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The Effects of Jackpots on Responding and Choice in Two Domestic Dogs
The current study investigated the impact of delivering a jackpot on response rate and response allocation in two domestic dogs. For the purpose of this research, a jackpot was defined as a one-time, within-session increase in the magnitude of reinforcement. Two experiments were conducted to investigate the effects of delivering a jackpot in both single-operant and concurrent schedule procedures. Experiment 1 investigated the impact of a one-time, within-session increase in the magnitude of reinforcement on response rate in a single-operant procedure. Results of Experiment 1 showed no clear change in response rate after the delivery of the jackpot. Experiment 2 investigated the impact of a one-time, within-session increase in the magnitude of reinforcement on response allocation in a concurrent schedule procedure. Results of Experiment 2 showed an increase in response allocation to the jackpotted contingency in both subjects. These results suggest that a jackpot, as defined here, has no effect in single-operant procedures while having an effect in concurrent schedule procedures. These effects are similar to those reported in the magnitude of reinforcement literature. digital.library.unt.edu/ark:/67531/metadc28456/
Maleic anhydride grafted polypropylene coatings on steel: Adhesion and wear.
Polymeric coatings are being used in a growing number of applications, contributing to protection against weather conditions and localized corrosion, reducing the friction and erosion wear on the substrate. In this study, various polypropylene (PP) coatings were applied onto steel substrates by compression molding. Chemical modification of PP has been performed to increase its adhesion to metallic surfaces by grafting of maleic anhydride (MAH) onto PP in the presence of dicumyl peroxide (DCP). Influence of different concentrations of MAH and DCP on the properties of resulting materials have been examined. The coated steel samples are characterized by scanning electron microscopy (SEM), shear adhesion testing, FTIR and tribometry. The coatings with 3 wt. % MAH have shown the maximum adhesion strength due to maximum amount of grafting. The wear rates increased with increasing the amount of MAH due to simultaneous increase in un-reacted MAH. digital.library.unt.edu/ark:/67531/metadc28452/
An Assessment of Undergraduate Course Syllabi in the Departments of English at Universities in Taiwan
This exploratory, qualitative research explored the extent that course syllabi in the Departments of English in 13 public and 9 private universities in Taiwan reflect the inclusion of syllabus components to promote learning as recommended in the literature in the United States. Research questions included: what components can be inferred from the literature in the U.S. for the recommended components of a course syllabus, for the components for a learning-centered syllabus, and for a model to analyze Bloom's cognitive level of learning? And when these are applied to analyze course syllabi in English courses, are syllabi in these universities congruent with the models? The research identified and analyzed 235 course syllabi from the core courses listed online at these universities. The findings indicated that these syllabi are highly congruent with the syllabus components template; 68% of the syllabi included seven or more of the ten components. Additionally, these syllabi reflect medium congruency with the learning-centered syllabus template. Verbs used in objectives and learning outcomes in different English courses indicate different levels of cognitive learning goals as identified by Bloom's cognitive domain. Additional findings indicate that there was no difference in inclusion of components based on where faculty earned their doctoral degree. This research assumed similarities between higher education in Taiwan and the U.S., conclusions indicate that the course syllabi in Departments of English in Taiwan are congruent with the models recommended in the literature in the U.S. digital.library.unt.edu/ark:/67531/metadc28451/
A Performer's Analysis of Dominick Argento's Miss Havisham's Wedding Night
Dominick Argento's Miss Havisham's Wedding Night is the least explored of his artistic output. A monodrama in one act for soprano, Miss Havisham's Wedding Night contains some of Argento's most beautiful and challenging music of his compositional output. The purpose of a detailed analysis of the structure and content of Argento's Miss Havisham's Wedding Night is to facilitate the solo vocal performer's interpretation. Argento's setting of Miss Havisham's Wedding Night is unique in that he musically translates the manic psychological state of the literary character. Argento structured the one act opera in such a manner that the music would illuminate the text and the audience might connect with the unstable psychological episodes and outbursts demonstrated by Miss Havisham. To that end, each section and phrase has its own psychological motivation, which in turn demands a varied musical and dramatic interpretation. Utilizing selected scenes from Miss Havisham's Wedding Night, the researcher will analyze Argento's musical manifestation of Dickens's literary work. This research will include an investigation into the manner in which Argento uses the shape of melody and the musical phrase along with the harmonic materials to enhance the text and dramatic content. The author will explore the musical nuances Argento incorporates in an effort to develop and portray Miss Havisham's psychological state. Through an analysis of the orchestral writing the author will show how Argento's aesthetic balance between the music and text represents the emotional and psychological implications of the monodrama. digital.library.unt.edu/ark:/67531/metadc28455/
Optimal design of Dutch auctions with discrete bid levels.
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The theory of auction has become an active research area spanning multiple disciplines such as economics, finance, marketing and management science. But a close examination of it reveals that most of the existing studies deal with ascending (i.e., English) auctions in which it is assumed that the bid increments are continuous. There is a clear lack of research on optimal descending (i.e., Dutch) auction design with discrete bid levels. This dissertation aims to fill this void by considering single-unit, open-bid, first price Dutch auctions in which the bid levels are restricted to a finite set of values, the number of bidders may be certain or uncertain, and a secret reserve price may be present or absent. These types of auctions are most attractive for selling products that are perishable (e.g., flowers) or whose value decreases with time (e.g., air flight seats and concert tickets) (Carare and Rothkopf, 2005). I began by conducting a comprehensive survey of the current literature to identify the key dimensions of an auction model. I then zeroed in on the particular combination of parameters that characterize the Dutch auctions of interest. As a significant departure from the traditional methods employed by applied economists and game theorists, a novel approach is taken by formulating the auctioning problem as a constrained mathematical program and applying standard nonlinear optimization techniques to solve it. In each of the basic Dutch auction model and its two extensions, interesting properties possessed by the optimal bid levels and the auctioneer's maximum expected revenue are uncovered. Numerical examples are provided to illustrate the major propositions where appropriate. The superiority of the optimal strategy recommended in this study over two commonly-used heuristic procedures for setting bid levels is also demonstrated both theoretically and empirically. Finally, economic as well as managerial implications of the findings reported in this dissertation research are discussed. digital.library.unt.edu/ark:/67531/metadc28450/
Luke's Mama
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A creative nonfiction thesis, Luke's Mama is a memoir of personal essays that explore how the birth of my son has affected the ways that I relate within and interpret different areas of my life. Chapter I, Introduction, identifies personal and ethical concerns involved in telling my story and explores how others have handled similar issues. Chapter II, Family, illustrates how my relationship with my family of origin has changed since I've become a parent and also how my new family and I interact with society. Chapter III, Calling, depicts my struggle in finding a balance between work and family priorities. Chapter IV, Partner, presents a contrast between my relationship with my partner before and after my son's birth. Chapter V, Parent, displays the beginning of my ever-growing relationship with my son and sense of parenthood. digital.library.unt.edu/ark:/67531/metadc2845/
Identification of highly gifted 5- and 6-year-old children: Measures to predict academic achievement.
