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Base Effects on the Thermal Decomposition of Sec-butyllithium Solutions

Description: The pyrolysis of sec-butyllithium in solution was studied in an attempt to understand the loss of stereo-specificity and the atypical kinetics that have been reported. Additionally, the effect of added lithium alkoxides was studied to determine their effects on the highly reactive sec-butyllithium substrate.
Date: June 1966
Creator: Adams, George Michael
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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Organomagnesium Compounds in Benzene Solvent and Their Application in Synthesis of Organoberyllium Compounds

Description: The work reported by D. Bryce-Smith and G. F. Cox, along with several recent publications describing experimental results designed to elucidate the long disputed question of the structure of the Grignard reagent in ether stimulated the work reported here, in an effort to obtain additional evidence of the structure of the organomagnesium complex in benzene solvent. Since the primary objective of this work was to prepare organoberyllium compounds using the organomagnesium complexes in hydrocarbon… more
Date: January 1966
Creator: Selman, Charles M.
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
open access

Recombination Rate Coefficient Measurements in the Helium Afterglow

Description: This thesis describes a method of determining the recombination rate coefficient experimentally, which does not depend on a specific model of the recombination process. With this method established, results are presented for the recombination rate coefficient measurements at 44.6 Torr.
Date: August 1969
Creator: Wells, William E.
Item Type: Refine your search to only Thesis or Dissertation
Partner: UNT Libraries
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