You limited your search to:
Partner:
UNT College of Arts and Sciences
Collection:
UNT Scholarly Works
Statue of James Prescott Joule
Date: Spring 2011
Creator: Marshall, James L., 1940- & Marshall, Virginia R.
Description: Front cover of the spring 2011 issue of the Hexagon, which features a statue James Joule wearing a coat and sitting in a chair. The inside cover includes a table of contents, a list of staff, an editorial, and a description of the cover.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc111257/
Tracking molecular wave packets in cesium dimers by coherent Raman scattering
Date: August 31, 2012
Creator: Yuan, Luqi; Murawski, Robert K.; Ariunbold, Gombojav O.; Zhi, Miaochan; Wang, Xi; Sautenkov, Vladimir A. et al
Description: None
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc103258/
Reductive Elimination of Alkylamines from Low-Valent, Alkylpalladium(II) Amido Complexes
Date: August 30, 2012
Creator: Hanley, Patrick S.; Marquard, Seth L.; Cundari, Thomas R., 1964- & Hartwig, John F.
Description: This article discusses reductive elimination of alkylamines from low-valent, alkylpalladium(II) amido complexes. A series of three-coordinate norbornylpalladium amido complexes ligated by bulky N-heterocyclic carbene (NHC) ligands were prepared that undergo reductive eliminations to form the alkyl-nitrogen bond of alkylamine products. The rates of reductive elimination reveal that complexes containing more-electron-donating amido groups react faster than those with less-electron-donating amido groups, and complexes containing more-sterically bulky amido groups undergo reductive elimination more slowly than complexes containing less-sterically bulky amido groups. Complexes ligated by more-electron-donating ancillary NHC ligands undergo reductive elimination faster than complexes ligated by less-electron-donating NHC ligands. In contrast to the reductive elimination of benzylamines from bisphosphine-ligated palladium amides, these reactions occur with retention of configuration at the alkyl group, indicating that these reductive eliminations proceed by a concerted pathway. The experimentally determined free energy barrier of 26 kcal/mol is close to the computed free energy barrier of 23.9 kcal/mol (363 K) for a concerted reductive elimination from the isolated, three-coordinate NHC-ligated palladium anilido complex.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc107792/
A web-based multi-genome synteny viewer for customized data
Date: August 2, 2012
Creator: Revanna, V. Kashi; Munro, Daniel; Gao, Alvin; Chiu, Chi-Chen; Pathak, Anil & Dong, Qunfeng
Description: This article discusses a web-based multi-genome synteny viewer for customized data. Background: Web-based synteny visualization tools are important for sharing data and revealing patterns of complicated genome conservation and rearrangements. Such tools should allow biologists to upload genomic data for their own analysis. This requirement is critical because individual biologists are generating large amounts of genomic sequences that quickly overwhelm any centralized web resources to collect and display all those data. Recently, the authors published a web-based synteny viewer, GSV, which was designed to satisfy the above requirement. However, GSV can only compare two genomes at a given time. Extending the functionality of GSV to visualize multiple genomes is important to meet the increasing demand of the research community. Results: The authors have developed a multi-Genome Synteny Viewer (mGSV). Similar to GSV, mGSV is a web-based tool that allows users to upload their own genomic data files for visualization. Multiple genomes can be presented in a single integrated view with an enhanced user interface. Users can navigate through all selected genomes in either pairwise or multiple viewing mode to examine conserved genomic regions as well as the accompanying genome annotations. Besides serving users who manually interact with the web server, ...
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc122141/
Derivation of the evolution of empathic other-regarding social emotions as compared to non-social self-regarding emotions
Date: July 16, 2012
Creator: Tam, Nicoladie D.
