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 Degree Level: Doctoral
Acceptance Theories for Behavior in Conducting Research: Instructors in the Rajabhat University System, Thailand

Acceptance Theories for Behavior in Conducting Research: Instructors in the Rajabhat University System, Thailand

Date: December 2015
Creator: Laksaniyanon, Benchamat
Description: Responding to globalization and its effects on education and research development, the Thai government decided to push all public universities to become autonomous and establish a system of quality assurances. The establishment of quality assurances has had a large impact on many Thai instructors, especially in new public universities. Thai instructors are now forced to more focus on conducting research because the number of research publications is regarded as one of the main criteria for quality universities. The purpose of this study is to investigate the key factors, at the individual and university levels, which impact on the instructors' behavior in conducting research of the full-time instructors in the faculty of Management Science from the Rajabhat Universities in Thailand. The current study will help explain how and why the instructors accept or refuse to conduct research and provide insight into the salient factors motivating the instructors to produce more research by conducting HLM. Data were collected from 694 participants at 37 institutions via a questionnaire survey. The findings revealed that there was no difference among these 37 universities on behavior in conducting research. The key factors statistically influencing behavior in conducting research of the instructors were facilitating conditions, academic degree, ...
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Accurate Energetics Across the Periodic Table Via Quantum Chemistry

Accurate Energetics Across the Periodic Table Via Quantum Chemistry

Date: December 2015
Creator: Peterson, Charles Campbell
Description: Greater understanding and accurate predictions of structural, thermochemical, and spectroscopic properties of chemical compounds is critical for the advancements of not only basic science, but also in applications needed for the growth and health of the U.S. economy. This dissertation includes new ab initio composite approaches to predict accurate energetics of lanthanide-containing compounds including relativistic effects, and optimization of parameters for semi-empirical methods for transition metals. Studies of properties and energetics of chemical compounds through various computational methods are also the focus of this research, including the C-O bond cleavage of dimethyl ether by transition metal ions, the study of thermochemical and structural properties of small silicon containing compounds with the Multi-Reference correlation consistent Composite Approach, the development of a composite method for heavy element systems, spectroscopic of compounds containing noble gases and metals (ArxZn and ArxAg+ where x = 1, 2), and the effects due to Basis Set Superposition Error (BSSE) on these van der Waals complexes.
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Addressing Multicultural Issues in the Counselor Education Classroom: a Phenomenological Analysis

Addressing Multicultural Issues in the Counselor Education Classroom: a Phenomenological Analysis

Date: December 2015
Creator: Wagner, Terra M.
Description: Multicultural education in counselor education is a popular topic among counselor educators and scholars. To date, scholars have focused on understanding the experiences of counselor educators who teach dedicated multicultural courses. However, less attention has been given to other counselor educators who are required by ethical and training standards to address multicultural issues across the curriculum. The purpose of this study was to understand counselor educators’ experiences addressing multicultural issues in courses that do not have a specific multicultural or diversity focus. I used phenomenological methodology to explore the experiences of counselor educators who hold doctoral degrees in counseling or a related field, have taken a multicultural/diversity course in their graduate training, are full-time clinical or tenure-line faculty members in CACREP-accredited programs, and have never taught courses dedicated to multicultural or diversity issues. Twelve participants (six men and six women), ranging in age ranged from 31 to 65, participated in the study. Ten participants identified as White, one African-American, and one Hispanic. The research team identified eight themes: (1) reasons for avoidance, (2) constraints, (3) qualities and practices, (4) educator as a factor in student development, (5) infusion, (6) personal background, (7) awareness of biases and assumptions, and (8) counselor ...
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Áskell Másson’s Solos for Snare Drum: Maximizing Musical Expression Through Varying Compositional Techniques and Experimentation in Timbre

Áskell Másson’s Solos for Snare Drum: Maximizing Musical Expression Through Varying Compositional Techniques and Experimentation in Timbre