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Studies indicate the educational needs of highly gifted students are best met through accelerated learning. It is difficult to recognize very young children that are suited for an accelerated curriculum because younger students frequently lack school records or portfolios used to identify gifted students. This study examined the accuracy of cognitive ability and achievement tests in predicting academic achievement by the end of second grade, correlating test results and final grade averages collected from sixteen children ages five to six who entered a public school program for high-ability learners in kindergarten. A multiple regression analysis indicated the Wechsler Preschool and Primary Scale of Intelligence produced the highest mean IQ score and a strong correlation with reading achievement. The Wechsler Individual Achievement Test contributed in small part to the prediction of academic achievement. The Naglieri Nonverbal Ability Test and the Kaufman Brief Intelligence Test-Second Edition had negative correlations with final grade averages, indicating they are not predictors of academic achievement for these students. digital.library.unt.edu/ark:/67531/metadc28471/
An Analysis of Interrater Agreement Between the Motivation Assessment Scale (MAS), Questions About Behavioral Function (QABF), and Analog Assessment Outcomes
An analysis of interrater agreement across multiple respondents on anecdotal assessments was compared with experimental functional analysis outcomes for correspondence. Experiment 1 evaluated the agreement of multiple respondents on the function of problem behavior for 22 individuals across 42 target behaviors using the Motivation Assessment Scale (MAS) and the Questions About Behavioral Function (QABF). Results showed agreement on the primary maintaining consequence for 4 or 5 of the 5 respondents in 52% (22/42) of the individual's target behaviors with the MAS and 57% (24/42) with the QABF. Experiment 2 examined whether correspondence occurred between the anecdotal assessment results and experimental functional analysis (EFA) results for 7 individuals selected from Experiment 1. Correspondence between the QABF assessment and the EFA was found for 6 of 7 participants, and 4 of the 7 showed correspondence between the EFA and the MAS. This study showed that the QABF had higher correspondence with analog assessments than the MAS thus, supporting the previous findings of Paclawskyj et al. (2001). digital.library.unt.edu/ark:/67531/metadc28477/
Rail Transit and Its Influence on Land Use: A Dallas Case Study
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Mass transit investments continue to be utilized in many cities as means of dealing with various transportation issues. In Dallas Texas, light rail transit was developed with the hopes of encouraging compact and orderly growth. This research uses the DART system as a case study in examining transportation/land use relationships in Dallas. As such, this thesis reviews past research that examined transit systems impacts on urban areas, analyzes historical changes in land use pattern development around the existing twenty stations of the DART light rail starter system, and summarizes the progression of land use trends in the transit corridor as they relate to DART impacts. Results of this study suggest that DART's light rail system has been an effective tool used in achieving the transportation and land use goals for the region. Finally, recommendations are presented with respect to what can be expected for future light rail development in Dallas. digital.library.unt.edu/ark:/67531/metadc2847/
Daughters of the King and Founders of a Nation: Les Filles du Roi in New France
The late seventeenth century was a crucial era in establishing territorial claims on the North American continent. In order to strengthen France's hold on the Quebec colony, Louis XIV sent 770 women across the Atlantic at royal expense in order to populate New France. Since that time, these women known as the filles du roi, have often been reduced to a footnote in history books, or else mistakenly slandered as women of questionable morals. This work seeks to clearly identify the filles du roi through a study of their socioeconomic status, educational background, and various demographic factors, and compare the living conditions they had in France with those that awaited them in Canada. The aim of this undertaking is to better understand these pioneer women and their reasons for leaving France, as well as to identify the lasting contributions they made to French-Canadian culture and society. digital.library.unt.edu/ark:/67531/metadc28470/
Examining the Origins of Sociology: Continuities and Divergences Between Ibn Khaldun, Giambattista Vico, August Comte, Ludwig Gumplowicz, and Emile Durkheim
This thesis examines the extent to which Ibn Khaldun can legitimately be considered a founding father of sociology. To pursue this research, Khaldun's theoretical framework will be compared with four Western scholars: Auguste Comte, Emile Durkheim, Giambattista Vico, and Ludwig Gumplowicz. This paper begins with an Introduction (Chapter I), followed by a general overview of Khaldun's work (Chapter II). Next, Khaldun's work is compared to that of Auguste Comte (Chapter III), Emile Durkheim (Chapter IV), Ludwig Gumplowicz (Chapter V) and Giambattista Vico (Chapter VI). In each of these chapters, Khaldun is compared and contrasted to the other social theorist, illustrating their similarities and considering their differences. Finally, in Chapter VII, I put forth conclusions that consider the extent to which Khaldun can validly be considered a founding father of sociology. digital.library.unt.edu/ark:/67531/metadc28478/
The Legacy of Theodore Leschetizky as Seen through His Pedagogical Repertoire and Teaching Style
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Theodore Leschetizky's singular pianistic legacy survives to this day because of his revolutionary pedagogical methods and his compositions for the piano repertory. The amalgamation of these two aspects formed his distinctive contributions to the fields of piano and piano pedagogy and left an indelible mark on the history of the instrument. His students lead an impressive list of the greatest artists of the previous century, each influencing the evolution of pianism with their own remarkable style and personality. While Leschetizky was arguably without peer as a pedagogue, many pianists today are unaware of the vast number of compositions that he wrote. These pieces were intended not only for the concert stage, but also as a very specific pedagogical repertoire that he used within his own teaching studio. This repertoire comprises a vital component of the Leschetizky legacy, albeit one which is often slighted in comparison. It is imperative that the pianists of our current generation understand the dual aspects of his contribution to our art form, in order to fully grasp the way in which he has changed the face of pianism. The purpose of this dissertation and lecture recital is to enumerate the various aspects that constitute the dual components of Leschetizky's pianistic legacy. For pedagogues of the current generation, it is of vital importance that we understand not only our own personal pedagogical lineage, but the various other individuals that, through their contributions, have led us to where we are in our understanding of the instrument. What is needed in the current research on this subject is one individual source that not only documents the characteristics of a pedagogical genius, but explores the legacy he left for future generations through documented accounts of his students and the examination of his own unfamiliar, pedagogical repertoire for the piano. digital.library.unt.edu/ark:/67531/metadc28474/
A Study of Student's Perceptions of Blended Learning Environments at a State-Supported Postsecondary Institution
The purpose of this study was to conduct exploratory research regarding students' perceptions of blended learning environments at a state supported postsecondary institution. Specifically investigated were students' overall perceptions of blended learning environments, the reasons they chose to take a blended course, and whether generational differences existed in students' affected perceptions. An electronic survey was distributed to students enrolled in blended learning courses at the end of the spring 2009 term. digital.library.unt.edu/ark:/67531/metadc28475/
161 Glass: Site Specific Music in an Artistic Context
The composition 161 Glass is a 17-minute musical work with percussion, wind and brass instruments in which the intersection of mid-century architecture, and the art and culture of a dynamic city are inextricably linked. Through this paper, I explore the process of composing a musical work in relationship to the significance of site specific context. The paper begins by defining the concept of site specific art works; then reviews the discourse of the intersection of art, music and architecture. I then delve into the cultural and geographic context surrounding this project from the modern era through the present, and how those perspectives apply to the building and my piece. I reveal how the composition relates the musical ideas to the site. Finally, I describe the collaborative process between myself, the musicians and the Dallas Contemporary staff. digital.library.unt.edu/ark:/67531/metadc28472/