Description: This article accompanies a poster presentation on the derivation of the evolution of empathic other-regarding social emotions as compared to non-social self-regarding emotions. The present study derives the evolution of social emotions by inclusion of other-regarding concerns from the non-social emotions of self-regarding concerns. Emotional processing is a self-discovered error-correction feedback process in which computations are involved to assess the accuracy of the internal brain-generated predictions with respect to the reality, in order to increase its probability of an organism's own survival.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc122156/
Controllable enhanced dragging of light in ultradispersive media
Date: July 5, 2012
Creator: Rostovtsev, Yuri V. & Davuluri, Sankar
Description: This article discusses controllable enhanced dragging of light in ultradispersive media. Abstract: We have theoretically demonstrated an enhanced Fizeau effect due to dragging the light that occurs when the group velocity of light is ultraslow. The proposed experiment can be done in a cell of atomic Rb vapor under conditions such that the group velocity of light is of the order of a few hundred meters per second. We show theoretically that higher-order dispersion can influence the Fizeau effect and can be observed experimentally. It has been shown that the change of phase is sensitive to the motion of the cell with the speed of the order of 10⁻³ cm/s and for possible displacements as small as 10 Å. The enhanced dragging effect can be applied for position control, detection of slow mechanical motion, and efficient modulators of light.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc103255/
P02.123. The anti-diabetic and cholesterol-lowering effects of common and cassia cinnamon (Cinnamomum verum and C. aromaticum): a randomized controlled trial
Date: June 12, 2012
Creator: Dugoua, Jean-Jacques; Perri, Dan; Seely, Dugald; Ardilouze, J.; Ridout, Rowena; Bowers, K. et al
Description: This paper accompanies a poster presentation on the anti-diabetic and cholesterol-lowering effects of common and cassia cinnamon (Cinnamomum verum and C. aromaticum). According to the World Health Organization (WHO), approximately 150 million people worldwide have type 2 diabetes. It is a growing health concern. Common and cassia cinnamon have been reported to have anti-diabetic and lipid-lowering effects. The objective was to determine if the combination of common and cassia cinnamon (Cinnamomum verum and C. aromaticum) reduces fasting blood glucose, insulin, glycosylated hemoglobin (HA1C), triglyceride, total cholesterol, HDL cholesterol and LDL cholesterol levels in people with type 2 diabetes.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc122161/
Charge transfer equilibria in ambient-exposed epitaxial graphene on (0001) 6 H-SiC
Date: June 5, 2012
Creator: Sidorov, Anton N.; Gaskill, D. Kurt.; Buongiorno Nardelli, Marco; Tedesco, Joseph L.; Myers-Ward, Rachel L.; Eddy, Charles R. et al
Description: This article discusses charge transfer equilibria in ambient-exposed epitaxial graphene on (0001) 6 H-SiC. Abstract: The transport properties of electronic materials have been long interpreted independently from both the underlying bulk-like behavior of the substrate or the influence of ambient gases. This is no longer the case for ultra-thin graphene whose properties are dominated by the interfaces between the active material and its surroundings. Here, the authors show that the graphene interactions with its environments are critical for the electrostatic and electrochemical equilibrium of the active device layers and their transport properties. Based on the prototypical case of epitaxial graphene on (0001) 6 H-SiC and using a combination of 'in-situ' thermoelectric power and resistance measurements and simulations from first principles, the authors demonstrate that the cooperative occurrence of an electrochemically mediated charge transfer from the graphene to air, combined with the peculiar electronic structure of the graphene/SiC interface, explains the wide variation of measured conductivity and charge carrier type found in prior reports.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc132974/
C-H Functionalization Reactivity of a Nickel-Imide
Date: May 22, 2012
Creator: Wiese, Stefan; McAfee, Jason L.; Pahls, Dale R.; McMullin, Claire L.; Cundari, Thomas R., 1964- & Warren, Timothy H.
Description: This article discusses C-H functionalization reactivity of a Nickel-Imide. Abstract: We report report bifunctional reactivity of the β-diketiminato Ni(III)-imide [Me₃NN]Ni=NAd (1), which undergoes H-atom abstraction (HAA) reactions with benzylic substrates R-H (indane, ethylbenzene, toluene). Nickel-imide 1 competes with the nickel-amide HAA product [Me₃NN]Ni-NHAd (2) for the resulting hydrocarbyl radical R• to give the nickel-amide [Me₃NN]Ni-N(CHMePh)Ad (3) (R-H = ethylbenzene) or aminoalkyl tautomer [Me₃NN]Ni(ɳ²-CH(Ph)NHAd) (4) (R-H = toluene). A significant amount of functionalized amine R-NHAd is observed in the reaction of 1 with indane along with the dinickel imide {[Me₃NN]Ni}₂(μ-NAd) (5). Kinetic and DFT analyses point to rate-limiting HAA from R-H by 1 to give R•, which may add to either imide 1 or amide 2, each featuring significant N-based radical character. Thus, these studies illustrate a fundamental competition possible in C-H amination systems that proceed via a HAA/radical rebound mechanism.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc107790/
Philosophy Matters - Examining the Value of Knowledge
Date: May 10, 2012
Creator: Frodeman, Robert & Holbrook, J. Britt
Description: This paper discusses the University of North Texas' (UNT) Center for the Study of Interdisciplinarity (CSID), where philosophers continue to examine the value of knowledge. The authors also discuss one example of CSID's work with the Comparative Assessment of Peer Review (CAPR) project. CAPR is a four-year project (2008-2012) studying the changing nature of peer review processes across six U.S. and foreign public science agencies. CAPR is funded by the U.S. National Science Foundation's (NSF) Science of Science and Innovation Policy (SciSIP) program.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc84353/