Description: This article discusses reductive elimination of alkylamines from low-valent, alkylpalladium(II) amido complexes. A series of three-coordinate norbornylpalladium amido complexes ligated by bulky N-heterocyclic carbene (NHC) ligands were prepared that undergo reductive eliminations to form the alkyl-nitrogen bond of alkylamine products. The rates of reductive elimination reveal that complexes containing more-electron-donating amido groups react faster than those with less-electron-donating amido groups, and complexes containing more-sterically bulky amido groups undergo reductive elimination more slowly than complexes containing less-sterically bulky amido groups. Complexes ligated by more-electron-donating ancillary NHC ligands undergo reductive elimination faster than complexes ligated by less-electron-donating NHC ligands. In contrast to the reductive elimination of benzylamines from bisphosphine-ligated palladium amides, these reactions occur with retention of configuration at the alkyl group, indicating that these reductive eliminations proceed by a concerted pathway. The experimentally determined free energy barrier of 26 kcal/mol is close to the computed free energy barrier of 23.9 kcal/mol (363 K) for a concerted reductive elimination from the isolated, three-coordinate NHC-ligated palladium anilido complex.

Description: This report describes the findings of a study conducted on the watersheds of "Lake Lewisville, Lake Ray Roberts, Lake Grapevine and the Elm Fork of the Trinity River between Lake Lewisville and Frazier Dam," which are all part of the upper Trinity drainage basin (p. 31). The study examines the potential benefit of "remote sensing and geographic information systems (GIS) for watershed management" in and around Dallas, Texas (p. i).

Description: In this article, the authors consider two different approaches, to which the authors refer to as renewal and modulation, to generate time series with a nonexponential distribution of waiting times. The authors show that different time series with the same waiting time distribution are not necessarily statistically equivalent, and might generate different physical properties. Renewal generates aging and anomalous scaling, while modulation yields no significant aging and either ordinary or anomalous diffusion, according to the dynamic prescription adopted. The authors show, in fact, that the physical realization of modulation generates two classes of events. The events of the first class are determined by the persistent use of the same exponential time scale for an extended lapse of time, and consequently are numerous; the events of the second class are identified with the abrupt changes from one to another exponential prescription, and consequently are rare. The events of the second class, although rare, determine the scaling of the diffusion process, and for this reason the authors term them as crucial events. According to the prescription adopted to produce modulation, the distribution density of the time distances between two consecutive crucial events might have, or not, a diverging second moment. In the ...

Description: This article discusses how resistance to impact criteria can lead to a tightening of the accountability noose. Vague impact criteria are a blessing in disguise. The authors write that researchers who push against criteria that allow considerable autonomy are foolish and should learn from overseas contemporaries that a clearer definition of impact requirements is not dissimilar from a tightening of the noose.

Description: This article is a response to "A critique of Abraham and Acree's correlation for deca-1,9-diene/water partition coefficients." Abstract: The manuscript responds to the critique of Nitsche and Kasting concerning our published correlation for deca-1,9-diene-water partition coefficients. Several statements made in the critique are refuded, and shown to be misrepresentations of ideas contained in our earlier paper.