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Materials properties of ruthenium and ruthenium oxides thin films for advanced electronic applications.

Description: Ruthenium and ruthenium dioxide thin films have shown great promise in various applications, such as thick film resistors, buffer layers for yttrium barium copper oxide (YBCO) superconducting thin films, and as electrodes in ferroelectric memories. Other potential applications in Si based complementary metal oxide semiconductor (CMOS) devices are currently being studied. The search for alternative metal-based gate electrodes as a replacement of poly-Si gates has intensified during the last few … more
Date: May 2006
Creator: Lim, ChangDuk

Mechanical behavior and performance of injection molded semi-crystalline polymers.

Description: I have used computer simulations to investigate the behavior of polymeric materials at the molecular level. The simulations were performed using the molecular dynamics method with Lennard-Jones potentials defining the interactions between particles in the system. Significant effort was put into the creation of realistic materials on the computer. For this purpose, an algorithm was developed based on the step-wise polymerization process. The resulting computer-generated materials (CGMs) exhibit… more
Date: August 2003
Creator: Simoes, Ricardo J. F.

Nano-Manufacturing of Catalytic Amorphous Alloys

Description: In this dissertation, nano-manufacturing of amorphous alloys for electro-catalytic applications is reported and the role of chemistry and active surface area on catalytic behavior is discussed. The catalytic activity of recently developed platinum and palladium-based metallic glasses was studied using cyclic voltammetry and localized electrochemical techniques. The synergistic effect between platinum and palladium was shown for amorphous alloys containing both these elements. The mechanism for … more
Date: December 2019
Creator: Hasannaeimi, Vahid

Phase Transformation and Elastic Constants in Binary Titanium Alloys: An Atomistic Study

Description: The current understanding of the mechanical properties and deformation behavior of some individual phases in titanium alloys is limited due to the fine scale at which these phases precipitate within the β-phase matrix. The α and ω phases represent the most widely observed phases in titanium alloys depending on the alloy composition and also the heat treatment procedure adopted during processing. The possibility of precipitating ω-phase depends on the content of the β-stabilizers within the syst… more
Date: August 2019
Creator: Salloom, Riyadh Farooq

Phase Transformations in Refractory High Entropy Alloys

Description: High entropy alloys (HEAs) based on refractory elements have shown a great potential for high temperature structural applications. In particular, the ones containing Al, exhibits a microstructure similar to the γ-γ' in Ni-based superalloys. While these alloys exhibit impressive strengths at room temperature (RT) and at elevated temperatures, the continuous B2 matrix in these alloys is likely to be responsible for their brittle behavior at RT. Phase stability of five such alloys are studied by t… more
Date: August 2019
Creator: Soni, Vishal

Process-Structure-Property Relationships in Friction Stir Welded Precipitation Strengthened Aluminum Alloys

Description: Through a series of carefully designed experiments, characterization and some modeling tools, this work is aimed at studying the role of thermal profiles on different microstructural zones and associated properties like strength and corrosion through a variation of weld parameters, thermal boundary conditions and material temper. Two different alloys belonging to the Al-Cu and Al-Cu-Li system in different temper conditions- peak aged (T8) and annealed (O) were used. A 3D-thermal pseudo mechanic… more
Date: May 2019
Creator: Mondal, Barnali

Processing-Structure-Property Relationships of Reactive Spark Plasma Sintered Boron Carbide-Titanium Diboride Composites

Description: Sintering parameter effects on the microstructure of boron carbide and boron carbide/titanium diboride composites are investigated. The resulting microstructure and composition are characterized by scanning electron microscopy (SEM), x-ray microscopy (XRM) and x-ray diffraction (XRD). Starting powder size distribution effects on microstructure are present and effect the mechanical properties. Reactive spark plasma sintering introduces boron nitride (BN) intergranular films (IGF's) and their eff… more
Date: August 2019
Creator: Lide, Hunter

Study of Conductance Quantization by Cross-Wire Junction

Description: The thesis studied quantized conductance in nanocontacts formed between two thin gold wires with one of the wires coated by alkainthiol self assembly monolayers (SAM), by using the cross-wire junction. Using the Lorenz force as the driving force, we can bring the two wires in contact in a controlled manner. We observed conductance with steps of 2e2 / h. The conductance plateaus last several seconds. The stability of the junction is attributed to the fact that the coating of SAM improves the st… more
Date: May 2004
Creator: Zheng, Tao

Supercritical Silylation and Stability of Silyl Groups

Description: Methylsilsesquioxane (MSQ) and organosilicate glass (OSG) are the materials under this study because they exhibit the dielectric constant values necessary for future IC technology requirements. Obtaining a low-k dielectric value is critical for the IC industry in order to cope time delay and cross talking issues. These materials exhibit attractive dielectric value, but there are problems replacing conventional SiO2, because of their chemical, mechanical and electrical instability after plasma p… more
Date: May 2006
Creator: Nerusu, Pawan Kumar

Synthesis and Characterization of Crystalline Assemblies of Functionalized Hydrogel Nanoparticles

Description: Two series monodispersed nanoparticles of hydroxylpropyl cellulose (HPC) and functionalized poly-N-isopropylamide (PNIPAM) particles have been synthesized and used as building blocks for creating three-dimensional networks, with two levels of structural hierarchy. The first level is HPC nanoparticles were made from methacrylated or degradable cross-linker attached HPC. These nanoparticles could be stabilized at room temperature by residual methacrylate or degradable groups are present both with… more
Date: December 2005
Creator: Cai, Tong

Understanding the Micromechanism of Cyclic Loading Behavior of Ultrafine Grained Alloys

Description: In the current study, we have investigated the cyclic loading behavior of conventional as well as novel alloy system exhibiting fine and ultrafine-grained structure. While in case of conventional alloy systems (here aluminum alloy AA5024), the effect of three different grain sizes was investigated. Improvement in fatigue properties was observed with decreasing grain size. The unique microstructure produced via Friction stir processing was responsible for the improved fatigue response. Additiona… more
Date: August 2019
Creator: Shukla, Shivakant
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