Retirees' Attitudes Toward Mental Illness Treatment: A Life-Course Perspective
This purpose of this dissertation was to examine the attitudes of retirees toward mental illness treatment. Secondary data from the Survey Research Center at the University of North Texas was utilized for this study. The focus was on the influence that gender, income, education, race/ethnicity, personal experience, fear, goodwill, and social control might have had on retirees' attitudes toward mental illness treatment. An n = 225 was selected out of the existing data to serve as the sample population. Binary logistic regression was utilized to analyze the data. Results indicated that the obtained significant findings were consistent with existing literature. digital.library.unt.edu/ark:/67531/metadc28479/
Determining Factors that Influence High School Principal Turnover Over a Five Year Period
The purpose of this study was to determine the effects of salary, compensation and benefits, accountability, job stress, increased instructional responsibilities, changes in student demographics, lack of support, politics, advancement opportunities and promotion on tenure and turnover among high school principals in the state of Texas. The participants in the study included 60 Texas high school principals who left a high school principalship for a different high school principalship within the past 5 years. The participants completed the Texas Principal Survey and data were analyzed using binary logistic regression. The data indicated that salary, compensation and benefits was a significant factor in predicting an increase in the odds of principal turnover for principals who had been in their prior principalship 5 or more years over principals who had been in their prior principalship less than 5 years. Additionally, advancement opportunities was a significant factor in predicting a decrease in the odds of principal turnover for principals who had been in their prior principalship 5 or more years over principals who had been in their prior principalship less than 5 years. Responses from an open ended question asking principals why they left their prior principalship suggested that principals left for reasons including new challenges, lack of support and family. The results of this study support the need for continued research in the area of principal turnover and provide insight to district superintendents, school boards and principals. digital.library.unt.edu/ark:/67531/metadc28476/
Microwave-Assisted Synthesis, Characterization, and Photophysical Properties of New Rhenium(I) Pyrazolyl-Triazine Complexes
The reaction of the chelating ligand 4-[4,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazin-2-yl]-N,N-diethyl-benzenamine, L, with pentacarbonylchlororhenium by conventional heating method produces the complexes fac-[ReL(CO)3Cl2] and fac-[Re2L(CO)6Cl2] in a period of 48 hours. The use of microwaves as the source of heat and the increase in the equivalents of one of the reactants leads to a more selective reaction and also decreases the reaction time to 1 hour. After proper purification, the photophysical properties of fac-[ReL(CO)3Cl] were analyzed. The solid-state photoluminescence analysis showed an emission band at 628 nm independent of temperature. However, in the solution studies, the emission band shifted from 550 nm in frozen media to 610 nm when the matrix became fluid. These results confirm that this complex possess a phenomenon known as rigidochromism. digital.library.unt.edu/ark:/67531/metadc28473/
X, An Analytical Approach to John Chowning's Phoné
The analysis of computer music presents new challenges to the field of music theory. This study examines the fixed media composition Phoné by John Chowning from its aesthetic perspective, compositional theory and computer sound synthesis techniques. Fast Fourier Transform analyses are used to create spectrograms. The findings from the spectrograms are juxtaposed with compositional philosophies of John Chowning, Jean-Claude Risset, Pierre Schaeffer and Arnold Schoenberg and the techniques are represented via PureData patches. digital.library.unt.edu/ark:/67531/metadc28445/
Use of GIS to Identify and Delineate Areas of Fluoride, Sulfate, Chloride, and Nitrate Levels in the Woodbine Aquifer, North Central Texas, in the 1950s, 1960s, 1970s, 1980s, and 1990s
ArcView and ArcInfo were used to identify and delineate areas contaminated by fluoride, sulfate, chloride, and nitrate in the Woodbine Aquifer. Water analysis data were obtained from the TWDB from the 1950s to 1990s covering 9 counties. 1990s land use data were obtained to determine the relationship with each contaminant. Spearman's rank correlation coefficients and Kruskal-Wallis tests were used to calculate relationships between variables. Land uses had little effect on distributions of contaminants. Sulfate and fluoride levels were most problematic in the aquifer. Depth and lithology controlled the distributions of each contaminant. Nitrate patterns were controlled mainly by land use rather than geology, but were below the maximum contaminant level. In general, contaminant concentrations have decreased since the 1950s. digital.library.unt.edu/ark:/67531/metadc2869/
Three Topics in Descriptive Set Theory
This dissertation deals with three topics in descriptive set theory. First, the order topology is a natural topology on ordinals. In Chapter 2, a complete classification of order topologies on ordinals up to Borel isomorphism is given, answering a question of Benedikt Löwe. Second, a map between separable metrizable spaces X and Y preserves complete metrizability if Y is completely metrizable whenever X is; the map is resolvable if the image of every open (closed) set in X is resolvable in Y. In Chapter 3, it is proven that resolvable maps preserve complete metrizability, generalizing results of Sierpiński, Vainštein, and Ostrovsky. Third, an equivalence relation on a Polish space has the Laczkovich-Komjáth property if the following holds: for every sequence of analytic sets such that the limit superior along any infinite set of indices meets uncountably many equivalence classes, there is an infinite subsequence such that the intersection of these sets contains a perfect set of pairwise inequivalent elements. In Chapter 4, it is shown that every coanalytic equivalence relation has the Laczkovich-Komjáth property, extending a theorem of Balcerzak and Głąb. digital.library.unt.edu/ark:/67531/metadc28441/
Adaptive Advantages of Carotenoid Pigments in Alpine and Subalpine Copepod Responses to Polycyclic Aromatic Hydrocarbon Induced Phototoxicity
Alpine zooplankton are exposed to a variety of stressors in their natural environment including ultraviolet radiation. Physiological coping mechanisms such as the accumulation of photoprotective compounds provide these zooplankton protection from many of these stressors. Elevated levels of carotenoid compounds such as astaxanthin have been shown to help zooplankton survive longer when exposed to ultraviolet radiation presumably due to the strong antioxidant properties of carotenoid compounds. This antioxidant capacity is important because it may ameliorate natural and anthropogenic stressor-induced oxidative stress. While previous researchers have shown carotenoid compounds impart increased resistance to ultraviolet radiation in populations of zooplankton, little work has focused on the toxicological implications of PAH induced phototoxicity on zooplankton containing high levels of carotenoid compounds. This thesis discusses research studying the role that carotenoid compounds play in reducing PAH induced phototoxicity. By sampling different lakes at elevations ranging from 9,500' to 12,700' in the front range of the Colorado Rocky Mountains, copepod populations containing different levels of carotenoid compounds were obtained. These populations were then challenged with fluoranthene and ultraviolet radiation. Results discussed include differences in survival and levels of lipid peroxidation among populations exhibiting different levels of carotenoid compounds, and the toxicological and ecological implications of these results. digital.library.unt.edu/ark:/67531/metadc28444/
A Possible Role of Ascorbate in Boron Deficient Radish (Raphanus sativa L. cv. Cherry Belle)
