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The Mechanism of Action of Immune Guinea Pig Serum in Staphylococcus Infection in Mice

The Mechanism of Action of Immune Guinea Pig Serum in Staphylococcus Infection in Mice

Date: August 1958
Creator: Moore, James Walter
Description: It is the aim of this work to study the role, if any, of C'4 in the immune response against Staphylococcus aureus infections.
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Mechanisms Affecting Bench Press Throw Performance while Using a Counter-Balanced Smith Machine

Mechanisms Affecting Bench Press Throw Performance while Using a Counter-Balanced Smith Machine

Date: May 2011
Creator: Buddhadev, Harsh
Description: The use of a counter-balance weight system of a Smith machine affects measures of bench press throw performance. Twenty-four men performed bench press throws at 30% of their one-repetition maximum under four different conditions: 1) counter-balance and rebound movement (RC), 2) no counter-balance and rebound movement (RNC), 3) counter-balance and concentric only movement (CC), and 4) no counter-balance and concentric only movement (CNC). Peak power, force, and concentric and eccentric velocities were measured using a linear accelerometer; and peak ground reaction force (GRF) was measured using a forceplate. Peak measures for concentric and eccentric velocities showed that NCB> CB and RBT > CBT. Peak GRF measures showed CB > NCB and RBT > CBT. The lower performance measures for CB were likely due to an increase in the net external load when the barbell accelerates faster than the gravitational constant causing the counter-balance weight becomes ineffective.
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Mechanisms of Cyanide Assimilation in Pseudomonas fluorescens NCIMB 11764

Mechanisms of Cyanide Assimilation in Pseudomonas fluorescens NCIMB 11764

Date: August 1992
Creator: Nagappan, Olagappan
Description: Pseudomonas fluorescens NCIMB 11764 was capable of utilizing cyanide as a sole nitrogen source for growth. Cyanate (OCN") and S-cyanoalanine could also serve as nitrogenous substrates, but do not appear to play a role as intermediates in cyanide metabolism. Growth of this strain on cyanate as the sole nitrogen source led to the induction of an enzyme characterized as a cyanase (EC 3.5.5.3) based on its stoichiometric conversion of cyanate to ammonia, and dependence on bicarbonate for maximal activity. However, since cyanase activity was not elevated in cyanide-grown cells it was concluded that it serves no role in cyanide metabolism. Related studies aimed at examining a possible role for S-cyanoalanine as a cyanide-assimilation intermediate showed that while this compound also serves as a nitrogen source, it also is not important in cyanide metabolism. Studies focused on the utilization of free cyanide as a growth substrate led to the development of a fed-batch cultivation procedure greatly facilitating further experimentation aimed at the identification of cyanide metabolites. In addition to CO_2 and NH_3 as described earlier, two additional metabolites including formamide and formate were detected by using nC-NMR, HPLC, radioisotrapping methods and other analytical means. The formation of metabolites was shown to ...
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The Mechanisms of Methane C–h Activation and Oxy-insertion Via Small Transition Metal Complexes: a Dft Computational Investigation

The Mechanisms of Methane C–h Activation and Oxy-insertion Via Small Transition Metal Complexes: a Dft Computational Investigation

Date: May 2014
Creator: Prince, Bruce M.
Description: Our country continues to demand clean renewable energy to meet the growing energy needs of our time. Thus, natural gas, which is 87% by volume of methane, has become a hot topic of discussion because it is a clean burning fuel. However, the transportation of methane is not easy because it is a gas at standard temperature and pressure. The usage of transition metals for the conversion of small organic species like methane into a liquid has been a longstanding practice in stoichiometric chemistry. Nonetheless, the current two-step process takes place at a high temperature and pressure for the conversion of methane and steam to methanol via CO + H2 (syngas). The direct oxidation of methane (CH4) into methanol (CH3OH) via homogeneous catalysis is of interest if the system can operate at standard pressure and a temperature less than 250 C. Methane is an inert gas due to the high C-H bond dissociation energy (BDE) of 105 kcal/mol. This dissertation discusses a series of computational investigations of oxy-insertion pathways to understand the essential chemistry behind the functionalization of methane via the use of homogeneous transition metal catalysis. The methane to methanol (MTM) catalytic cycle is made up of two key ...
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Mechanisms of Methoxide Ion Substitution and Acid- Catalyzed Z/E Isomerization of N-Methoxyimines

