Date: January 31, 2014
Creator: Stevenson, Jeffry W. & Koeppel, Brian J.
Description: This progress report covers technical work performed during fiscal year 2013 at PNNL under Field Work Proposal (FWP) 40552. The report highlights and documents technical progress in tasks related to advanced cell and stack component materials development and computational design and simulation. Primary areas of emphasis for the materials development work were metallic interconnects and coatings, cathode and anode stability/degradation, glass seals, and advanced testing under realistic stack conditions: Metallic interconnects and coatings • Effects of surface modifications to AISI 441 (prior to application of protective spinel coatings) on oxide scale growth and adhesion were evaluated as a function of temperature and time. Cathode stability/degradation • Effects of cathode air humidity on performance and stability of SOFC cathodes were investigated by testing anode-supported cells as a function of time and temperature. • In-situ high temperature XRD measurements were used to correlate changes in cathode lattice structure and composition with performance of anode-supported button cells. Anode stability/degradation • Effects of high fuel steam content on Ni/YSZ anodes were investigated over a range of time and temperature. • Vapor infiltration and particulate additions were evaluated as a potential means of improving tolerance of Ni/YSZ anodes to sulfur-bearing fuel species. Glass seals • ...
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