The most apparent symptom of boron deficiency in higher plants is a cessation of growth. Deficiency causes a reduction in ascorbate concentration and the absorption of nutrient ions. Addition of ascorbate temporarily relieves deficiency symptoms. In boron sufficient plants the addition of ascorbate to media causes an increased uptake of nutrients. In an attempt to discover if ascorbate addition to deficient plants causes increased ion uptake, radish plants were grown hydroponically in four different strengths of boron solution. A colorimetric assay for phosphorus was performed both before and after supplementation. Results, however, were inconclusive. digital.library.unt.edu/ark:/67531/metadc2867/
Similarities in the Use of Dramatic Recitative Style in the Music of Claudio Monteverdi and Giuseppe Verdi, with Some Performance-Practice Issues
The objective of this dissertation, inspired by performance experience, was to establish the similarities in the use of recitative style in the music of Claudio Monteverdi and Giuseppe Verdi. To achieve this objective, their use of recitative style was examined through comparative analysis of four scenes from their operas: “Arianna's Lament” from L'Arianna and “Disprezzata regina” from L'incoronazione di Poppea by Monteverdi, and “Condotta ell'era in ceppi” from Il trovatore and “Judgment Scene” from Aida by Verdi. The examination of the similarities included a discussion of the following: (a) the historical influences and cultural backgrounds of the composers; (b) general similarities in their compositional approaches to recitative style; (c) comparable characteristics of the dramatic recitative style in the early Baroque monody and in Verdi's operas; (d) similarities in musical characterization and expression of affective and emotional content through stylistic musical devices; (e) similarities in the composers' approaches to vocal and acting issues with special emphasis on the problems of diction; and (f) some related performance-practice issues. A discussion of the poetic lament and the influence of its form and content on musical setting was also a part of this research. The comparative research revealed numerous similarities in the historical circumstances influencing Monteverdi's and Verdi's choice of musical styles; their motivation; formal and stylistic characteristics of their dramatic recitative scenes; their choice of libretto; their use of the elements of lament; their musical treatment of emotional content of the text; and their prerogatives in vocal and acting issues. Numerous similar characteristics were also established regarding vibrato, tempo, rhythm, and ornamentation in the performance practice of the early Baroque recitative soliloquy and Verdi's dramatic recitative scenes. The similarities of the four scenes' functions, topics, form, and characterization through devices of musical style indicated a fundamental continuity in the development of Italian opera from its inception to the end of the nineteenth century. digital.library.unt.edu/ark:/67531/metadc2880/
The regulatory roles of PyrR and Crc in pyrimidine metabolism in Pseudomonas aeruginosa
The regulatory gene for pyrimidine biosynthesis has been identified and designated pyrR. The pyrR gene product was purified to homogeneity and found to have a monomeric molecular mass of 19 kDa. The pyrR gene is located directly upstream of the pyrBC' genes in the pyrRBC' operon. Insertional mutagenesis of pyrR led to a 50- 70% decrease in the expression of pyrBC', pyrD, pyrE and pyrF while pyrC was unchanged. This suggests that PyrR is a positive activator. The upstream regions of the pyrD, pyrE and pyrF genes contain a common conserved 9 bp sequence to which the purified PyrR protein is proposed to bind. This consensus sequence is absent in pyrC but is present, as an imperfect inverted repeat separated by 11 bp, within the promoter region of pyrR. Gel retardation assays using upstream DNA fragments proved PyrR binds to the DNA of pyrD, pyrE, pyrF as well as pyrR. This suggests that expression of pyrR is autoregulated; moreover, a stable stem-loop structure was determined in the pyrR promoter region such that the SD sequence and the translation start codon for pyrR is sequestered. β-galactosidase activity from transcriptional pyrR::lacZ fusion assays, showed a two-fold in increase when expressed in a pyrR- strain compared to the isogenic pyrR+ strain. Thus, pyrR is negatively regulated while the other pyr genes (except pyrC) are positively activated by PyrR. That no regulation was seen for pyrC is in keeping with the recent discovery of a second functional pyrC that is not regulated in P. aeruginosa. Gel filtration chromatography shows the PyrR protein exists in a dynamic equilibrium, and it is proposed that PyrR functions as a monomer in activating pyrD, pyrE and pyrF and as a dimeric repressor for pyrR by binding to the inverted repeat. A related study discovered that the catabolite repression control (Crc) protein was indirectly involved in pyr gene regulation, and shown to negatively regulate expression of PyrR at the posttranscriptional level. digital.library.unt.edu/ark:/67531/metadc2875/
Polyamide-imide and Montmorillonite Nanocomposites
Solvent suspensions of a high performance polymer, Polyamide-imide (PAI) are widely used in magnetic wire coatings. Here we investigate the effect that the introduction of montmorillonite (MMT) has on PAI. MMT was introduced into an uncured PAI suspension; the sample was then cured by step-wise heat treatment. Polarized optical microscopy was used to choose the best suitable MMT for PAI matrix and to study the distribution of MMT in PAI matrix. Concentration dependent dispersion effect was studied by x-ray diffraction (XRD) and was confirmed by Transmission electron microscopy (TEM). Differential scanning Calorimetry (DSC) and Thermogravimetric analysis (TGA) was used to study impact of MMT on glass transition temperature (Tg) and degradation properties of PAI respectively. Micro-hardness testing of PAI nanocomposites was also performed. A concentration dependent state of dispersion was obtained. The glass transition (Tg), degradation and mechanical properties were found to correlate to the state of dispersion. digital.library.unt.edu/ark:/67531/metadc2873/
Teaching Points in Comparing the Great Depression to the 2008-2009 Recession in the United States
For an introductory macroeconomics course, the discussion of historical relevance helps foster important learning connections. By comparing the Great Depression to the 2008-2009 recession, a macroeconomics instructor can provide students with connections to history. This paper discusses the major causes of each recession, major fiscal policy and monetary policy decisions of both recessions, and the respective relevance in teaching the relationship of each policy to gross domestic product. The teaching points addressed in this paper are directed towards an introductory college-level macroeconomics course, incorporating a variety of theories from historical and economic writers and data from government and central bank sources. A lesson plan is included in an appendix to assist the instructor in implementing the material. digital.library.unt.edu/ark:/67531/metadc28442/
Hispanic Representation in the Superintendency: Perceived Competencies and Organizational Outcomes That Benefit School Districts
This study assessed 40 factors often cited in literature to determine the extent that Hispanic superintendents perceive them as influential when accessing the superintendency. Eight Hispanic superintendents in Texas participated in this qualitative study, which was based on interviews as well as written responses to a survey. This study found that the factors considered most influential to these superintendents were their ability to communicate, self-perception/self-efficacy, and level of overall preparedness. These findings contrast with previous research indicating that race or ethnicity, mentoring, and career path are most influential. The study also identified factors related to race and ethnicity that most influenced a Hispanic's ability to access the superintendency, albeit to a lesser degree. These factors were the ability to serve as a Hispanic role model to students, ability to increase Hispanic students' academic performance, and the ability to speak a second language. Moreover, through analysis of a large number of survey responses the study examined the extent to which a superintendent's race or ethnicity is significant to addressing the needs of Hispanics. To assure this question a comparative analysis of Hispanics' and non-Hispanics competencies and organizational outcome was conducted. The results indicate that superintendents, in general, regardless of race or ethnicity, can acquire knowledge about the Hispanic culture, develop cultural competence, and produce outcomes that affect Hispanics. A Hispanic, however, who possesses the ability to speak Spanish and has authentic cultural experiences, can potentially provide unique competencies in serving Hispanics. Cultural competence with Hispanics, however, does not supersede the importance of a superintendent's overall effectiveness and ability to meet the needs of all students. Whereas other studies have addressed the significance of cultural competency in other institutions that serve the public, such as the healthcare industry, this study addressed cultural competency in public education. Progressive definitions of cultural competency included the extent to which outcomes met constituent needs for measuring cultural competency. The overall findings in this study suggest a need to develop preparation programs that result in culturally competent leaders, a need to revise state required certification requirements to reflect a need for cultural competence, and a need to revise locally-developed job postings/descriptions to indicate that the superintendent must provide culturally competent leadership. digital.library.unt.edu/ark:/67531/metadc283806/