Date: December 2015
Creator: O’Neal, John Micheal
Description: This dissertation and accompanying lecture recital explores the musical elements present in Áskell Másson’s three solos for snare drum, PRÍM (1984), KÍM (2001) and B2B: Back to Basics (2010). Two of the primary challenges for the performer when playing solo literature on a non-pitch oriented instrument are identifying thematic structures and understanding how to interpret all innovative sound production techniques employed within the music. A thematic and compositional analysis, as well as an investigation into the experimentation of timbre found in Másson’s three pieces for solo snare drum will help to clarify the musical complexities that are present throughout.
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Biological Applications of a Strongly Luminescent Platinum (Ii) Complex in Reactive Oxygen Species Scavenging and Hypoxia Imaging in Caenorhabditis Elegans

Biological Applications of a Strongly Luminescent Platinum (Ii) Complex in Reactive Oxygen Species Scavenging and Hypoxia Imaging in Caenorhabditis Elegans

Date: December 2015
Creator: Kinyanjui, Sophia Nduta
Description: Phosphorescent transition metal complexes make up an important group of compounds that continues to attract intense research owing to their intrinsic bioimaging applications that arise from bright emissions, relatively long excited state lifetimes, and large stokes shifts. Now for biomaging assay a model organism is required which must meet certain criteria for practical applications. The organism needs to be small, with a high turn-over of progeny (high fecundity), a short lifecycle, and low maintenance and assay costs. Our model organism C. elegans met all the criteria. The ideal phosphor has low toxicity in the model organism. In this work the strongly phosphorescent platinum (II) pyrophosphito-complex was tested for biological applications as a potential in vivo hypoxia sensor. The suitability of the phosphor was derived from its water solubility, bright phosphorescence at room temperature, and long excited state lifetime (~ 10 µs). The applications branched off to include testing of C. elegans survival when treated with the phosphor, which included lifespan and fecundity assays, toxicity assays including the determination of the LC50, and recovery after paraquat poisoning. Quenching experiments were performed using some well knows oxygen derivatives, and the quenching mechanisms were derived from Stern-Volmer plots. Reaction stoichiometries were derived from ...
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Characterizing the Molecular Changes of Austrofundulus Limnaeus As It Develops Towards and Enters Diapause Ii

Characterizing the Molecular Changes of Austrofundulus Limnaeus As It Develops Towards and Enters Diapause Ii

Date: December 2015
Creator: Toni, Lee S.
Description: Austrofundulus limnaeus is a species of annual killifish which inhabits ephemeral ponds in South America. The species is able to survive seasonally desiccating ponds due to their ability to produce robust embryos. The embryos of this species are capable of entering a developmental arrest, termed diapause II, which precedes the onset of drought. While in this arrested state embryos exhibit the greatest tolerance to anoxia of any characterized vertebrate at 25ºC. Furthermore, when raised at 30ºC, embryos escape the entrance to diapause II and go on to develop directly. Currently, little is known about the molecular mechanisms which induce and maintain this developmentally arrested state. In this study I have developed methods to analyze changes in histone modifications in the context of diapause II. Histone modifications were chosen due to their extreme conservation and well characterized role as modulators of gene expression in other systems. Results utilizing adapted immunobased assays show significant changes in the global amount of H3S10P, H3K27me and H3K4me, as the embryos progress from early embryogenesis through the exit of diapause. Additionally, it is revealed that there exists a degree of phenotypic plasticity with regards to the entrance into diapause II which is modulated by the environment ...
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Comparing Three Effect Sizes for Latent Class Analysis

Comparing Three Effect Sizes for Latent Class Analysis

Date: December 2015
Creator: Granado, Elvalicia A.
Description: Traditional latent class analysis (LCA) considers entropy R2 as the only measure of effect size. However, entropy may not always be reliable, a low boundary is not agreed upon, and good separation is limited to values of greater than .80. As applications of LCA grow in popularity, it is imperative to use additional sources to quantify LCA classification accuracy. Greater classification accuracy helps to ensure that the profile of the latent classes reflect the profile of the true underlying subgroups. This Monte Carlo study compared the quantification of classification accuracy and confidence intervals of three effect sizes, entropy R2, I-index, and Cohen’s d. Study conditions included total sample size, number of dichotomous indicators, latent class membership probabilities (γ), conditional item-response probabilities (ρ), variance ratio, sample size ratio, and distribution types for a 2-class model. Overall, entropy R2 and I-index showed the best accuracy and standard error, along with the smallest confidence interval widths. Results showed that I-index only performed well for a few cases.
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Computational Modeling of Small Molecules

