Charge-state dependence of M-shell x-ray production in 67Ho by 2-12-MeV carbon ions
Date: November 1995
Creator: Yu, Y. C.; Sun, H. L.; Duggan, Jerome L.; McDaniel, Floyd Del. (Floyd Delbert), 1942-; Yin, J. Y. & Lapicki, Gregory
Description: This article discusses charge-state dependence of M-shell x-ray production in 67Ho by 2-12-MeV carbon ions. Abstract: Charge-state dependence of M-shell x-ray production cross sections of 67Ho bombarded by 2-12-MeV carbon ions, with and without K-shell vacancies, were measured using a windowless Si(Li) x-ray detector with a full-width-at-half-maximum resolution of 135 eV at 5.9 keV. Carbon ions of different charge states were produced using a postacceleration, nitrogen gas stripping cell. The carbon ions were then magnetically analyzed to select the desired charge state and energy before entering the target chamber. The total M-shell and Mζ, Mα,β, and Mγ x-ray cross sections were measured. The electron-capture (EC) contributions as well as the direct-ionization (DI) contributions can be determined by making a comprehensive study of the projectile-charge-state dependence of the target x-ray production cross sections for targets in which the single-collision realm is maintained. In this paper, both EC and DI contributions and the total M-shell x-ray production cross sections are compared to both the first Born theory and to the perturbed-stationary-state theory with energy-loss, Coulomb-deflection, and relativistic corrections.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc139496/
Comments on the Competitive Preferential Solvation Theory
Date: 1990
Creator: Acree, William E. (William Eugene); Zvalgzne, Anita I. & Tucker, Sheryl A.
Description: This article offers comments on the competitive preferential solvation theory. Abstract: Simple additive relationships for the physico-chemical properties of a solute dissolved in binary solvent mixtures are developed from the competitive preferential solvation model. Additive expressions for solute mole fraction solubility and logarithm of solute solubility are mathematically identical to equations derived previously from the microscopic partition and basic nearly ideal binary solvent models. Calculated values based on the various additive relationships are compared to carbazole solubilities in ten binary solvent mixtures containing dibutyl ether with n-hexane, n-heptane, n-octane, cyclohexane, cyclo-octane, methylcyclohexane, iso-octane, n-hexadecane, squalane and t-butylcyclohexane.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc157300/
Control of chaos in a CO2 laser
Date: September 5, 1994
Creator: Pérez, José M.; Steinshnider, J.; Stallcup, Richard E. & Aviles, A. F.
Description: This article discusses the control of chaos in a CO2 laser. Abstract: We report the experimental control of chaos in an optically modulated CO2 laser. The CO2 laser was driven into chaos by injecting a feedback beam modulated by an electro-optical modulator. Control of chaos was achieved using a modified proportional feedback technique in which the control pulses were delayed by approximately one relaxation period. Using this technique, it was possible to control unstable periodic orbits up to period 6.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc84149/
Design of highly specific cytotoxins by using trans-splicing ribozymes
Date: March 30, 1999
Creator: Ayre, Brian G.; Köhler, Uwe; Haseloff, Jim & Goodman, Howard M.
Description: This article discusses the design of highly specific cytotoxins by using trans-splicing ribozymes. Abstract: We have designed ribozymes based on a self-splicing group I intron that can trans-splice exon sequences into a chosen RNA target to create a functional chimeric mRNA and provide a highly specific trigger for gene expression. We have targeted ribozymes against the coat protein mRNA of a widespread plant pathogen, cucumber mosaic virus. The ribozymes were designed to trans-splice the coding sequence of the diphtheria toxin A chain in frame with the viral initiation codon of the target sequence. Diphtheria toxin A chain catalyzes the ADP ribosylation of elongation factor 2 and can cause the cessation of protein translation. In a Saccharomyces cerevisiae model system, ribozyme expression was shown to specifically inhibit the growth of cells expressing the virus mRNA. A point mutation at the target splice site alleviated this ribozyme-mediated toxicity. Increasing the extent of base pairing between the ribozyme and target dramatically increased specific expression of the cytotoxin and reduced illegitimate toxicity in vivo. Trans-splicing ribozymes may provide a new class of agents for engineering virus resistance and therapeutic cytotoxins.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc83320/
Direct evidence for the amorphous silicon phase in visible photoluminescent porous silicon
Date: August 3, 1992
Creator: Pérez, José M.; Villalobos, J.; McNeill, P.; Prasad, J.; Cheek, R.; Kelber, J. et al
Description: This article discusses direct evidence for the amorphous silicon phase in visible photoluminescent porous silicon. Abstract: We report on micro-Raman spectroscopy studies of porous silicon which show an amorphous silicon Raman line at 480 R cm-1 from regions that emit visible photoluminescence. A Raman line corresponding to microcrystalline silicon at 510 R cm-1 is also observed. X-ray photoelectron spectroscopy data is presented which shows a high silicon-dioxide content in porous silicon consistent with an amorphous silicon phase.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc84327/
Dynamic Approach to the Thermodynamics of Superdiffusion
Date: April 26, 1999
Creator: Buiatti, Marco, 1972-; Grigolini, Paolo & Montagnini, Anna
Description: This article discusses dynamic approach to the thermodynamics of superdiffusion. Abstract: We address the problem of relating thermodynamics to mechanics in the case of microscopic dynamics without a finite time scale. The solution is obtained by expressing the Tsallis entropic index q as a function of the Lévy index α, and using dynamic rather than probabilistic arguments.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc77167/
Dynamical approach to Lévy processes
Date: November 1996
Creator: Allegrini, Paolo; Grigolini, Paolo & West, Bruce J.
