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2010-2019
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Comparative Assessment of Peer Review: Project Outcomes Report
Date: January 2013
Creator: Frodeman, Robert; Holbrook, J. Britt; Moen, William E.; Burggren, Warren W. & Mitcham, Carl
Description: This report discusses the Comparative Assessment of Peer Review (CAPR) project outcomes. Public funding agencies are required to demonstrate accountability to their government funders (e.g., Congress) as well as to the public. Some agencies - including the US National Science Foundation (NSF) - have used broader societal impacts criteria as part of the review process of grant proposals in order to connect scientific research to societal needs. But these agencies have often encountered questions from scientists and engineers for how to integrate such demands for broader societal impacts into their research proposals. In an effort to help clarify the idea of broader impacts, in 2010 NSF and Congress proposed a list of national needs that NSF-funded research would be required to meet. But was this the best solution? This report discusses the authors' research.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc139466/
Cardiac and metabolic physiology of early larval zebrafish (Danio rerio) reflects parental swimming stamina
Date: February 24, 2012
Creator: Gore, Matthew & Burggren, Warren W.
Description: This article discusses cardiac and metabolic physiology of early larval zebrafish (Danio rerio) reflecting parental swimming stamina. Abstract: Swimming stamina in adult fish is heritable, it is unknown if inherited traits that support enhanced swimming stamina in offspring appear only in juveniles and/or adults, or if these traits actually appear earlier in the morphologically quite different larvae. To answer this question, mature adult zebrafish (Danio rerio) were subjected to a swimming performance test that allowed separation into low swimming stamina or high swimming stamina groups. Adults were then bred within their own performance groups. Larval offspring from each of the two groups, designated high (L(HSD)) and low stamina-derived larvae (L(LSD)), were then reared at 27°C in aerated water (21% O(2)). Routine (f(H),r) and active (f(H),a) heart rate, and routine [Formula: see text] and active [Formula: see text] mass-specific oxygen consumption were recorded from 5 days post fertilization (dpf) through 21 dpf, and gross cost of transport and factorial aerobic metabolic scope were derived from [Formula: see text] measurements. Heart rate generally ranged between 150 and 225 bpm in both L(HSD) and L(LSD) populations. However, significant (P<0.05) differences existed between the L(LSD) and L(HSD) populations at 5 and 14 dpf in ...
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc115198/
Carbon-Oxygen Bond Formation via Organometallic Baeyer-Villiger Transformations: A Computational Study on the Impact of Metal Identity
Date: December 20, 2011
Creator: Figg, Travis M.; Webb, Joanna R.; Cundari, Thomas R., 1964- & Gunnoe, T. Brent
Description: This article discusses a computational study on the impact of metal identity. Abstract: Metal-mediated formation of C-O bonds is an important transformation that can occur by a variety of mechanisms. Recent studies suggest that oxygen-atom insertion into metal-hydrocarbyl bonds in a reaction that resembles the Baeyer-Villiger transformation is a viable process. In an effort to identify promising new systems, this study is designed to assess the impact of metal identity on such O-atom insertions for the reaction [(bpy)ₓM(Me)(OOH)]ⁿ → [(bpy)ₓM(OMe)(OH)]ⁿ (x = 1 or 2; bpy = 2,2'-bipyridyl; n is varied to maintain the d-electron count at d⁶ or d⁸). Six d⁸-square-planar complexes (M = Ptᴵᴵ, Pdᴵᴵ, Niᴵᴵ, Irᴵ, Rhᴵ, and Coᴵ) and eight d⁶-octahedral systems (M = Irᴵᴵᴵ, Rhᴵᴵᴵ, Coᴵᴵᴵ, Feᴵᴵ, Ruᴵᴵ, Osᴵᴵ, Mnᴵ, and Tcᴵ) are studied. Using density functional theory calculations, the structures and energies of ground-state and transition-state species are elucidated. This study shows clear trends in calculated ∆G‡'s for the O-atom insertions. The organometallic Baeyer-Villiger insertions are favored by lower coordination numbers (x = 1 versus x = 2), earlier transition metals, and first-row (3d) transition metals.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc107789/
Building a Chilean Network for Long-Term Socio-Ecological Research: Advances, perspectives and relevance
Date: 2010
Creator: Anderson, Christopher B.; Rozzi, Ricardo, 1960-; Armesto, Juan J. & Gutiérrez, Julio R.
Description: This article discusses building a Chilean network for long-term socio-ecological research. Abstract: Since their formal inception in 1980, long-term ecological research (LTER) programs have served as a successful organizing framework to create research agendas and funding mechanisms that allow scientists to address meaningful ecological phenomena at the scales they occur. In its 30 years of existence, LTER has expanded its geographic range (currently the International LTER network has more than 40 country members with sites on every continent) and disciplinary foci (principally encompassing the natural and social sciences and leading some to call for a name change to long-term socio-ecological research efforts exist in both Chile and Argentina, and in 2008, the Institute of Ecology and Biodiversity launched Chile's first concerted effort to link three existing sites (Fray Jorge Forest National Park -33° S, Senda Darwin Biological Station - 43° S, and Omora Ethnobotanical Park - 55° S). Here, the authors present a special feature of the Revista Chilena de Historia Natural, dedicated to LTSER, with the aim of 1) providing a synthesis of some of the most emblematic cases of long-term socio-ecological research in Chile; 2) demonstrating the value of these efforts for the integration of research, education and ...
