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  Partner: UNT College of Arts and Sciences
 Decade: 2000-2009
Salman Rushdie: Reading the Postcolonial Texts in the Era of Empire

Salman Rushdie: Reading the Postcolonial Texts in the Era of Empire

Date: 2009
Creator: Raja, Masoof Ashraf
Description: This article discusses Salman Rushdie and reading the postcolonial texts in the era of empire. Using the first three novels of Salman Rushdie, this essay articulates a different conceptual framework for reading the postcolonial texts. It is a known fact that in most metropolitan readings of the global periphery, the text is made to stand in for an entire culture. Inundation, a technique introduced in this essay, ensures a more complex reading by inserting silenced knowledge and histories in our reading to challenge any reductive representations of the global periphery. An inundated text, the author suggests, becomes a better tool in teaching the complexities of the postcolony to the metropolitan audiences, while also taking the reader beyond the politics of representation. It is hoped that this essay will invite other scholars to expand on this concept (inundation), for a new mode of reading is absolutely necessary in the politically charged world of today's empire.
Contributing Partner: UNT College of Arts and Sciences
Scaling Breakdown: A Signature of Aging

Scaling Breakdown: A Signature of Aging

Date: July 12, 2002
Creator: Allegrini, Paolo; Bellazzini, Jacopo; Bramanti, G.; Ignaccolo, Massimiliano; Grigolini, Paolo & Yang, J.
Description: In this article, the authors prove that the Lévy walk is characterized by bilinear scaling. This effect mirrors the existence of a form of aging that does not require the adoption of nonstationary conditions.
Contributing Partner: UNT College of Arts and Sciences
Scaling Detection in Time Series: Diffusion Entropy Analysis

Scaling Detection in Time Series: Diffusion Entropy Analysis

Date: September 25, 2002
Creator: Scafetta, Nicola & Grigolini, Paolo
Description: This article discusses scaling detection in time series. The methods currently used to determine the scaling exponent of a complex dynamic process described by a time series are based on the numerical evaluation of variance. This means that all of them can be safely applied only to the case where ordinary statistical properties hold true even if strange kinetics are involved. The authors illustrate a method of statistical analysis based on the Shannon entropy of the diffusion process generated by the time series, called diffusion entropy analysis (DEA). The authors adopt artificial Gauss and Lévy time series, as prototypes of ordinary and anomalous statistics, respectively, and the authors analyze them with the DEA and four ordinary methods of analysis, some of which are very popular. The authors show that the DEA determines the correct scaling exponent even when the statistical properties, as well as the dynamic properties, are anomalous. The other four methods produce correct results in the Gauss case but fail to detect the correct scaling in the case of Lévy statistics.
Contributing Partner: UNT College of Arts and Sciences
Scanning Tunneling Microscopy Studies of Temperature-Dependent Etching of Diamond (100) by Atomic Hydrogen

Scanning Tunneling Microscopy Studies of Temperature-Dependent Etching of Diamond (100) by Atomic Hydrogen

Date: April 9, 2001
Creator: Stallcup, Richard E. & Pérez, José M.
Description: In this article, the authors present a technique for obtaining atomic resolution ultrahigh vacuum scanning tunneling microscopy images of diamond (100) films by atomic hydrogen. The authors find that etching by atomic hydrogen is highly temperature dependent, resulting in a rough and pitted surface at T ≈ 200 and 500˚C, respectively. At T ≈ 1000˚C etching results in a smooth surface and is highly anisotropic, occurring predominantly in the direction of dimer rows. This observation supports recent theoretical models that propose anisotropic etching as the mechanism for the growth of smooth diamond (100) films.
Contributing Partner: UNT College of Arts and Sciences
A self-adaptive burst-detection algorithm