Repetition and Difference: Parodic Narration in Kander and Ebb's "The Scottsboro Boys"
The American musical team John Kander and Fred Ebb created many celebrated works, yet musicologists have carried out little research on those works. This study examines the role of music in the parodic narration of Kander and Ebb's final collaboration, The Scottsboro Boys. Kander and Ebb use minstrelsy to tell the story of the historic Scottsboro Boys trials with actors portraying the Scottsboro Boys as minstrels; at the same time, they employ a number of devices to subvert minstrelsy stereotypes and thereby comment on racism. Drawing on African American literary theory, sociolinguistics, and Bakhtin's dialogism, this study illuminates how Signifyin(g), a rhetorical tradition used to encode messages in some African American communities, is the primary way the actors playing the Scottsboro Boys subvert through minstrelsy. This study not only contributes to the discussion of Signifyin(g) in African American musicals and theatre as a tool of subversion, but also provides an example of non-African American creators—Kander and Ebb—using Signifyin(g) devices. They use these in the music and the book; in particular, Kander and Ebb do some Signifyin(g) on Stephen Foster's plantation melodies. digital.library.unt.edu/ark:/67531/metadc283804/
Metabolic Engineering in Plants to Control Source/sink Relationship and Biomass Distribution
Traditional methods like pruning and breeding have historically been used in crop production to divert photoassimilates to harvested organs, but molecular biotechnology is now poised to significantly increase yield by manipulating resource partitioning. It was hypothesized that metabolic engineering in targeted sink tissues can favor resource partitioning to increase harvest. Raffinose Family Oligosaccharides (RFOs) are naturally occurring oligosaccharides that are widespread in plants and are responsible for carbon transport, storage and protection against cold and drought stress. Transgenic plants (GRS47, GRS63) were engineered to generate and transport more RFOs through the phloem than the wild type plants. The transgenic lines produced more RFOs and the RFOs were also detected in their phloem exudates. But the 14CO2 labeling and subsequent thin layer chromatography analysis showed that the RFOs were most likely sequestered in an inactive pool and accumulate over time. Crossing GRS47 and GRS63 lines with MIPS1 plants (that produces more myo-inositol, a substrate in the RFO biosynthetic pathway) did not significantly increase the RFOs in the crossed lines. For future manipulation of RFO degradation in sink organs, the roles of the endogenous α-galactosidases were analyzed. The alkaline α-galactosidases (AtSIP1 and AtSIP2 in Arabidopsis) are most likely responsible for digesting RFOs in the cytoplasm and may influence the ability to manipulate RFO levels in engineered plants. Atsip1/2 (AtSIP1/AtSIP2 double-knockout plants) were generated and phenotypically characterized based on seed germination patterns, flowering time, and sugar content to observe the impact on RFO sugar levels. The observations and analysis from these lines provide a basis for further insight in the manipulation of resource allocation between source and sink tissues in plants for future research. digital.library.unt.edu/ark:/67531/metadc283836/
By Air Power Alone: America's Strategic Air War in China, 1941-1945
During World War II, the Army Air Force waged three strategic air offensives in and from China against Japan. At first, the Flying Tigers and 10th Air Force constituted the whole of American aid to China, but the effort soon expanded. Supported by Chiang Kai-shek, Claire Chennault and his 14th Air Force waged an anti-shipping campaign, to which the Japanese Imperial Army responded with Operation Ichigo and against which Joseph Stilwell accurately warned. 20th Bomber Command used B-29s to wage Operation Matterhorn, failed, and later conducted PACAID missions. 14th Air Force then waged a counterproductive transportation campaign as The Pacific War, also known as the Greater East Asian War, ended. Events in the China-Burma-India and China Theaters provide lessons in logistics, targeting, training, and air-ground cooperation that are applicable in the post-Cold War era. digital.library.unt.edu/ark:/67531/metadc2800/
The Role of Attachment in Perceptions of Interparental Conflict and Behavior Problems in Middle Childhood
The current study investigated the association of interparental conflict, parent-child attachment, and children's behavior problems in middle childhood. Although the effects of interparental conflict have been studied extensively, there has been little research done in the developmental period of middle childhood. This study examined the potential mediating role of the attachment relationship between parents and children in a community sample consisting of 86 two-parent families with at least one child between the ages of 8-11. Path modeling procedures indicated that attachment security serves as a mediator between interparental conflict and child behavior problems based on child reports. In particular, child-reported attachment security to the mother significantly mediated the association between children's perceptions of threat from interparental conflict and child-reported internalizing and inattentive/hyperactive symptoms. Child-reported attachment security to the father was not a significant mediator and mediation was not supported in parent-report models. The current findings have implications for families experiencing conflict and speak to the importance of attachment in the parent-child relationship when explaining the association between instances of interparental conflict and child behavioral outcomes. In particular, parents who engage in conflict can prevent the damaging effects of that conflict by making the conflict less overt, explaining to children the reasons for the conflict, and providing children with some assurance that a secure parent-child and interparental relationship is still present, despite the conflict. digital.library.unt.edu/ark:/67531/metadc283822/
Learner-to-Learner: Refocusing the Lens of Educational Immediacy
As the current body of instructional communication research focuses primarily on the relationship between teacher and learner, three studies investigating the relationship between learners were completed in order to better understand how student motivation and learning are influenced by learner-to-learner immediacy behaviors within the college classroom environment. Study I resulted in an extensive list of both positive and negative verbal and nonverbal immediacy behaviors commonly used by learners. Study II required the comparison of the behaviors identified in study one to existing measures of teacher to learner immediacy behaviors, producing a new measure focusing on learner-to-learner immediacy. Following a pilot survey, the reliability of this new measure was determined through face validity and factor analysis, producing the Learner-to-Learner Immediacy Behavior Scale. In Study III, the Learner-to-Learner Immediacy Behavior Scale was combined with Christophel's 1990 Immediacy Behavior Scale, Cognitive Learning Scale, Affective Learning Scale, and Trait and State Motivation Scales and administered to 273 undergraduate students to test the affects of common learner-to-learner immediacy behaviors on student state motivation, affective learning, and perceptions of cognitive learning loss. Multiple regression analyses indicated learner-to-learner immediacy as functioning similarly to teacher-to-student immediacy when mediated through state motivation in its influence on student affective learning and perceptions of cognitive learning loss. digital.library.unt.edu/ark:/67531/metadc28372/
Mutual Influences in Romantic Attachment, Religious Coping, and Marital Adjustment
