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  Partner: UNT College of Arts and Sciences
 Decade: 2010-2019
El Espejo, Volume 3, 2013

El Espejo, Volume 3, 2013

Date: January 2013
Creator: University of North Texas
Description: El Espejo literary journal contains writing by Spanish students at the University of North Texas including essays in Spanish literature and linguistics and creative pieces such as poetry and short stories.
Contributing Partner: UNT College of Arts and Sciences
El Espejo, Volume 2, 2012

El Espejo, Volume 2, 2012

Date: Spring 2012
Creator: University of North Texas. Department of World Languages, Literatures and Cultures.
Description: El Espejo literary journal contains writing by Spanish students at the University of North Texas including essays in Spanish literature and linguistics and creative pieces such as poetry and short stories.
Contributing Partner: UNT College of Arts and Sciences
El Espejo, Volume 1, 2011

El Espejo, Volume 1, 2011

Date: 2011
Creator: University of North Texas. Department of World Languages, Literatures and Cultures.
Description: El Espejo literary journal contains writing by Spanish students at the University of North Texas including essays in Spanish literature and linguistics and creative pieces such as poetry and short stories.
Contributing Partner: UNT College of Arts and Sciences
Construyendo una Red Chilena para Estudios Socioecológicos a Largo Plazo: Avances, enfoques y relevancia

Construyendo una Red Chilena para Estudios Socioecológicos a Largo Plazo: Avances, enfoques y relevancia

Date: 2010
Creator: Anderson, Christopher B.; Rozzi, Ricardo, 1960-; Armesto, Juan J., 1953- & Gutiérrez, Julio R., 1953-
Description: This article discusses building a Chilean network for long-term socio-ecological research. Abstract: Since their formal inception in 1980, long-term ecological research (LTER) programs have served as a successful organizing framework to create research agendas and funding mechanisms that allow scientists to address meaningful ecological phenomena at the scales they occur. In its 30 years of existence, LTER has expanded its geographic range (currently the International LTER network has more than 40 country members with sites on every continent) and disciplinary foci (principally encompassing the natural and social sciences and leading some to call for a name change to long-term socio-ecological research efforts exist in both Chile and Argentina, and in 2008, the Institute of Ecology and Biodiversity launched Chile's first concerted effort to link three existing sites (Fray Jorge Forest National Park -33° S, Senda Darwin Biological Station - 43° S, and Omora Ethnobotanical Park - 55° S). Here, the authors present a special feature of the Revista Chilena de Historia Natural, dedicated to LTSER, with the aim of 1) providing a synthesis of some of the most emblematic cases of long-term socio-ecological research in Chile; 2) demonstrating the value of these efforts for the integration of research, education and ...
Contributing Partner: UNT College of Arts and Sciences
Comparative Assessment of Peer Review: Project Outcomes Report

Comparative Assessment of Peer Review: Project Outcomes Report

Date: January 2013
Creator: Frodeman, Robert; Holbrook, J. Britt; Moen, William E.; Burggren, Warren W. & Mitcham, Carl
Description: This report discusses the Comparative Assessment of Peer Review (CAPR) project outcomes. Public funding agencies are required to demonstrate accountability to their government funders (e.g., Congress) as well as to the public. Some agencies - including the US National Science Foundation (NSF) - have used broader societal impacts criteria as part of the review process of grant proposals in order to connect scientific research to societal needs. But these agencies have often encountered questions from scientists and engineers for how to integrate such demands for broader societal impacts into their research proposals. In an effort to help clarify the idea of broader impacts, in 2010 NSF and Congress proposed a list of national needs that NSF-funded research would be required to meet. But was this the best solution? This report discusses the authors' research.
Contributing Partner: UNT College of Arts and Sciences
Cardiac and metabolic physiology of early larval zebrafish (Danio rerio) reflects parental swimming stamina

Cardiac and metabolic physiology of early larval zebrafish (Danio rerio) reflects parental swimming stamina

Date: February 24, 2012
Creator: Gore, Matthew & Burggren, Warren W.
Description: This article discusses cardiac and metabolic physiology of early larval zebrafish (Danio rerio) reflecting parental swimming stamina. Abstract: Swimming stamina in adult fish is heritable, it is unknown if inherited traits that support enhanced swimming stamina in offspring appear only in juveniles and/or adults, or if these traits actually appear earlier in the morphologically quite different larvae. To answer this question, mature adult zebrafish (Danio rerio) were subjected to a swimming performance test that allowed separation into low swimming stamina or high swimming stamina groups. Adults were then bred within their own performance groups. Larval offspring from each of the two groups, designated high (L(HSD)) and low stamina-derived larvae (L(LSD)), were then reared at 27°C in aerated water (21% O(2)). Routine (f(H),r) and active (f(H),a) heart rate, and routine [Formula: see text] and active [Formula: see text] mass-specific oxygen consumption were recorded from 5 days post fertilization (dpf) through 21 dpf, and gross cost of transport and factorial aerobic metabolic scope were derived from [Formula: see text] measurements. Heart rate generally ranged between 150 and 225 bpm in both L(HSD) and L(LSD) populations. However, significant (P<0.05) differences existed between the L(LSD) and L(HSD) populations at 5 and 14 dpf in ...
Contributing Partner: UNT College of Arts and Sciences
Carbon-Oxygen Bond Formation via Organometallic Baeyer-Villiger Transformations: A Computational Study on the Impact of Metal Identity

Carbon-Oxygen Bond Formation via Organometallic Baeyer-Villiger Transformations: A Computational Study on the Impact of Metal Identity

