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  Partner: UNT College of Arts and Sciences
 Decade: 2000-2009
 Year: 2003
Asupra unei probleme de loc geometric a lui A. Dafina

Asupra unei probleme de loc geometric a lui A. Dafina

Date: 2003
Creator: Anghel, Nicolae
Description: This paper generalizes a certain geometric locus problem due to A. Dafina.
Contributing Partner: UNT College of Arts and Sciences
Generalized Master Equation Via Aging Continuous-Time Random Walks

Generalized Master Equation Via Aging Continuous-Time Random Walks

Date: 2003
Creator: Allegrini, Paolo; Aquino, Gerardo; Grigolini, Paolo; Palatella, Luigi & Rosa, Angelo
Description: This article discusses generalized master equation via aging continuous-time random walks. Abstract: We discuss the problem of the equivalence between continuous-time random walk (CTRW) and generalized master equation (GME). The walker, making instantaneous jumps from one site of the lattice to another, resides in each site for extended times. The sojourn times have a distribution density ψ(t) that is assumed to be an inverse power law with the power index μ. We assume that the Onsager principle is fulfilled, and we use this assumption to establish a complete equivalence between GME and the Montroll-Weiss CTRW.We prove that this equivalence is confined to the case where ψ(t) is an exponential. We argue that is so because the Montroll-Weiss CTRW, as recently proved by Barkai [E. Barkai, Phys. Rev. Lett. 90, 104101 (2003)], is nonstationary, thereby implying aging, while the Onsager principle is valid only in the case of fully aged systems. The case of a Poisson distribution of sojourn times is the only one with no aging associated to it, and consequently with no need to establish special initial conditions to fulfill the Onsager principle. We consider the case of a dichotomous fluctuation, and we prove that the Onsager principle is ...
Contributing Partner: UNT College of Arts and Sciences
Long- and Short-Time Analysis of Heartbeat Sequences: Correlation with Mortality Risk in Congestive Heart Failure Patients

Long- and Short-Time Analysis of Heartbeat Sequences: Correlation with Mortality Risk in Congestive Heart Failure Patients

Date: 2003
Creator: Allegrini, Paolo; Balocchi, Rita; Chillemi, Santi; Grigolini, Paolo; Hamilton, P.; Maestri, Roberto et al
Description: This paper discusses long- and short-time analysis of heartbeat sequences and the correlation with mortality risk in congestive heart failure patients. Abstract: We analyze RR heartbeat sequences with a dynamic model that satisfactorily reproduces both the long- and the short-time statistical properties of heart beating. These properties are expressed quantitatively by means of two significant parameters, the scaling δ concerning the asymptotic effects of long-range correlation, and the quantity 1 - π establishing the amount of uncorrelated fluctuations. We find a correlation between the position in the phase space (δ,π) of patients with congestive heart failure and their mortality risk.
Contributing Partner: UNT College of Arts and Sciences
Vortex Dynamics in Evolutive Flows: A Weakly Chaotic Phenomenon

Vortex Dynamics in Evolutive Flows: A Weakly Chaotic Phenomenon

Date: 2003
Creator: Bellazzini, Jacopo; Menconi, Giulia; Ignaccolo, Massimiliano; Buresti, Guido & Grigolini, Paolo
Description: In this article, the authors make use of a wavelet method to extract, from experimental velocity signals obtained in an evolutive flow, the dominating velocity components generated by vortex dynamics. The authors characterize the resulting time series complexity by means of a joint use of data compression and of an entropy diffusion method. The authors assess that the time series emerging from the wavelet analysis of the vortex dynamics is a weakly chaotic process with a vanishing Kolmogorov-Sinai entropy and a power-law growth of the information content. To reproduce the Fourier spectrum of the experimental signal, the authors adopt a harmonic dependence on time with a fluctuating frequency, ruled by an inverse power-law distribution of random events. The complexity of these fluctuations is determined by studying the corresponding artificial sequences. The authors reproduce satisfactorily both spectral and complex properties of the experimental signal by locating the complexity of the fluctuating process at the border between the stationary and the nonstationary states.
Contributing Partner: UNT College of Arts and Sciences
Compression and Diffusion: A Joint Approach to Detect Complexity

Compression and Diffusion: A Joint Approach to Detect Complexity

Date: February 2003
Creator: Allegrini, Paolo; Benci, V. (Vieri); Grigolini, Paolo; Hamilton, P.; Ignaccolo, Massimiliano; Menconi, G. et al
Description: This article discusses a joint approach to detect complexity. Abstract: The adoption of the Kolmogorov-Sinai (KS) entropy is becoming a popular research tool among physicists, especially when applied to a dynamical system fitting the conditions of validity of the Pesin theorem. The study of time series that are a manifestation of system dynamics whose rules are either unknown or too complex for a mathematical treatment, is still a challenge since the KS entropy is not computable, in general, in that case. Here the authors present a plan of action based on the joint action of two procedures, both related to the KS entropy, but compatible with computer implementation through fast and efficient programs. The former procedure, called Compression Algorithm Sensitive To Regularity (CASToRe), establishes the amount of order by the numerical evaluation of algorithmic compressibility. The latter, called Complex Analysis of Sequences via Scaling AND Randomness Assessment (CASSANDRA), establishes the complexity degree through the numerical evaluation of the strength of an anomalous effect. This is the departure, of the diffusion process generated by the observed fluctuations, from ordinary Brownian motion. The CASSANDRA algorithm shares with CASToRe a connection with the Kolmogorov complexity. This makes both algorithms especially suitable to study ...
Contributing Partner: UNT College of Arts and Sciences
A Priori Assessment of the Stereoelectronic Profile of Phosphines and Phosphites