This study examined associations among romantic attachment anxiety and avoidance, positive and negative religious coping, and marital adjustment in a community sample of 81 heterosexual couples. Both spouses completed the Experiences in Close Relationships Scale (ECR), a brief measure of religious coping (Brief RCOPE), the Dyadic Adjustment Scale (DAS), and a demographic questionnaire as part of a larger study. Multilevel modeling (MLM) for the actor-partner interdependence model (APIM) was used. Attachment avoidance was inversely related to positive religious coping. In contrast, attachment anxiety was directly related to negative religious coping. Positive religious coping buffered the relationship between attachment avoidance and marital adjustment. In contrast, attachment anxiety was detrimental to marital adjustment regardless of positive religious coping, and positive religious coping was related to higher marital adjustment only in the context of low attachment anxiety. Surprisingly, the spouse's attachment anxiety was inversely related to the respondent's marital adjustment only when the respondent reported low levels of negative religious coping, whereas in the context of high negative religious coping, the partner's attachment anxiety was related to higher marital adjustment. Results support using attachment theory to conceptualize religious coping and the consideration of both attachment and religious coping constructs in counseling. digital.library.unt.edu/ark:/67531/metadc283784/
Synthesis and Design of Microwave Filters and Duplexers with Single and Dual Band Responses
In this thesis the general Chebyshev filter synthesis procedure to generate transfer and reflection polynomials and coupling matrices were described. Key concepts such as coupled resonators, non-resonant nodes have been included. This is followed by microwave duplexer synthesis. Next, a technique to design dual band filter has been described including ways to achieve desired return loss and rejection levels at specific bands by manipulating the stopbands and transmission zeros. The concept of dual band filter synthesis has been applied on the synthesis of microwave duplexer to propose a method to synthesize dual band duplexers. Finally a numerical procedure using Cauchy method has been described to estimate the filter and duplexer polynomials from measured responses. The concepts in this thesis can be used to make microwave filters and duplexers more compact, efficient and cost effective. digital.library.unt.edu/ark:/67531/metadc283787/
Racial Stereotypes and Racial Assimilation in a Multiracial Society
Interest in a multiracial society has increased in recent years and including on racism and prejudice and in the propensity to stereotype out-groups. Theories on racism help explain the dominant group's prejudice toward subordinate groups. Yet they only explain why dominant group members stereotype subordinates or if the dominant group's propensity to stereotype is different from that of subordinate groups. Recent assimilation theories suggest that some minorities are assimilating with Whites but Blacks are not undergoing assimilation. Classic assimilation theory suggests that when a subordinate group assimilates with the dominant group then they will also take on the dominant group's values and beliefs, including their prejudices and propensities to stereotype. The use of racial stereotypes in support of the assimilation of a minority group has not been tested. Results from the LSAF national survey provide support for Asians to be assimilating with Whites. However, Hispanics do not appear to be taking on Whites' propensity to stereotype, contradicting the prediction that Hispanics are assimilating with Whites. digital.library.unt.edu/ark:/67531/metadc28379/
Level Curves of the Angle Function of a Positive Definite Symmetric Matrix
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Given a real N by N matrix A, write p(A) for the maximum angle by which A rotates any unit vector. Suppose that A and B are positive definite symmetric (PDS) N by N matrices. Then their Jordan product {A, B} := AB + BA is also symmetric, but not necessarily positive definite. If p(A) + p(B) is obtuse, then there exists a special orthogonal matrix S such that {A, SBS^(-1)} is indefinite. Of course, if A and B commute, then {A, B} is positive definite. Our work grows from the following question: if A and B are commuting positive definite symmetric matrices such that p(A) + p(B) is obtuse, what is the minimal p(S) such that {A, SBS^(-1)} indefinite? In this dissertation we will describe the level curves of the angle function mapping a unit vector x to the angle between x and Ax for a 3 by 3 PDS matrix A, and discuss their interaction with those of a second such matrix. digital.library.unt.edu/ark:/67531/metadc28376/
Predicting Chemical and Biochemical Properties Using the Abraham General Solvation Model
Several studies were done to illustrate the versatillity of the Abraham model in mathematically describing the various solute-solvent interactions found in a wide range of different chemical and biological systems. The first study focused on using the solvation model to construct mathematical correlations describing the minimum inhibitory concentration of organic compounds for growth inhibition towards the three bacterial strains Porphyromonas gingivalis, Selenomonas artemidis, and Streptococcus sobrinus. The next several studies expand the practicallity of the Abraham model by predicting free energies of partition in chemical systems. The free energy studies expand the use of the Abraham model to other temperatures and properties by developing correlations for the enthalpies of solvation of gaseous solutes of various compounds dissolved in water, 1-octanol, hexane, heptane, hexadecane, cyclohexane, benzene, toluene, carbon tetrachloride, chloroform, methanol, ethanol, 1-butanol, propylene carbonate, dimethyl sulfoxide, 1,2-dichloroethane, N,N-dimethylformamide, tert-butanol, dibutyl ether, ethyl acetate, acetonitrile, and acetone. Also, a generic equation for linear alkanes is created for use when individual datasets are small. The prediction of enthalpies of solvation is furthered by modifying the Abraham model so that experimental data measured at different temperatures can be included into a single correlation expression. The temperature dependence is directly included in the model by separating each coefficient into an enthalpic and entropic component. Specifically, the final study describes the effects of temperature on the sorption coefficients of organic gases onto humic acid. The derived predicted values for each research study show a good correlation with experimental values. digital.library.unt.edu/ark:/67531/metadc28373/
An Examination of Resnick's Model of Malingering: a Pai Study of Feigned Ptsd
Malingered posttraumatic stress disorder (PTSD) poses a formidable clinical challenge in personal injury and disability cases because of the apparent ease in feigning PTSD and the supposed link (proximate cause) to the claimed damages. The effective assessment of feigned PTSD is particularly challenging because this diagnosis is both easier to fake than other Axis I disorders and more difficult to detect. As an additional confound, some patients with genuine PTSD produce highly variable, elevated profiles on multiscale inventories that are difficult to distinguish from feigned PTSD. The current study examined whether the Personality Assessment Inventory (PAI) can effectively differentiate between genuine and feigned PTSD in 109 inpatients from a trauma unit. The two most effective scales were the MAL and the NDS scales. As a primary focus, the current study was the first empirical investigation of Resnick's model of malingered PTSD that is comprised of three subtypes: pure malingering (pure-M), partial malingering (partial-M), and false imputation (false-I). The primary goal was to evaluate whether each feigning group was able to (a) effectively simulate PTSD symptoms and diagnoses and (b) avoid being classified as feigning. The partial-M group proved to be the best feigning group in achieving these two goals. Furthermore, the use of well-defined groups, including an indeterminate band (i.e., unclassified) around each cut score, was explored. Overall, the use of well-defined groups improved accuracy in classification and reduced the number of false-positives. digital.library.unt.edu/ark:/67531/metadc283796/
Preschool Teachers' Self-reported Levels of Preparation for Classroom Behavior Management
Research indicates that serious behavior problems begin during the early childhood years. The study examined the perceived preparedness of teachers related to behavior management as well as preschool teachers' usage of evidence-based prevention and intervention strategies. The data indicates that preschool teachers feel prepared for managing aggression in their classrooms and report utilizing evidence-based prevention and intervention strategies regularly. Additionally, the data shows a weak relationship between teacher variables and the likelihood of feeling prepared for managing aggression or utilizing evidence-based strategies. The results can be used to gain a better understanding of special education preschool teachers' training needs in regard to behavior management and managing behavior problems in the preschool classroom. digital.library.unt.edu/ark:/67531/metadc283797/
Investigating the effects on parallel play between siblings: Teaching children with autism to emit social phrases to their typically developing sibling.