Mechanisms of Methoxide Ion Substitution and Acid- Catalyzed Z/E Isomerization of N-Methoxyimines

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Date: December 2001
Creator: Dolliver, Debra D.
Description: The second order rate constants for nucleophilic substitution by methoxide of (Z)- and (E)-O-methylbenzohydroximoyl fluorides [C6H4C(F)=NOCH3] with various substituents on the phenyl ring [p-OCH3 (1h, 2h), p-CH3 (1g, 2g), p-Cl (1f, 2f), p-H (1e, 2e), (3,5)-bis-CF3 (1i, 2i)] in 90:10 DMSO:MeOH have been measured. A Hammett plot of these rate constants vs σ values gave positive ρ values of 2.95 (Z isomer) and 3.29 (E isomer). Comparison of these rates with methoxide substitution rates for Omethylbenzohydroximoyl bromide [C6H4C(Br)=NOCH3] and Omethylbenzohydroximoyl chloride [C6H4C(Cl)=NOCH3] reveal an element effect for the Z isomers of Br:Cl:F(1e) = 2.21:1.00:79.7 and for the E isomers of Cl:F(2e) = 1.00:18.3. With the p-OCH3-imidoyl halides the following element effects are found: Br:Cl:F(1h) = 2.78:1.00:73.1 for the Z isomer and Br:Cl:F(2h) = 1.97:1.00:12.1 for the E isomer. Measurement of activation parameters revealed ∆S≠ = -17 eu for 1e and ∆S≠ = -9.9 eu for 2e. Ab initio calculations (HF/6-31+G*, MP2/6-31+G*//HF/6-31+G*, B3LYP/6- 31+G*//HF/6-31+G*, HF-SCIPCM/6-31+G*//HF/6-31+G*) were performed to define the reaction surface. These calculations demonstrate a relatively large barrier for nucleophilic attack in relation to halogen loss and support the experimental findings that this reaction proceeds by an addition-elimination mechanism (AN# + DN). The imidoyl fluorides have been used to synthesize ...
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Mechanisms of Ordered Gamma Prime Precipitation in Nickel Base Superalloys

Mechanisms of Ordered Gamma Prime Precipitation in Nickel Base Superalloys

Date: May 2011
Creator: Singh, Antariksh Rao Pratap
Description: Commercial superalloys like Rene88DT are used in high temperature applications like turbine disk in aircraft jet engines due to their excellent high temperature properties, including strength, ductility, improved fracture toughness, fatigue resistance, enhanced creep and oxidation resistance. Typically this alloy's microstructure has L12-ordered precipitates dispersed in disordered face-centered cubic γ matrix. A typical industrially relevant heat-treatment often leads to the formation of multiple size ranges of γ¢ precipitates presumably arising from multiple nucleation bursts during the continuous cooling process. The morphology and distribution of these γ′ precipitates inside γ matrix influences the mechanical properties of these materials. Therefore, the study of thermodynamic and kinetic factors influencing the evolution of these precipitates and subsequent effects is both relevant for commercial applications as well as for a fundamental understanding of the underlying phase transformations. The present research is primarily focused on understanding the mechanism of formation of different generations of γ′ precipitates during continuous cooling by coupling scanning electron microscopy (SEM), energy filtered TEM and atom probe tomography (APT). In addition, the phase transformations leading to nucleation of γ′ phase has been a topic of controversy for decades. The present work, for the first time, gives a novel insight into the mechanism ...
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Mechanisms of rapid receptive field reorganization in rat spinal cord