Description: This article discusses a dynamical approach to Lévy processes.Abstract: We derive the diffusion process generated by a correlated dichotomous fluctuating variable y starting from a Liouville-like equation by means of a projection procedure. This approach makes it possible to derive all statistical properties of the diffusion process from the correlation function of the dichotomous fluctuating variable Φy(t). Of special interest is that the distribution of the times of sojourn in the two states of the fluctuating process is proportional to d²Φy(t)/dt². Furthermore, in the special case where Φy(t) has an inverse power law, with the index β ranging from 0 to 1, thus making it nonintegrable, the authors show analytically that the statistics of the diffusing variable approximate in the long-time limit the α-stable Lévy distributions. The departure of the diffusion process of dynamical origin from the ideal condition of the Lévy statistics is established by means of a simple analytical expression. We note, first of all, that the characteristic function of a genuine Lévy process should be an exponential in time. We evaluate the correction to this exponential and show it to be expressed by a harmonic time oscillation modulated by the correlation function Φy(t). Since the characteristic function ...
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc139498/
Dynamical model for DNA sequences
Date: November 1995
Creator: Allegrini, Paolo; Barbi, M.; Grigolini, Paolo & West, Bruce J.
Description: This article discusses a dynamical model for DNA sequences. Abstract: We address the problem of DNA sequences, developing a "dynamical" method based on the assumption that the statistical properties of DNA paths are determined by the joint action of two processes, one deterministic with long-range correlations and the other random and δ-function correlated. The generator of the deterministic evolution is a nonlinear map belonging to a class of maps recently tailored to mimic the processes of weak chaos responsible for the birth of anomalous diffusion. It is assumed that the deterministic process corresponds to unknown biological rules that determine the DNA path, whereas the noise mimics the influence of an infinite-dimensional environment on the biological process under study. We prove that the resulting diffusion process, if the effect of the random process is determined by the joint action of the deterministic and the random process, the correlation effects of the "deterministic dynamics" are canceled on the short-range scale, but show up in the long-range one. We denote their prescription to generate statistical sequences as the copying mistake map (CMM). We carry out their analysis of several DNA sequences and their CMM realizations with a variety of techniques and the authors ...
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc139499/
An Effective Core Potential Study of Transition-Metal Chalcogenides. 1. Molecular Structure
Date: May 1994
Creator: Benson, Michael T.; Cundari, Thomas R., 1964-; Lim, Soon J.; Nguyen, Hoang D. & Pierce-Beaver, Karen
Description: This article discusses an effective core potential study of transition-metal chalcogenides. Abstract: A structural analysis is reported of roughly 150 transition-metal (TM)-chalcogenido complexes in a variety of chemical environments. With few exceptions, agreement between calculated and experimental geometries is excellent. The research provides convincing evidence that computational methods employed are adequately describing the bonding in these diverse TM complexes. Interesting trends in relative TMCh (Rмсh-Rмсh) bond lengths are found. Experimental and computational data show that other than the zirconocene-and halfnocene-oxos there is similar behavior in relative bond lengths for widely varying TM-chalcogenido complexes. Relative bond lengths versus oxo (S-O, Se-O, and Te-O) in group IVB metallocenes tend to be larger than for other families of complexes and show less variation among the heavier chalcogens (Se-S, Te-S, and Te-Se). Analysis of localized wave functions for Cp₂ZrCh point to a greater contribution from a singly-bonded Zr-Ch structure (relative to Zr=Ch) when Ch is O compared to heavier chalcogens. Taken together, the data suggest that there is a fundamental difference in the Zr-oxo (and Hf-oxo) bond in relation to heavier chalcogens, consistent with recent experimental data. In previous studies of multiply bonded TM complexes the authors have focused on the ability of ECPs ...
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc107778/
Effects of O2, H2, and N2 gases on the field emission properties of diamond-coated microtips
Date: August 23, 1999
Creator: Lim, Seong-Chu; Stallcup, Richard E.; Akwani, Ikerionwu A. & Pérez, José M.
Description: This article discusses the effects of O2, H2, and N2 gases on the field emission properties of diamond-coated microtips. Abstract: We report the effects of O2, H2, and N2 residual gases on the field emission properties of uncoated and diamond-coated individual Mo microtips. The microtips are made using electrochemical etching techniques and positioned 5 µm from the anode using a scanning tunneling microscopy system. The authors observe that the field emission (FE) current and turn-on voltage of diamond-coated microtips are significantly less degraded by O2 exposure that those of uncoated Mo microtips. H2 exposure enhances the FE properties of both uncoated and diamond-coated microtips, while N2 exposure does not have any significant effect.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc84151/