The focus of this study was three fold. First, modeling and feedback were investigated as a training package for social interactions between siblings. Second, the effects of social phrases taught to the sibling with autism were investigated. Third, the magnitude of these social phrases was measured by timing duration of parallel play. The experimental design is an A-B-A1-A2 design conducted in a clinic, with a probe for generalization in the home environment. This intervention was replicated across an additional sibling dyad to indicate its effectiveness. This study ascertained that the sibling with autism was a viable participant in learning new social skills that could function as a behavioral cusp and increase sibling interactions. digital.library.unt.edu/ark:/67531/metadc28370/
An Investigation of Malingering and Defensiveness Using the Spanish Pai Among Spanish-speaking Hispanic American Outpatients
For response styles, malingering describes the deliberate production of feigned symptoms by persons seeking external gain such as financial compensation, exemption from duty, or leniency from the criminal justice system. In contradistinction, defensiveness occurs when patients attempt to downplay their symptoms of psychological impairment. Both of the aforementioned response styles can markedly affect the accuracy of diagnosis, especially on self-reports, such as multiscale inventories. As an important oversight, no studies have been conducted to examine the effect of culturally specific response styles on profile validity and the classification of malingering among Hispanic American clinical populations. The current study investigated whether the Spanish Personality Assessment Inventory (PAI) effectively distinguished between Spanish-speaking outpatient groups randomly assigned to honest, feigning, and defensive experimental conditions. In examining the results, PAI malingering indicators utilizing Rare Symptoms strategies (NIM and MAL) demonstrated moderate to large effect sizes. For defensiveness, Spanish PAI indicators also demonstrated moderate to very large effect sizes (M d = 1.27; range from 0.94 to 1.68). Regarding psychometric properties, Spanish PAI validity scales, provide adequate to good data on reliability and discriminant validity. Clinical utility of the Spanish PAI increases as different cut scores are employed. digital.library.unt.edu/ark:/67531/metadc283782/
A New Wireless Sensor Node Design for Program Isolation and Power Flexibility
Over-the-air programming systems for wireless sensor networks have drawbacks that stem from fundamental limitations in the hardware used in current sensor nodes. Also, advances in technology make it feasible to use capacitors as the sole energy storage mechanism for sensor nodes using energy harvesting, but most current designs require additional electronics. These two considerations led to the design of a new sensor node. A microcontroller was chosen that meets the Popek and Goldberg virtualization requirements. The hardware design for this new sensor node is presented, as well as a preliminary operating system. The prototypes are tested, and demonstrated to be sustainable with a capacitor and solar panel. The issue of capacitor leakage is considered and measured. digital.library.unt.edu/ark:/67531/metadc28378/
Grounds-Based and Grounds-Free Voluntarily Child Free Couples: Privacy Management and Reactions of Social Network Members
Voluntarily child free (VCF) individuals face stigmatization in a pronatalist society that labels those who do not want children as deviant. Because of this stigmatization, VCF couples face privacy issues as they choose to reveal or conceal their family planning decision and face a variety of reactions from social network members. Therefore, communication privacy management and communication accommodation theory was use to examine this phenomenon. Prior research found two different types of VCF couples: grounds-based and grounds-free. Grounds-based individuals cite medical or biological reasons for not having children, while grounds-free individuals cite social reasons for not having children. The purpose of this study is to examine how grounds-based and grounds-free VCF couples manage their disclosure of private information and how social network members react to their family planning decision. Findings revealed that grounds-free individuals are more likely to engage in the self-defense hypothesis and grounds-based individuals are more likely to engage in the expressive need hypothesis. Grounds-based individuals were asked about their decision in dyadic situations, whereas grounds-free individuals were asked at group gatherings. Additionally, social network members used under-accommodation strategies the most frequently and grounds-free individuals experienced more name calling than grounds-based. Finally, while grounds-free individuals experienced non-accommodation and over-accommodation strategies, grounds-based did not. Findings suggest that grounds-free individuals are more stigmatized by social network members. Implications for merging CPM and CAT are discussed. digital.library.unt.edu/ark:/67531/metadc28374/
A Performance Guide to Arvo Pärt's Concerto Piccolo Über B-A-C-H for Trumpet, Strings, Harpsichord, and Piano
Arvo Pärt's Concerto Piccolo über B-A-C-H for trumpet, strings, harpsichord, and piano is a brief yet challenging work in the trumpet repertoire. A carefully articulated performance guide is necessary to aid trumpeters in overcoming the numerous musical challenges presented in this piece. Currently, there is no resource that helps in solving performance choices and difficulties in this work. This first section of this document provides historical and contextual information on Arvo Pärt, his compositional output during his experimental period, and subsequently, Concerto Piccolo. The second section includes a performance analysis of the work, while the third gives trumpet players pedagogical suggestions and practical exercises for proper preparation of Concerto Piccolo. This guide presents performers with relevant background, analytical, and pedagogical information required for an informed and high-level performance. digital.library.unt.edu/ark:/67531/metadc283781/
A study of freshman interest groups and leadership practices at Texas Woman's University
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This study investigated the level of leadership practices and retention rates of freshman students at Texas Woman's University. The data for the study were collected using the Leadership Practices Inventory, Student Version. The sample for the study consisted of 151 freshman students. The students were each placed in one of three control groups. Group A students (the treatment group) were in the Neighbors Educated Together Program (NET). Group B students (control group) were in one of two university-sponsored programs (COLORS or University 1000), and Group C students (control group) were the residual group of first-time college freshmen. These three groups were surveyed prior to their participation in the NET program or a university-sponsored program and again at the end of 14 weeks. In addition, retention rates were examined on the 12 class day of the spring semester. The study found statistically significant differences (p <. 05) on the pretests and posttests between Group C, residual students, and the other two groups on the Enabling the Followers to Act subscale, the Inspiring a Shared Vision subscale, and Encouraging the Heart subscale. Group A, NET students, and Group B, COLORS/University 1000 students, showed no statistically significant differences between groups. The difference from the residual group could indicate that students who self-select into programs such as NET, COLORS, and University 1000 are more likely to engage in practices measured by the subscale prior to enrollment in the respective programs. No statistically significant differences were found on the Challenging the Process or Modeling the Way subscales. The lack of significance shows that there are no differences in practices for any of these groups prior to enrollment at the university or as a result of participation in a university-sponsored program such as NET, COLORS, or University 1000. A chi-square test was performed following the 12 class day for the Spring 2001 th semester. Approximately 89% of the students in Group C Residual, 97% of Group B COLORS/University 1000, and 91% of Group A NET were retained. The chi- square frequency test revealed no statistically significant differences in level of retention between groups. digital.library.unt.edu/ark:/67531/metadc2837/