Computational Modeling of Small Molecules

Date: December 2015
Creator: Weber, Rebecca J.
Description: Computational chemistry lies at the intersection of chemistry, physics, mathematics, and computer science, and can be used to explain the behavior of atoms and molecules, as well as to augment experiment. In this work, computational chemistry methods are used to predict structural and energetic properties of small molecules, i.e. molecules with less than 60 atoms. Different aspects of computational chemistry are examined in this work. The importance of examining the converged orbitals obtained in an electronic structure calculation is explained. The ability to more completely describe the orbital space through the extrapolation of energies obtained at increasing quality of basis set is investigated with the use of the Sapporo-nZP-2012 family of basis set. The correlation consistent Composite Approach (ccCA) is utilized to compute the enthalpies of formation of a set of molecules and the accuracy is compared with the target method, CCSD(T,FC1)/aug-cc-pCV∞Z-DK. Both methodologies are able to produce computed enthalpies of formation that are typically within 1 kcal mol-1 of reliable experiment. This demonstrates that ccCA can be used instead of much more computationally intensive methods (in terms of memory, processors, and time required for a calculation) with the expectation of similar accuracy yet at a reduced computational cost. The ...
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Conquering the Natural Frontier: French Expansion to the Rhine River During the War of the First Coalition, 1792-1797

Conquering the Natural Frontier: French Expansion to the Rhine River During the War of the First Coalition, 1792-1797

Date: December 2015
Creator: Hayworth, Jordan R.
Description: After conquering Belgium and the Rhineland in 1794, the French Army of the Sambre and Meuse faced severe logistical, disciplinary, and morale problems that signaled the erosion of its capabilities. The army’s degeneration resulted from a revolution in French foreign policy designed to conquer the natural frontiers, a policy often falsely portrayed as a diplomatic tradition of the French monarchy. In fact, the natural frontiers policy – expansion to the Rhine, the Pyrenees, and the Alps – emerged only after the start of the War of the First Coalition in 1792. Moreover, the pursuit of natural frontiers caused more controversy than previously understood. No less a figure than Lazare Carnot – the Organizer of Victory – viewed French expansion to the Rhine as impractical and likely to perpetuate war. While the war of conquest provided the French state with the resources to survive, it entailed numerous unforeseen consequences. Most notably, the Revolutionary armies became isolated from the nation and displayed more loyalty to their commanders than to the civilian authorities. In 1797, the Sambre and Meuse Army became a political tool of General Lazare Hoche, who sought control over the Rhineland by supporting the creation of a Cisrhenan Republic. Ultimately, ...
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Culturally Proficient Leadership:  Teacher Perceptions of Elementary School Principals in Urban, Title I Schools

Culturally Proficient Leadership: Teacher Perceptions of Elementary School Principals in Urban, Title I Schools

Date: December 2015
Creator: Hendrix, Royond P.
Description: This study examined elementary teachers’ perceptions of their principal’s level of cultural proficiency. Practices for Developing a Culturally Competent School Environment, a survey Camille Smith and adapted by Dr. Mack T. Hines, was completed from a sample size of 119 teachers. The survey contained 35 items, including six constructs: valuing diversity, assessing the culture, managing the dynamics of difference, institutionalizing cultural knowledge and resources, adapting to diversity and inclusiveness. Teachers rated their principal using a Likert scale which consisted of 1 = never uses, 2 = rarely uses, 3 = sometimes uses, 4 = frequently uses, and 5 = always uses. Teachers of various races, ages and years with their principal participated in this study. The study reveals that these variables do not make a statistically significant difference in the teachers’ perception of how proficient they are in valuing diversity, a assessing his/her own culture and institutionalizing cultural knowledge. This quantitative study reveals the variances of statistical significance of teacher demographics: age, gender, years served under current principal and accountability rating of the school. Cultural proficiency is important to the development and maintenance of the necessary relationships among students, teachers, principals and the school community.
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