A self-adaptive burst-detection algorithm

Date: July 6, 2007
Creator: Tam, Nicoladie D.
Description: This article accompanies a poster presentation on a self-adaptive burst-detection algorithm. A self-adaptive, time-scale invariant single-unit spike train analysis technique is introduced to detect burst firings in neurons. This burst-detection method is an adaptive algorithm that uses the characteristic firing patterns statistics within and between bursts to identify the inter-burst period, intra-burst period and burst duration.
Contributing Partner: UNT College of Arts and Sciences
Single-Electron Oxidation of Monomeric Copper(I) Alkyl Complexes: Evidence for Reductive Elimination through Biomolecular Formation of Alkanes

Single-Electron Oxidation of Monomeric Copper(I) Alkyl Complexes: Evidence for Reductive Elimination through Biomolecular Formation of Alkanes

Date: July 21, 2006
Creator: Goj, Laurel A.; Blue, Elizabeth D.; Delp, Samuel A.; Gunnoe, T. Brent; Cundari, Thomas R., 1964- & Petersen, Jeffrey L.
Description: This article discusses single-electron oxidation of monomeric copper(I) alkyl complexes. Monomeric Cu(I) alkyl complexes (NHC)Cu(R) (NHC = N-heterocyclic carbene; R = Me or Et) and (dtbpe)Cu(Me) (dtbpe = 1,2-bis(di-tert-butylphosphino)ethane) have been prepared, isolated, and characterized. Single-electron oxidation of the Cu(I) alkyl complexes upon reaction with AgOTf to form putative Cu(II) intermediates of the type [(L)Cu(R)]+ (L = NHC or dtbpe, R = Me or Et) results in the rapid production of (L)Cu(X) (X = OTf) and R2. Experimental studies suggest that the reductive elimination of R2 from Cu(II) occurs through a nonradical bimolecular mechanism. Computational studies of the Cu-Cmethyl yield bond dissocation enthalpies of [(SIPr)Cu-CH3]n+ (80 kcal/mol for n = 0 {Cu(I)} and 38 kcal/mol for n = 1 {Cu(II)}).
Contributing Partner: UNT College of Arts and Sciences
Six-, Five-, and Four-Coordinate Ruthenium(II) Hydride Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones

Six-, Five-, and Four-Coordinate Ruthenium(II) Hydride Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones

Date: February 20, 2009
Creator: Lee, John P.; Ke, Zhuofeng; Ramírez, Magaly A.; Gunnoe, T. Brent; Cundari, Thomas R., 1964-; Boyle, Paul D. et al
Description: This article discusses six-, five-, and four-coordinate ruthenium(II) hydride complexes. The Ru(II) hydride complex (IMes)2Ru(Cl)(H)(CO) (1) {IMes = 1,3-bis-(2,4,6-trimethylphenyl)imidazol-2-ylidene} was synthesized from [Ru(CO)2Cl2]n and free IMes. Complex 1 rapidly reacts with CO to produce the cis-dicarbonyl Ru(II) complex (IMes)2Ru(Cl)(H)(CO)2 (2). The reaction of 1 with NaBAr'4 {Ar' = 3,5-(CF3)C6H3} produces the four-coordinate Ru(II) cationic complex [(IMes)2Ru(H)(CO)][BAr'4] (4), which can be trapped by two equivalents of tert-butylisonitrile to produce [(IMes)2Ru(H)(CO)(CNtBu)2][BAr'4] (5). Experimental and computational studies suggest that complex 4 is a diamagnetic system that adopts a sawhorse structure. The hydride ligand of complex 2 is readily displaced as dihydrogen upon reaction with HCI to produce (IMes)2Ru(CI)2(CO)2 (3). Both complex 1 and 4 were found to react with D2 (30 psi) at room temperature to produce the isotopomers (IMes)2Ru(CI)(D)(CO) (1-d1) and [(IMes)2Ru(D)(CO)][BAr'4] (4-d1), respectively, with the rate of formation of 4-d1 at least 28 times faster than the conversion of 1/D2 to 1-d1. In the presence of excess D2 complex 4 reversibly incorporates deuterium into the ortho methyl groups of the IMes ligands, whereas complex 1 does not show evidence of H/D exchange with the IMes ligands. Both 1 and 4 were found to catalyze the hydrogenation of olefins, ketones, and aldehydes.
Contributing Partner: UNT College of Arts and Sciences
Solar Turbulence in Earth's Global and Regional Temperature Anomalies