Accuracy and Interpretability Testing of Text Mining Methods
Extracting meaningful information from large collections of text data is problematic because of the sheer size of the database. However, automated analytic methods capable of processing such data have emerged. These methods, collectively called text mining first began to appear in 1988. A number of additional text mining methods quickly developed in independent research silos with each based on unique mathematical algorithms. How good each of these methods are at analyzing text is unclear. Method development typically evolves from some research silo centric requirement with the success of the method measured by a custom requirement-based metric. Results of the new method are then compared to another method that was similarly developed. The proposed research introduces an experimentally designed testing method to text mining that eliminates research silo bias and simultaneously evaluates methods from all of the major context-region text mining method families. The proposed research method follows a random block factorial design with two treatments consisting of three and five levels (RBF-35) with repeated measures. Contribution of the research is threefold. First, the users perceived a difference in the effectiveness of the various methods. Second, while still not clear, there are characteristics with in the text collection that affect the algorithms ability to extract meaningful results. Third, this research develops an experimental design process for testing the algorithms that is adaptable into other areas of software development and algorithm testing. This design eliminates the bias based practices historically employed by algorithm developers. digital.library.unt.edu/ark:/67531/metadc283791/
Comparative Phyto-uptake Across Distribution Coefficients of Pharmaceutical Compounds and Aquatic Macrophytes: Carbamazepine and Amiodarone Uptake in Lemna Spp
Few studies have been conducted on the effectiveness of phytoremediation of pharmaceutical compounds, although the persistent and non-acutely toxic nature of many of these compounds in today's water bodies may yield an ideal application for this practice. To quantify the potential effectiveness of plant uptake, kinetic and proportional bioconcentration factors (BCFk, and BCFp, respectively) in nanograms (ng) carbamazepine and amiodarone per gram (g) wet weight plant tissue for Lemna spp. were determined utilizing a 14-day continuous flow-through study. Samples were analyzed using isotope dilution liquid chromatography-tandem mass spectrometry (ID-LC-MS/MS) running in positive ion mode. Kinetic BCF was estimated at 0.538, while proportional BCF was estimated at 0.485. Kinetic BCF for the amiodarone study was estimated at 23.033, whereas proportional BCF was estimated at 41.340. Possible contamination of the C18 column and peristaltic pump failure may have impacted uptake results. In light of variability and current lack of research in the field, this work should be considered exploratory rather than conclusive. digital.library.unt.edu/ark:/67531/metadc283798/
Correlates Between Adult Romantic Attachment Patterns and Dimensional Personality Pathology
Previous research has suggested that adult attachment disturbance is related to maladaptic interaction patterns and personality disorder constructs. Specifically, research indicates that those with attachment disturbance are significantly more likely to meet criteria for a number of personality disorders, including borderline personality disorder, narcissistic personality disorder, and antisocial personality disorder. The purpose of this study was to investigate the associations between adult attachment and the new dimensional model of personality disorders scheduled to be released in the Diagnostic and Statistical Manual for Mental Health Diosrders (5th ed.) in spring 2013. Participants completed the Schedule for Adaptive and Nonadaptive Personality (SNAP) to measure dimensional personality functioning and the Experiences in Close Relationships (ECR-R) and the Attachment Prototypes to measure adult attachment patterns. Additionally, select scales from the Personality Assessment Inventory (PAI) and the Five Factor Model (FFM) will be utilized as secondary measures of personality patterns. The results suggest strong associations between adult attachment orientations and specific maladaptive personality characteristics. digital.library.unt.edu/ark:/67531/metadc283794/
Transition Metal Mediated C-o Bond Cleavage: From Co2 Activation to Lignin Degradation
CO2 activation and conversion mediated by transition metal (TM) catalysts were investigated. Homogeneous catalysis of the reverse water gas shift reaction CO2+H2→H2O+CO was studied as a means to reduce CO2.  β-diketiminato metal models L'MI ( L' =C3N2H5-; M = first-row TMs) were considered as potential catalysts. The thermodynamics of prototypical reaction pathways were simulated using B3LYP/aug-cc-pVTZ. Results show that middle series metal complexes result in more thermodynamically favorable properties; therefore, more detailed thermodynamic and kinetic studies were carried out for Mn, Fe, and Co complexes. On the other hand, heterogeneous catalysis of the reduction of CO2 to CO was carried out on Fe, Co, Ni, and Cu surfaces, using the PBE functional. Reaction barriers were calculated using the climbing image nudged elastic band method. Late 3d and 4d transition metal ion (Fe, Co, Ni, Cu, Ru, Rh, Pd, and Ag) mediated activation of dimethyl ether was studied to investigate the intrinsic catalytic properties of metals for C-O bond cleavage. A set of density functional theory (DFT) methods (BLYP, B3LYP, M06, M06-L, B97-1, B97-D, TPSS, and PBE) with aug-cc-pVTZ basis sets was calibrated with CCSD(T)/CBS calculations on reaction energies and barriers. digital.library.unt.edu/ark:/67531/metadc283790/
The Masculinity Masquerade: the Portrayal of Men in Modern Advertising
The depiction of gender in advertising is a topic of continuous discussion and research. The present study adds to past findings with an updated look at how men are represented in U.S. advertising media and the real effects these portrayals have on the male population under the theoretical framework of hegemony and social cognitive theory. This research is triangulated with a textual analysis of the ads found in the March 2013 editions of four popular print publications and three focus group sessions separated by sex (two all-male, one all-female), each of which is composed of a racially diverse group of undergraduate journalism and communications students from a large Southwestern university. The results of the textual analysis reveal little ethnic or physical diversity among male figures in advertising and distinguish six main profiles of masculinity, the most frequent of which is described as the "sophisticated man." The focus groups identify depictions of extreme muscularity and stereotypical male incompetence as the most negative representations, while humorous and hyperbolic portrayals of sexual prowess and hyper-masculinity are viewed positively as effective means of marketing to men. digital.library.unt.edu/ark:/67531/metadc283789/