Date: December 20, 2011
Creator: Figg, Travis M.; Webb, Joanna R.; Cundari, Thomas R., 1964- & Gunnoe, T. Brent
Description: This article discusses a computational study on the impact of metal identity. Abstract: Metal-mediated formation of C-O bonds is an important transformation that can occur by a variety of mechanisms. Recent studies suggest that oxygen-atom insertion into metal-hydrocarbyl bonds in a reaction that resembles the Baeyer-Villiger transformation is a viable process. In an effort to identify promising new systems, this study is designed to assess the impact of metal identity on such O-atom insertions for the reaction [(bpy)ₓM(Me)(OOH)]ⁿ → [(bpy)ₓM(OMe)(OH)]ⁿ (x = 1 or 2; bpy = 2,2'-bipyridyl; n is varied to maintain the d-electron count at d⁶ or d⁸). Six d⁸-square-planar complexes (M = Ptᴵᴵ, Pdᴵᴵ, Niᴵᴵ, Irᴵ, Rhᴵ, and Coᴵ) and eight d⁶-octahedral systems (M = Irᴵᴵᴵ, Rhᴵᴵᴵ, Coᴵᴵᴵ, Feᴵᴵ, Ruᴵᴵ, Osᴵᴵ, Mnᴵ, and Tcᴵ) are studied. Using density functional theory calculations, the structures and energies of ground-state and transition-state species are elucidated. This study shows clear trends in calculated ∆G‡'s for the O-atom insertions. The organometallic Baeyer-Villiger insertions are favored by lower coordination numbers (x = 1 versus x = 2), earlier transition metals, and first-row (3d) transition metals.
Contributing Partner: UNT College of Arts and Sciences
Building a Chilean Network for Long-Term Socio-Ecological Research: Advances, perspectives and relevance

Building a Chilean Network for Long-Term Socio-Ecological Research: Advances, perspectives and relevance

Date: 2010
Creator: Anderson, Christopher B.; Rozzi, Ricardo, 1960-; Armesto, Juan J. & Gutiérrez, Julio R.
Description: This article discusses building a Chilean network for long-term socio-ecological research. Abstract: Since their formal inception in 1980, long-term ecological research (LTER) programs have served as a successful organizing framework to create research agendas and funding mechanisms that allow scientists to address meaningful ecological phenomena at the scales they occur. In its 30 years of existence, LTER has expanded its geographic range (currently the International LTER network has more than 40 country members with sites on every continent) and disciplinary foci (principally encompassing the natural and social sciences and leading some to call for a name change to long-term socio-ecological research efforts exist in both Chile and Argentina, and in 2008, the Institute of Ecology and Biodiversity launched Chile's first concerted effort to link three existing sites (Fray Jorge Forest National Park -33° S, Senda Darwin Biological Station - 43° S, and Omora Ethnobotanical Park - 55° S). Here, the authors present a special feature of the Revista Chilena de Historia Natural, dedicated to LTSER, with the aim of 1) providing a synthesis of some of the most emblematic cases of long-term socio-ecological research in Chile; 2) demonstrating the value of these efforts for the integration of research, education and ...
Contributing Partner: UNT College of Arts and Sciences
Calculations of the Relative Energies of the 2B1g and 2A2u States of Cyclobutanetetraone Radical Cation and Radical Anion Provide Further Evidence of a 3B2u Ground State for the Neutral Molecule: A Proposed Experimental Test of the Prediction of a Triplet Ground State for (CO)4

Calculations of the Relative Energies of the 2B1g and 2A2u States of Cyclobutanetetraone Radical Cation and Radical Anion Provide Further Evidence of a 3B2u Ground State for the Neutral Molecule: A Proposed Experimental Test of the Prediction of a Triplet Ground State for (CO)4

Date: 2010
Creator: Zhou, Xin; Hrovat, David A. & Borden, Weston T., 1943-
Description: This article discusses ground states. Abstract: B3LYP, CCSD(T), and CASPT2 calculations with the 6-311+G(2df) basis set have been performed on the radical anion and radical cation of cyclobutanetetraone (1). The very similar energies computed for the 2B1g and 2A2u states of both 1·+ and 1·- indicate that the singly occupied b1g and a2u MOs in these two states of the radical cation and anion have nearly the same energies, thus supporting the previously made prediction that neutral 1 has a 3B2u ground state. Reaction of squaric acid with O.(-), followed by negative ion photoelectron spectroscopy (NIPES) on the 1.(-) thus formed, is proposed as an experimental test of the startling prediction that tetraketone (1), a molecule that would be expected to be a closed-shell singlet, actually has a triplet ground state.
Contributing Partner: UNT College of Arts and Sciences
Calculations Predict That Carbon Tunneling Allows the Degenerate Cope Rearrangement of Semibullvalene to Occur Rapidly at Cryogenic Temperatures

Calculations Predict That Carbon Tunneling Allows the Degenerate Cope Rearrangement of Semibullvalene to Occur Rapidly at Cryogenic Temperatures

Date: May 27, 2010
Creator: Zhang, Xue; Hrovat, David A. & Borden, Weston T., 1943-
Description: This article discusses carbon tunneling. Abstract: Calculations on the role of tunneling in the degenerate Cope rearrangements of semibullvalene (1) and barbaralane (3) predict that, at temperatures below 40 K, tunneling from the lowest vibrational level should make the temperature-independent rate constants k = 1.43 x 10(-3) s(-1) and k = 7.28 x 10(-9) s(-1), respectively. An experiment, using semibullvalene-2(4)-d1, is proposed to test the prediction of rapid tunneling by 1 at cryogenic temperatures.
Contributing Partner: UNT College of Arts and Sciences
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