Solar Turbulence in Earth's Global and Regional Temperature Anomalies

Date: February 26, 2004
Creator: Scafetta, Nicola; Grigolini, Paolo; Imholt, Timothy; Roberts, Jim & West, Bruce J.
Description: This article presents a study of the influence of solar activity on the earth's temperature. In particular, the authors focus on the repercussion of the fluctuations of the solar irradiance on the temperature of the Northern and Southern hemispheres as well as on land and ocean regions. While solar irradiance data are not directly analyzed, the authors make use of a published solar irradiance reconstruction for long-time-scale fluctuations, and for short-time-scale fluctuations the authors hypothesize that solar irradiance and solar flare intermittency are coupled in such a way that the solar flare frequency fluctuations are stochastically equivalent to those of the solar irradiance. The analysis is based upon wavelet multiresolution techniques and scaling analysis methods for processing time series. The limitations of the correlation analysis applied to the short-time-scale fluctuations are discussed. The scaling analysis uses both the standard deviation and the entropy of the diffusion generated by the temperature signals. The joint use of these two scaling methods yields evidence of a Levy component in the temporal persistence of the temperature fluctuations within the temporal range from a few weeks to a few years. This apparent Levy persistence of the temperature fluctuations is found, by using an appropriate model, ...
Contributing Partner: UNT College of Arts and Sciences
Speed of Sound in Periodic Elastic Composites

Speed of Sound in Periodic Elastic Composites

Date: December 29, 2003
Creator: Krokhin, Arkadii; Arriaga, J. & Gumen, L.
Description: In this article, the authors consider the low-frequency limit (homogenization) for propagation of sound waves in periodic elastic medium (phononic crystals). Exact analytical formulas for the speed of sound propagating in a three-dimensional periodic arrangement of liquid and gas or in a two-dimensional arrangement of solids are derived. The authors apply their formulas to the well-known phenomenon of the drop of the speed of sound in mixtures. For air bubbles in water, the authors obtain a perfect agreement with the recent results of coherent potential approximation obtained by M. Kafesaki, R.S. Penciu, and E.N. Economou [Phys. Rev. Lett. 84, 6050 (2000)] if the filling of air bubbles is far from close parking. When air spheres almost touch each other, the approximation gives 10 times lower speed of sound than the exact theory does.
Contributing Partner: UNT College of Arts and Sciences
Spontaneous Brain Activity as a Source of Ideal 1/f Noise

Spontaneous Brain Activity as a Source of Ideal 1/f Noise

Date: December 18, 2009
Creator: Allegrini, Paolo; Menicucci, Danilo; Bedini, Remo; Fronzoni, Leone; Gemignani, Angelo; Grigolini, Paolo et al
Description: In this article, the authors study the electroencephalogram (EEG) of 30 closed-eye subjects with a technique of analysis recently proposed to detect punctual events signaling rapid transitions between different metastable states. After single-EEG-channel event detection, the authors study global properties of events simultaneously occurring among two or more electrodes termed coincidences. The authors convert the coincidences into a diffusion process with three distinct rules that can yield the same μ only in the case where the coincidences are driven by a renewal process. The authors establish that the time interval between two consecutive renewal events driving the coincidences has a waiting-time distribution with inverse power-law index μ≈2 corresponding to ideal 1/f noise. The authors argue that this discovery, shared by all subjects of our study, supports the conviction that 1/f noise is an optimal communication channel for complex networks as in art or language and may therefore be the channel through which the brain influences complex processes and is influenced by them.
Contributing Partner: UNT College of Arts and Sciences