Mechanisms of rapid receptive field reorganization in rat spinal cord

Date: August 2002
Creator: Vu, Hung
Description: Rapid receptive field (RF) reorganization of somatosensory neurons in the rat dorsal horn was examined using extracellular single unit recording. Subcutaneous injection of lidocaine into RFs of dorsal horn neurons results in expansion of their RFs within minutes. The expanded RFs appear adjacent to or/and proximal to original RFs. Out of 63 neurons tested, 36 (58%) show RF reorganization. The data suggest that dorsal horn of spinal cord is one of the initial sites for RF reorganization. The neural mechanisms of this effect are not well understood. We propose that changes in biophysical properties (membrane conductance, length constant) of the neurons resulting from lidocaine injection contribute to RF reorganization. Iontophoretic application of glutamate onto dorsal horn neurons that show lidocaine induced RF's expansion were used to test the model. Application of glutamate produced reduction of reorganized RFs in 9 of 20 (45%) tested cells. Application of NBQX produced no effect on either original or expanded RFs indicate that RF shrinkage effects of glutamate involve NMDA receptors. The results are consistent with the prediction of the proposed model. Subcutaneous injection of capsaicin into tactile RFs of low threshold mechanoreceptive dorsal horn neurons produced no effect on the RF sizes that are ...
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Mechanization of Aircraft Performance

Mechanization of Aircraft Performance

Date: 1956
Creator: Cotten, Frances Patterson
Description: The purpose of this paper is to describe the mechanization of the basic equations of motion for the performance and maneuver characteristics of an airplane with some simplifications which render solutions more practicable. The results of a study made to program these equations for calculation by the IBM MODEL 650 digital computer are presented as well as the steps to be taken in using this method of calculation.
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Medgar Evers (1925-1963) and the Mississippi Press

Medgar Evers (1925-1963) and the Mississippi Press

Date: December 1996
Creator: Tisdale, John Rochelle, 1958-
Description: Medgar Evers was gunned down in front of his home in June 1963, a murder that went unpunished for almost thirty years. Assassinated at the height of the civil rights movement, Evers is a relatively untreated figure in either popular or academic writing. This dissertation includes three themes. Evers's death defined his life, particularly his public role. The other two themes define his relationship with the press in Mississippi (and its structure), and his relationship to the various civil rights organizations, including his employer, the National Association for the Advancement of Colored People. Was the newspaper press, both state and national, fair in its treatment of Evers? Did the press use Evers to further the civil rights agenda or to retard that movement, and was Evers able to employ the press as a public relations tool in promoting the NAACP agenda? The obvious answers have been that the Mississippi press editors and publishers defended segregation and that Evers played a minor role in the civil rights movement. Most newspaper publishers and editorial writers slanted the news to promote segregation but not all newspapers editors. The Carters of Greenville, J. Oliver Emmerich of McComb and weekly editors Ira Harkey and Hazel ...
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Media and Corporate Social Responsibility: How Leading Business Magazines Frame a Controversial Concept

Media and Corporate Social Responsibility: How Leading Business Magazines Frame a Controversial Concept

Date: August 2013
Creator: Riddell, Brad
Description: Corporate social responsibility (CSR) is an emerging concept that continues to play a controversial role in the business world. Different CSR theories and ethical foundations inform different approaches to embedding socially responsible behavior into today's business functions. As technology, globalization, and economic challenges change the corporate world, the meaning and application of CSR also changes. While no empirical evidence of CSR's impact on performance exists, many corporations operate under the assumption that CSR holds significant value. This study examines the framing of CSR in stories published by leading business magazines between 2008 and 2012. By examining the presentation of CSR concepts, the resulting analysis can provide important conclusions for corporations, public relations practitioners, mass media, and consumers. This study resulted in a hierarchical pyramid of frames that organizes the framing of CSR in business magazines into three layers: category, motivation, and classification as either responsible behavior or irresponsible behavior. These results lead to recommendations for future CSR research, including the need for quantitative evidence of a connection or disconnection between CSR and profitability.
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