You limited your search to:
Partner:
UNT College of Arts and Sciences
Collection:
UNT Scholarly Works
3-Center-4-Electron Bonding in [(silox)2Mo=NtBu]2(μ-Hg) Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum π-Bond Energy Estimate
Date: May 18, 2005
Creator: Rosenfeld, Devon C.; Wolczanski, Peter T.; Barakat, Khaldoon A.; Buda, Corneliu & Cundari, Thomas R., 1964-
Description: This article discusses 3-center-4-electron bonding. Abstract: Na/Hg reduction of (silox)2Cl2Mo=NtBu (3) afforded C2h [(silox)2Mo=NtBu]2(μ-Hg) (12-Hg), which consists of two distorted trigonal monoprisms with Hg at the each apex (d(MoHg) = 2.6810(5)Å). Calculations reveal 3c4e bonding in the linear MoHgMo linkage that renders 12-Hg susceptible to nucleophilic cleavage. Exposure to PMe3 and pyridine rapidly (<5 min) affords (silox)2(tBuN)MoLn (L = PMe3, n = 1 (1-PMe3); py, n = 2 (1-py2)), while poorer nucleophiles (L = C2H4, 2-butyne) yield adducts (e.g., 1-C2H4 and 1-C2Me2) after prolonged heating. The HOMO and LUMO of 12-Hg are "stretched" π and π* orbitals from which four states arise: 1Ag (GS), 3Bu, 1Bu, and 1Ag. ∆E = E(1Bu) - E(3Bu) = 2K, where K is the exchange energy. Magnetic studies indicate E(3Bu) - E(1Ag) ≈ 550 cm-1 (calcd 1744 cm-1), and a UV-vis absorption at 10 000 cm-1 is assigned to 1Ag → 1Bu, permitting K to be evaluated as 4725 cm-1. With the π → π* transition in Schrock's [Mo(NAr)(CH2tBu)(OC6F5)]2 (4) assigned at 528 nm, this estimation places its π-bond energy as {E(π2 → π-1 → π*1 in 4) - E(1Ag → 1Bu in 12-Hg)} + E(1Ag → 3Bu in 12-Hg) = 27 kcal/mol.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc77136/
₁¹H+ - and ₂⁴He+ - induced M-shell x-ray-production cross sections for selected elements in the rare-earth region
Date: December 1983
Creator: Mehta, R.; Duggan, Jerome L.; Price, J. L.; Kocur, P. M.; McDaniel, Floyd Del & Lapicki, G.
Description: This article discusses ₁¹H+ - and ₂⁴He+ -induced M-shell x-ray production cross sections for selected elements in the rare-earth region. Abstract: The measurements of M-shell x-ray-production cross sections induced by ₁¹H+ and ₂⁴He+ ions are compared to the first-Born-approximation and ECPSSR (energy loss, Coulomb-deflection effects; perturbed-stationary-state approximation, with relativistic corrections) theories. Most of the reported experimental data were measured in the authors' laboratory and the other measurements were taken from the literature. The data from the authors' laboratory were for incident H+ and He+ ions in the energy range from 0.25 to 2.5 MeV. The M-shell x-ray-production cross sections were measured for the following thin targets: 59Pr, 60Nd, 63Eu, 64Gd, 66Dy, 67Ho, 68Er, 70Yb, and 72Hf. The data were for the following elements: 54Xe, 59Pr, 60Nd, 62Sm, 63Eu, 64Gd, 65Tb, 66Dy, 67Ho, 68Er, 70Yb, 72Hf, 73Ta, 74W, 78Pt, 79Au, 80Hg, 82Pb, 83Bi, and 92U. The first-born-approximation calculations of the ionization cross section were made using the plane-wave Born approximation for direct ionization and the Oppenheimer-Brinkman-Kramers approximation of Nikolaev for electron capture. The ECPSSR theory of Brandt and Lapicki [Phys. Rev. A 23, 1717 (1981)] goes beyond the first Born approximation and accounts for the energy loss, Coulomb deflection, and relativistic ...
