UNT Libraries Government Documents Department - 2 Matching Results
Search Results
- Solidification/Stabilization of High Nitrate and Biodenitrified Heavy Metal Sludges with a Portland Cement/Flyash System
- Pond 207C at Rocky Flats Environmental Technology Site (RFETS) contains process wastewaters characterized by high levels of nitrates and other salts, heavy metal contamination, and low level alpha activity. The purpose of this research was to investigate the feasibility of treating a high-nitrate waste, contaminated with heavy metals, with a coupled dewateriug and S/S process, as well as to investigate the effects of biodenitrification pretreatment on the S/S process. Pond 207C residuals served as the target waste. A bench-scale treatability study was conducted to demonstrate an S/S process that would minimize final product volume without a significant decrease in contaminant stabilization or loss of desirable physical characteristics. The process formulation recommended as a result a previous S/S treatability study conducted on Pond 207C residuals was used as the baseline formulation for this research. Because the actual waste was unavailable due to difficulties associated with radioactive waste handling and storage, a surrogate waste, of known composition and representative of Pond 207C residuals, was used throughout this research. The contaminants of regulatory concern added to the surrogate were cadmium, chromium, nickel, and silver. Product volume reduction was achieved by dewatering the waste prior to S/S treatment. The surrogate was dewatered by evaporation at 60 to 80 C to total solids contents from 43% to 78% by weight, and treated with Portland cement and fly ash. Two cement to flyash ratios were tested, 2:1 and 1:2, by weight. Contaminant leachability testing was conducted with a 0.5 water to pozzolan (the cement/flyash mixture) ratio and both cement to flyash ratios. Each product was tested for unconfined compressive strength (UCS) and for contaminant leachability by the Toxicity Characteristics Leaching Procedure (TCLP). At the highest solids content achieved by dewatering, 78% solids by weight, the predicted final waste form volume f or Pond 207C residuals after …
- Magnetization and magnetostriction in highly magnetostrictive materials
- The majority of this research has been in developing a model to describe the magnetostrictive properties of Terfenol-D, Tb{sub 1{minus}x}Dy{sub x}Fe{sub y} (x = 0.7-0.75 and y = 1.8--2.0), a rare earth-iron alloy which displays much promise for use in device applications. In the first chapter an introduction is given to the phenomena of magnetization and magnetostriction. The magnetic processes responsible for the observed magnetic properties of materials are explained. An overview is presented of the magnetic properties of rare earths, and more specifically the magnetic properties of Terfenol-D. In the second chapter, experimental results are presented on three composition of Tb{sub 1{minus}x}Dy{sub x}Fe{sub y} with x = 0.7, y= 1.9, 1.95, and x= 0.73, y= 1.95. The data were taken for various levels of prestress to show the effects of composition and microstructure on the magnetic and magnetostrictive properties of Terfenol-D. In the third chapter, a theoretical model is developed based on the rotation of magnetic domains. The model is used to explain the magnetic and magnetostrictive properties of Terfenol-D, including the observed negative strictions and large change in strain. The fourth chapter goes on to examine the magnetic properties of Terfenol-D along different crystallographic orientations. In the fifth chapter initial data are presented on the time dependence of magnetization in nickel.