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc97937/
Calculations of the Relative Energies of the 2B1g and 2A2u States of Cyclobutanetetraone Radical Cation and Radical Anion Provide Further Evidence of a 3B2u Ground State for the Neutral Molecule: A Proposed Experimental Test of the Prediction of a Triplet Ground State for (CO)4
Date: 2010
Creator: Zhou, Xin; Hrovat, David A. & Borden, Weston T., 1943-
Description: This article discusses ground states. Abstract: B3LYP, CCSD(T), and CASPT2 calculations with the 6-311+G(2df) basis set have been performed on the radical anion and radical cation of cyclobutanetetraone (1). The very similar energies computed for the 2B1g and 2A2u states of both 1·+ and 1·- indicate that the singly occupied b1g and a2u MOs in these two states of the radical cation and anion have nearly the same energies, thus supporting the previously made prediction that neutral 1 has a 3B2u ground state. Reaction of squaric acid with O.(-), followed by negative ion photoelectron spectroscopy (NIPES) on the 1.(-) thus formed, is proposed as an experimental test of the startling prediction that tetraketone (1), a molecule that would be expected to be a closed-shell singlet, actually has a triplet ground state.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc71812/
Calculations Predict That Carbon Tunneling Allows the Degenerate Cope Rearrangement of Semibullvalene to Occur Rapidly at Cryogenic Temperatures
Date: May 27, 2010
Creator: Zhang, Xue; Hrovat, David A. & Borden, Weston T., 1943-
Description: This article discusses carbon tunneling. Abstract: Calculations on the role of tunneling in the degenerate Cope rearrangements of semibullvalene (1) and barbaralane (3) predict that, at temperatures below 40 K, tunneling from the lowest vibrational level should make the temperature-independent rate constants k = 1.43 x 10(-3) s(-1) and k = 7.28 x 10(-9) s(-1), respectively. An experiment, using semibullvalene-2(4)-d1, is proposed to test the prediction of rapid tunneling by 1 at cryogenic temperatures.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc71814/
Charge transfer equilibria in ambient-exposed epitaxial graphene on (0001) 6 H-SiC
Date: June 5, 2012
Creator: Sidorov, Anton N.; Gaskill, D. Kurt.; Buongiorno Nardelli, Marco; Tedesco, Joseph L.; Myers-Ward, Rachel L.; Eddy, Charles R. et al
Description: This article discusses charge transfer equilibria in ambient-exposed epitaxial graphene on (0001) 6 H-SiC. Abstract: The transport properties of electronic materials have been long interpreted independently from both the underlying bulk-like behavior of the substrate or the influence of ambient gases. This is no longer the case for ultra-thin graphene whose properties are dominated by the interfaces between the active material and its surroundings. Here, the authors show that the graphene interactions with its environments are critical for the electrostatic and electrochemical equilibrium of the active device layers and their transport properties. Based on the prototypical case of epitaxial graphene on (0001) 6 H-SiC and using a combination of 'in-situ' thermoelectric power and resistance measurements and simulations from first principles, the authors demonstrate that the cooperative occurrence of an electrochemically mediated charge transfer from the graphene to air, combined with the peculiar electronic structure of the graphene/SiC interface, explains the wide variation of measured conductivity and charge carrier type found in prior reports.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc132974/
Many Eyes on Nature: Diverse Perspectives in the Cape Horn Biosphere Reserve and their Relevance for Conservation
Date: 2010
Creator: Berghoefer, Uta; Rozzi, Ricardo, 1960- & Jax, Kurt
Description: This article discusses research on diverse perspectives in the Cape Horn Biosphere Reserve in Chile and their relevance for conservation. Relationships between humans and nature take multiple forms. This is a fundamental issue in conservation but one that is often neglected, leading to poor conservation outcomes. It is thus imperative that we come to understand better the complex relationships between humans and nature. To do so, we need to examine "nature" and the often assumed dichotomy between humans and nature. The authors conducted a qualitative social research inquiry to explore the societal relationships with nature in the Cape Horn Biosphere Reserve in Chile. From the results, the authors developed a framework that illustrates how different "natures" are created in the three-way relationship among the individual, society and the physical world. The authors further discuss the implications of the co-existence of various "natures" in one place. Their explicit consideration bears important potential for improving conservation practice. The framework can then serve as a heuristic tool for uncovering and addressing challenges in other conservation contexts.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc97943/
The road to biocultural ethics
Date: May 2011
Creator: Rozzi, Ricardo, 1960- & Massardo, Francisca
Description: This article discusses the road to biocultural ethics. As a child, Ricardo Rozzi visited indigenous communities in the high Andes with his grandfather and was enchanted by their close relationship with the natural world. Later, he and his wife would return to the region to explore the traditional ecological knowledge of the world's southernmost indigenous people.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc130193/
The 2012 Republican Primaries
Date: April 24, 2012
Creator: Eshbaugh-Soha, Matthew
Description: This presentation is part of the faculty lecture series UNT Speaks Out on the 2012 Presidential Primaries. In this presentation, the author gives the audience an overview of the structure of the primaries, and provides a recap of past primaries. The author also speaks about the money, momentum, and media attention in the primaries.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc83792/