sheared to within 1.5-in. of the end by modifying the gas hydraulic system of the shear. The force required to shear a highly carburized Mark I fuel assembly ductile tubing. Demonstration of the mec… more
Date: May 16, 1962
Creator: Whatley, M. E.; Haas, P. A.; Horton, R. W.; Ryon, A. D.; Suddath, J. C. & Watson, C. D.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Secondary Isotope Effects in Molecular Structure

Description: A study was made to determine whether secondary iso tope effects also occur in molecular structure. Electron diffraction studies were carried out on ethane and deuteroethane. In C/sub 2/H/sub 6/ the mean C-C and C-H bond lengths found agreed very closely with values determined for other paraffin hydrocarbons, and the C--H bond showed a normal primary isotope effect (~ 0.005 A) similar to that found in methane when H is replaced by O. The output of the leastsquares analysis suggested that the me… more
Date: June 15, 1962
Creator: Bartell, L. S.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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A Parametric Study of Certain Low-Molecular-Weight Compounds as Nuclear Rocket Propellants. v. Methane

Description: A parametric investigation was made of a series of lowmolecular-weight, high-hydrogen-content compounds as propellants for nuclear-powered rockets. The chemical compounds include H/sub 2/, NH/sub 3/, H/sub 2/0, LiH, CH/sub 4/, and CH/ sub 3/OH. A two-part computational program was carried out for each compound; the results for methane are presented in both tabular and graphic form. The results of the first part of the program are presented in static form, that is, by the conventional Mollier di… more
Date: August 1, 1961
Creator: Krieger, F.J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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BIO-ORGANIC CHEMISTRY QUARTERLY REPORT. December 1962 throughFebruary 1963

Description: This report covers the following titles: (1) A versatile solvent to replace phenol for the paper chromatography of radioactive intermediary metabolites; (2) Chromatography of plant lipids on alumina paper; (3) Quinone and pigment composition of chloroplasts and quantasomes from Spinacea oleracea; (4) The lipid composition of chloroplast lamellae from Spinacea oleracea; (5) Metal chelates and photochemistry of flavins; (6) Photoinduced ESR in some solutions of organic electron donors and accepto… more
Date: March 29, 1963
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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THE ORIGIN OF LIFE ON EARTH AND ELSEWHERE. II

Description: The synthesis of relatively complex organic molecules by ionizing and radical mechanisms (induced by high energy radiations, ultraviolet and electric discharge) from methane, ammonia, water, and hydrogen is described, both theoretically and experimentally. It is shown that the molecules which tend to be formed under such random conditions are the very ones which today are the common building blocks in the biological reconstruction of organic material. Such molecules are the amino acids, the sim… more
Date: October 19, 1960
Creator: Calvin, Melvin
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Primordial Organic Chemistry. I. Compounds Resulting from Electron Irradiation of C<sup>14</sup>H<sub>4</sub>

Description: C{sup 14}-labeled methane, together with a number of other presumed primordial gases of the earth's atmosphere, has been subjected to electron bombardments. The products formed have been examined by paper chromatography, ion exchange chromatography, mass spectrometry, and ultraviolet light spectrophotometry. A number of minor molecules have been specifically identified, and urea has been found as a major component in the absence of added phosphine; the formation of urea is inhibited by added ph… more
Date: December 1, 1961
Creator: Palm, Christopher & Calvin, Melvin
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Organic Compounds in Fission Reactors. [Part] 2. Thorio-Organic Compounds

Description: The advantages of the use of organic liquids in fission reactors to minmize corrosion and pressure problems were studied relative to the solution of thorium in such fluids. Thorio-organic compounds were prepared from organic acids, diketones, and other chelating compounds. Salts of carboxylic and phospho- organic acids were insoluble. The chelate with dibenzoylmethane was soluble in molten biphenyl but was decomposed at 300 deg C. The general low solubility of thorio-organic compounds in nonpol… more
Date: February 29, 1960
Creator: Baldwin, W. H.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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MOUND LABORATORY PROGRESS REPORT FOR JUNE 1963

Description: 3 8 ; 9 4 5 7 5 C 9 E ; < : 7over a 1456-day period. The half life was calculated to be 12.355 plus or minus 0.0l0 years, based on measurements in three calorimeters. The yields of /sup 208/Po and /sup 209/Po from the irradiation of multicurie quantities of /sup 210/Po were calculated. Production of small quantities of /sup 208/Po and /sup 209/Po is possible by the (n,xn) reaction; however, large quantities of /sup 210/Po would be present in the /sup 208/Po--/sup 209/Po sample. On the basis of … more
Date: June 28, 1963
Creator: Eichelberger, J.F.; Grove, G.R. & Jones, L.V.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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