5-Volt and 4.6 V plateaus in LiMn₂O₄ thin films
Description:
Additional plateaus with median voltages of {similar_to}4.6 V, and {similar_to}5 V have been observed on charging thin film lithium batteries with crystalline LiMn{sub 2}O{sub 4} cathodes to 5.3 V. Total charge extracted from the 4 V and the two additional plateaus corresponded to about 1Li/Mn{sub 2}O{sub 4}, but the distribution of capacity among the three plateaus varied from film to film. It is speculated that the additional plateaus result from formation of mixed spinel structures in which …
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Date:
January 1, 1996
Creator:
Bates, J. B.; Lubben, D.; Dudney, N. J.; Zuhr, R. A. & Hart, F. X.
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