A Priori Assessment of the Stereoelectronic Profile of Phosphines and Phosphites

Date: March 15, 2003
Creator: Cooney, Katharine D.; Cundari, Thomas R., 1964-; Hoffman, Norris W.; Pittard, Karl A.; Temple, M. Danielle & Zhao, Yong
Description: This article discusses research that has demonstrated the utility of a rigorously calibrated, molecular mechanics/semiempirical quantum mechanical protocol for developing stereoelectronic (Tolman) maps for phosphine ligands. A computational analysis of alkyl and aryl phosphines in common usage suggests that these ligands are quite similar stereoelectronically. A noticeable gap int he Tolman map for common phosphines is observed for large, electron-poor phosphines. Several candidates meeting these criteria were identified, the most promising of which is P(t-C₄F₉)₃. Phosphines in which the phosphorus participates in a ring, which comprise a very small subset of reported phosphines, have very interesting stereoelectronic properties, particularly those in which the ligating phosphorus is part of a three-membered ring. In terms of steric properties, the symmetric deformation coordinate proposed by Orpen and co-workers on the basis of crystallographic studies is calculated with sufficient accuracy using PM3(tm) to allow good confidence in predictions of novel phosphines. For quantification of the electronic properties of phosphines, the authors analyzed changes in the CO stretching frequency upon changing the ancillary phosphine ligands.
Contributing Partner: UNT College of Arts and Sciences
Symplastic Continuity between Companion Cells and the Translocation Stream: Long-Distance Transport Is Controlled by Retention and Retrieval Mechanisms in the Phloem

Symplastic Continuity between Companion Cells and the Translocation Stream: Long-Distance Transport Is Controlled by Retention and Retrieval Mechanisms in the Phloem

Date: April 2003
Creator: Ayre, Brian G.; Keller, Felix & Turgeon, Robert
Description: This article discusses symplastic continuity between companion cells and the translocation stream. Substantial symplastic continuity appears to exist between companion cells (CCs) and sieve elements of the phloem, which suggests that small solutes within the CC are subject to indiscriminate long-distance transport via the translocation stream. To test this hypothesis, the distributions of exotic and endogenous solutes synthesized in the CCs of minor veins were studied. Octopine, a charged molecule derived from arginine and pyruvate, was efficiently transported through the phloem but was also transferred in substantial amounts to the apoplast, and presumably other non-phloem compartments. The disaccharide galactinol also accumulated in non-phloem compartments, but long-distance transport was limited. Conversely, sucrose, raffinose, and especially stachyose demonstrated reduced accumulation and efficient transport out of the leaf. The authors conclude that small metabolites in the cytosol of CCs do enter the translocation stream indiscriminately but are also subject to distributive forces, such as nonselective and carrier-mediated membrane transport and symplastic dispersal, that may effectively clear a compound from the phloem or retain it for long-distance transport. A model is proposed in which the transport or oligosaccharides is an adaptive strategy to improve photoassimilate retention, and consequently translocation efficiency, the phloem.
Contributing Partner: UNT College of Arts and Sciences
Power-Law Time Distribution of Large Earthquakes

Power-Law Time Distribution of Large Earthquakes

Date: May 2003
Creator: Mega, Mirko S.; Allegrini, Paolo; Grigolini, Paolo; Latora, Vito; Palatella, Luigi; Rapisarda, Andrea et al
Description: In this article, the authors study the statistical properties of time distribution of seismicity in California by means of a new method of analysis, the diffusion entropy. The authors find that the distribution of time intervals between a large earthquake (the main shock of a given seismic sequence) and the next one does not obey Poisson statistics, as assumed by the current models. The authors prove that this distribution is an inverse power law with an exponent μ = 2.06 ± 0.01. The authors propose the long-range model, reproducing the main properties of the diffusion entropy and describing the seismic triggering mechanisms induced by large earthquakes.
Contributing Partner: UNT College of Arts and Sciences
Nanotubes in Microwave Fields: Light Emission, Intense Heat, Outgassing, and Reconstruction

Nanotubes in Microwave Fields: Light Emission, Intense Heat, Outgassing, and Reconstruction

Date: September 27, 2003
Creator: Imholt, Timothy; Dyke, Christopher A.; Hasslacher, Brosl; Pérez, José M.; Price, D.W.; Roberts, Jim et al
Description: This article discusses nanotubes in microwave fields. Single-walled carbon nanotubes (SWNTs) exhibit diverse and unique properties. Recently, a surprising feature has been the ignition of nanotubes in the presence of an ordinary camera flash. Here, the authors report that SWNTs, produced via the HiPco process, display strong microwave absorption (1.01 x 10⁻⁵ eV microwave field) with subsequent dramatic light emission, intense heat release, outgassing, and nanotube reconstruction.
Contributing Partner: UNT College of Arts and Sciences
Nanoparticle-assisted microwave absorption by single-wall carbon nanotubes

Nanoparticle-assisted microwave absorption by single-wall carbon nanotubes

Date: September 29, 2003
Creator: Wadhawan, Atul; Garrett, David & Pérez, José M.
Description: In this article, the authors report the effects of microwave irradiation on both unpurified and purified iron-catalyzed high-pressure disproportionation (HiPco)-grown single-walled carbon nanotubes (SWNTs) in ultrahigh vacuum. Under microwave irradiation, the authors observe that unpurified HiPco SWNTs quickly reach temperatures of approximately 1850 ºC. As a result, H2, H2O, CO, CO2, and CH4 gases are observed, and the Fe catalyst nanoparticles melt and coalesce into larger crystallites approximately four times their original diameter. In contrast, carbon black and purified HiPco SWNTs heat up to temperatures of 500-650 ºC. The authors propose that the significant heating of unpurified HiPco SWNTs is due to the Fe catalysts.
Contributing Partner: UNT College of Arts and Sciences
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