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc139491/
The 2011 Beta Eta Spring Banquet. Celebration of Rediscovery of the Elements
Date: Summer 2011
Creator: Marshall, James L., 1940-
Description: Article describing an Eta Beta celebration of the completion of James and Virginia Marshall's "Rediscovery of the Elements." Photographs from the event are included. Three separate articles appear on the right side of the page.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc111260/
The 2012 Republican Primaries
Date: April 24, 2012
Creator: Eshbaugh-Soha, Matthew
Description: This presentation is part of the faculty lecture series UNT Speaks Out on the 2012 Presidential Primaries. In this presentation, the author gives the audience an overview of the structure of the primaries, and provides a recap of past primaries. The author also speaks about the money, momentum, and media attention in the primaries.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc83792/
Abraham model correlations for solute partitioning into o-xylene, m-xylene and p-xylene from both water and the gas phase
Date: September 2011
Creator: Stephens, Timothy W.; De la Rosa, Nohelli E.; Saifullah, Mariam; Ye, Shulin; Chou, Vicky; Quay, Amanda et al
Description: This article discusses Abraham model correlations for solute partitioning into o-xylene, m-xylene and p-xylene from both water and the gas phase. Abstract: Experimental data have been compiled from the publisher literature on the partition coefficients of solutes and vapors into o-xylene, m-xylene and p-xylene at 298 K. The logarithms of the water-to-xylene partition coefficients, log P, and gas-to-xylene partition coefficients, log K, were correlated with the Abraham solvation parameter model. The derived mathematical expressions described the observed log P and log K data for the three xylene isomers to within average deviations of 0.14 log units or less.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc155635/
Abraham Model Correlations for Transfer of Neutral Molecules and Ions to Sulfolane
Date: October 15, 2011
Creator: Stephens, Timothy W.; De la Rosa, Nohelli E.; Saifullah, Mariam; Ye, Shulin; Chou, Vicky; Quay, Amanda et al
Description: This article discusses Abraham model correlations for the transfer of neutral molecules and ions to sulfolane. Data have been compiled from the published literature on the partition coefficients of solutes and vapors into anhydrous sulfolane. The logarithms of the water-to-sulfolane partition coefficients, log P, and gas-to-sulfolane partition coefficients, log K, were correlated with the Abraham solvation parameter model. The derived correlations described the observed log P and log K values for solutes dissolved in sulfolane to within average standard deviations of 0.14 log units or less. The log P correlation was extended to include the partition of ions by inclusion of a cation-solvent and an anion-solvent term.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc157293/
Absorption and Emission in the Non-Poissonian Case
Date: July 28, 2004
Creator: Aquino, Gerardo; Palatella, Luigi & Grigolini, Paolo
Description: This article discusses absorption and emission in the Non-Poissonian Case. Abstract: This Letter addresses the challenging problems posed to the Kubo-Anderson (KA) theory by the discovery of intermittent resonant fluorescence with a nonexponential distribution of waiting times. We show how to extend the KA theory from aged to aging systems, aging for a very extended time period or even forever, being a crucial consequence of non-Poisson statistics.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc67641/
An Abstract Index Theorem on Non-Compact Riemannian Manifolds
Date: 1993
Creator: Anghel, Nicolae
Description: This article discusses an abstract index theorem on non-compact Riemannian manifolds. Abstract: We prove an abstract index theorem for essentially self-adjoint Fredholm supersymmetric first-order elliptic differential operators on Hermitian vector bundles over complete oriented Riemannian manifolds. According to our main result the supersymmetric L2-index of such an operator can be expressed as the sum of a "local contribution" (the familiar Atiyah-Singer index form, suitably restricted to and integrated over a finite region) and a "boundary contribution" (which depends only on the restriction of the operator at large distances). This is done by splicing together local parametrices and Green's operators defined "at infinity". The result yields (in fact is equivalent to) a generalisation of the relative index theorem of Gromov and Lawson.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc159527/
Accountable Science: The COMPETES Act Needs to Demonstrate an Accountability Attitude
Date: September 16, 2010
Creator: Holbrook, J. Britt
Description: This article discusses the U.S. National Science Foundation's (NSF) Broader Impacts Merit Review Criterion in relation to the America COMPETES Reauthorization Act of 2010.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc86163/
Accurate Enthalpies of Formation of Alkali and Alkaline Earth Metal Oxides and Hydroxides: Assessment of the Correlation Consistent Composite Approach (ccCA)
Date: July 12, 2006
Creator: Ho, Dustin S.; DeYonker, Nathan J.; Cundari, Thomas R., 1964- & Wilson, Angela K.
Description: This article discusses accurate enthalpies of formation of alkali and alkaline earth metal oxides and hydroxides. Abstract: Computing the enthalpies of formation for alkali metal and alkaline earth metal oxides (MₓO) and hydroxides [M(OH)n] using the Gaussian-n (Gn) and Weismann-n (Wn) ab initio model chemistries is difficult due to an improper treatment of core-valence electron correlation effects. Using a new model chemistry called the correlation consistent Composite Approach (ccCA), enthalpies of formation were determined for eight different alkali/alkaline earth metal oxides and hydroxides. Unlike the Gn and Wn model chemistries, which must be modified to properly account for core-valence electron correlation, the standard implementations of the ccCA provide acceptable results, and all enthalpies of formation obtained with the ccCA are within the accepted range of recommended values.
Contributing Partner: UNT College of Arts and Sciences
Permallink:digital.library.unt.edu/ark:/67531/metadc77173/